• 한국식품영양과학회지
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• 제19권2호
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• pp.115-120
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• 1990

This study was conducted to investigate the relation of softening with the mineral compone-nts during ripening of tomato fruits. The mineral contents of Ca, K, Mg, Zn. Fe Mn and Cu and its existence form respiratory rate and hardness during ripening were evaluated. The respiratory rate of tomato fruits was decreased until 42 days after anthesis and then increased the climacteric maximum was found on 49 days after anthesis then decreased. The hardness of tomato fruits during ripening did not change greatly until 45days after anthesis then decrea-sed markedly. The major mineral components of tomato fruits were K, Ca, and Mg, Zn Fe Mn and Cu were the minor components. The contents of soluble Ca, Ma and K increased markedly and those of bound Ca and Mg decreased markedly after 45days during ripening,. However other components were not changed greatly.

• 한국균학회지
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• 제21권1호
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• pp.23-27
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• 1993

Rhizopus nigricans에 의한 progesterone의 $11{\alpha}-hydroxylation$과 ${5\alpha}-reduction$반응에 미치는 이온의 효과를 조사하였다. $Cu^{2+},\;Cd^{2+},\;Co^{2+},\;Mn^{2+},\;Zn^{2+},\;Fe^{2+},\;Mg^{2+},\;Fe^{3+}$ 및 $Na^+$은 $11{\alpha}-hydroxylation$ 반응의 활성을 저하시켰으나 $K^+$은 이 반응을 촉진시켰다. $11{\alpha}-hydroxyprogesterone$을 $5{\alpha}-reduction$시키는 효소는 $Fe^{2+},\;Mn^{2+},\;Mg^{2+},\;Co^{2+},\;Zn^{2+},\;Fe^{2+},\;K^+,\;Na^+$에 의하여 그 활성이 증가되었고 $Cd^{2+}$과 $Cu^{2+}$은 이 반응을 억제하였다. $11{\alpha}-hydroxylation$ 반응을 촉진하는데는 $10^{-3}\;M$의 $K^+$이 효과적이었으며 $5{\alpha}-reduction$반응을 엑제하기 위하여는 $10^{-4}\;M$의 $Cd^{2+}$이 적합하였다. R. nigricans는 세포내의 다효소체계에 의하여 progesterone이 $11\{alpha}-hydroxyprogesterone$으로 전환된 후 $11{\alpha}-hydroxy-allopregnane-3, 20-dione으로 $5{\alpha}-reduction$되므로 $10^{-3}\;M$의 $K^+$을 먼저 첨가하여 2시간 동안 progesterone 전환 반응을 실시한 후에 $10^{-4}\;M$의 $Cd^{2+}$을 첨가하였을 때 가장 높은 $11\{alpha}-hydroxyprogesterone$의 수득률을 얻을 수 있었다.

• 한국식품영양학회지
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• 제16권2호
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• pp.152-157
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• 2003

Serratia marcescen ATCC 25419 protease를 ammonium sulfate treatment, DEAE-cellulose anion exchange chromatography등의 방법으로 정제하였는데 최종 단계에서 667.5 unit/mg 이었으며 회수율은 43%이었고 448배 정제되었다. 정제한 S. marcescens protease로부터 아포효소를 만든 후 금속 재활성화에 대해 조사하였다. S. marcescens protease는 EDTA에 의해 완전히 활성을 잃는 metalloenzyme이며 Hg, Fe, Cu 등에 의해서 효소 활성을 70% 이상 잃은 반면, Co는 효소 활성을 약 20% 정도 증가시켰다. 아포효소의 재활성화는 pH 6~8에서 Mn, Co, Zn 등이 효과적이었다. Mn, Co, Zn등을 아포효소에 가하여 만든 효소들 중에서 Zn-효소는 효소 활성도, 알칼리-불활성화, 열-안정성 면에서 원래 protease와 유사하였다.

• 한국토양비료학회지
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• 제41권3호
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• pp.158-163
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• 2008

시설재배 수박에 대한 적정 양분함량 기준을 설정하기 위하여 2004년부터 2006년까지 고창에서 시설수박의 엽 중 무기양분함량과 수량을 조사하였다. 그 결과 3년간 조사한 수박 재배 농가 포장을 대상으로 생육단계별 적정 양분함량 범위를 설정하였다. 수박 수량과 생육단계별 엽 중 무기양분함량은 정식후 20일이 가장 유의성 있는 상관을 보였으며 이 때 엽 중 다량원소 적정 함량 범위는 N 5.0~6.3%, P 0.30~0.57%, K 3.5~4.2%, Ca 1.7~3.8%, Mg 0.20~0.42% 이었다. Fe, Mn, Zn, Cu 및 B 등의 미량원소 적정함량 범위는 Fe $96\sim128mg\;kg^{-1}$, Mn $67\sim201mg\;kg^{-1}$, Zn $40\sim60mg\;kg^{-1}$, Cu $6\sim9mg\;kg^{-1}$ 및 B $41{\sim}82mg\;kg^{-1}$ 이었고, 적정 양분함량 범위로 설정한 값의 하한치를 양분 결핍, 상한치를 양분 과잉으로 판단했다. 본 시험연구결과 제시한 수박의 생육단계별 적정 양분함량 범위 기준은 농업현장에서 빈번히 발생하는 수박의 영양장애를 해결하기 위한 양분지표로 사용할 수 있을 것이라 생각된다.

• 한국해양학회지:바다
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• 제6권1호
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• pp.27-34
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• 2001

전라북도 서해안의 새만금 조간대에서 채취한 38개 표층퇴적물에서 주성분 원소(Al, Fe, Mg, Ca, Na, K, Ti)와 미량원소(P, Mn, Ba, Sr, V, Cr, Co, Cu, Ni, Zn, Pb)를 분석하였다. 분석된 원소의 함량은 우리나라 타 조간대 퇴적물에서 보고된 값보다 전반적으로 낮았으며, Ba와 Pb를 제외한 모든 원소가 지각물질의 평균함량에 미달하였다. 함량의 변화는 대부분의 원소에서 <20%(${\sigma_x/\overline{x}$)로 비교적 작았으며, 주성분 원소의 Ca와 미량금속의 Ba, Cu 및 Mn이 각각 81%, 62%, 43% 및 33%로 가장 컸다. 공간적으로는 상부조간대에서 함량이 높은 원소와 지역간 차이가 뚜렷하지 않은 원소로 구분되었으며 , 이러한 분포를 결정짓는 가장 중요한 요인은 입도와의 관련성이었다. 입도 의존적인 경향을 나타낸 Al, Fe, Mg, Ti, Pi Mn, V, Co, Cr, Cu, Ni 및 Zn의 함량은 조간대의 상부로 갈수록 증가하였으며, 따라서 이들 원소의 분포는 조수 퇴적작용에 따른 퇴적물의 입도 분화에 의해 조절되는 것으로 판단된다. 한편, 입도와의 관련성이 미약한 Ca와 Sr, Na, K, Ba 및 Pb의 분포는 조립한 입도의 퇴적물에 많이 포함된 탄산염 및 규산염 광물의 영향을 반영하는 것으로 파악되었다.

• 한국해양학회지:바다
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• 제20권4호
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• pp.159-168
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• 2015

한국 남서해 연안의 도암만에서 44개 표층퇴적물을 채취하여 총유기탄소(TOC), 총질소(TN) 및 중금속(Al, Fe, Mn, Cr, Cu, Ni, Pb, Zn)을 분석하였으며, 11개 시료에 대해서는 화학적 존재형태별 분석을 병행하였다. TOC(0.32~3.10%), TN(0.03~0.26%)은 주변 해역의 평균 수준이었고, C/N 비(7.9~11.9)에 근거할 때 육상기원 유기물의 영향이 반영된 일부 지역이 구분되었다. 중금속 함량은 대부분의 정점에서 해양퇴적물 주의기준(TEL) 이하였고, 화학적 존재형태별 함량은 광물격자부분에서 Cr, Cu, Ni 등이, 비광물격자부분에서 Mn, Pb가 총량의 절반을 상회하였다. 연구지역의 중금속 배경농도를 누적빈도곡선과 선형회귀분석에 의해 추정한 결과 Cu=11.8, Ni=23.1, Pb=26.8, Zn=76.6, Cr=56.7, Mn=585 mg/kg으로 계산되었으며, 이를 바탕으로 한 농축지수($I_{geo}$)에 근거해 국지적인 Mn 농축의 징후를 확인하였다. 그러나 농축지수와 존재형태비를 고려할 때 Zn, Pb도 환경변화에 따른 용출 가능성이 추정되었다.

• 한국산업보건학회지
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• 제9권1호
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• pp.56-72
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• 1999

Airborne concentrations of welding fumes in which 13 different metals such as Al, Cd, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Si, Sn, Ti, and Zn were analyzed were measured at 18 factories including automobile assembly and manufactures, steel heavy industries and shipyards. Air samples were collected by personal sampler at each worker's worksite(n=339). Blood levels of Cd, Cu, Fe, Mn, Pb and Zn were also measured from samples taken from 447 welders by atomic absorption spectrometry and compared with control values obtained from 127 non-exposed workers. The results were as follows ; 1. Among various welding types, $CO_2$ welding 70.2 % were widely used, shielded metal arc welding(SMAW) 22.1 % came next, and rest of them were metal inert gas(MIG) welding, submerged arc welding(SAW), spot welding(SPOT) and tungsten inert gas(TIG) welding. 2. Welding fume concentration was $0.92mg/m^3$($0.02{\sim}15.33mg/m^3$) at automobile assembly and manufactures, $4.10mg/m^3$($0.02{\sim}70.75mg/m^3$) at steel heavy industries and $5.59mg/m^3$($0.30{\sim}91.16mg/m^3$) at shipyards, respectively, showing significant difference among industry types. Workers exposed to high concentration of welding fumes above Korean Permissible Exposure Limit(KPEL) amounted to 7.9 % and 12.5 %, in $CO_2$ welding and in SMAW at automobile assembly and manufactures and 62.7 % in $CO_2$ welding, and 12.5 % in SMAW at shipyards, and 66.2 % in $CO_2$ welding and 70.6 % in SMAW at steel heavy industries. 3. Geometric mean of airborne concentration of each metal released from welding fumes was below one 10th of KPEL in all welding types. Percentage of workers, however, exposed to airborne concentration of metals above KPEL amounted to 16.8 % in Mn and 7.6 % in Fe in $CO_2$ welding; 37.5 % in Cu in SAW, 30 % in Cu in TIG; and 25 % in Pb in SPOT welding. As a whole, 76 Workers(22.4%) were exposed to high concentration of any of the metals above KPEL. 4. There were differences in airborne concentration of metals such as Al, Cd, Cr, Cu. Fe. Mn, Mo, Ni, Pb, Si, Sn, Ti and Zn by industry types. These concentrations were higher in shipyards and steel heavy industries than in automobile assembly and manufactures. Workers exposed to higher concentration of Pb above KPEI amounted to 7.4 % of workers(7/94) in automobile assembly and manufactures. In shipyards, 19.2 % of workers(19/99) were over-exposed to Mn and 7.1 % (7/99) to Fe above KPEL. In steel heavy industries, 14.4 %(21/146), 7.5 %(11/146) and 13 %(19/146) were over-exposed to Mn, Fe and Cu, respectively. As a whole, 76 out of 339 workers(22.4%) were exposed to any of the metals above KPEL. 5. Blood levels of Cd, Cu, Fe, Mn, Pb, and Zn in welders were $0.11{\mu}g/100m{\ell}$, $0.84{\mu}g/m{\ell}$, $424.4{\mu}g/m{\ell}$, $1.26{\mu}g/100m{\ell}$, $5.01{\mu}g/100m{\ell}$ and $5.68{\mu}g/m{\ell}$, respectively, in contrast to $0.09{\mu}g/100m{\ell}$, $0.70{\mu}g/m{\ell}$, $477.2{\mu}g/m{\ell}$, $0.73{\mu}g/100m{\ell}$, $3.14{\mu}g/100m{\ell}$ and $6.15{\mu}g/m{\ell}$ in non-exposed control groups, showing significantly higher values in welders but Fe and Zn.

• 생약학회지
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• 제22권1호
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• pp.33-35
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• 1991

Heavy metals may cause trouble(s) in human body. For consideration of the safety of crude drugs cultivated in Korea, we selected some medicinal plants and soils from cultivated site and estimated their heavy metal contents by inductively coupled argon plasma spectrometry (ICAP). Among heavy metals tested, the highest level of Cu and Zn were shown in plants cultivated in Kyung Ki; the highest level of Fe in those in Youngnam and the highest level of Mg and Mn in those in Youngdong. The heavy metal content s were as low as to be permeasible at least for the medicinal plants we selected. There were no significant correlations between heavy metal contents of soils and cultivated medicinal plants.

• 한국대기환경학회지
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• 제5권2호
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• pp.72-83
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• 1989

Twenty-five atmospheric particulates were collected using a high volume aerosol sampler from Septermber to December, 1988 on a site located on the West coast of Korea and analysed for twelve elements (Na, Mg, Al, Mn, Fe, Cu, Co, Ni, Zn, Ag, Cd, and Pb) by AAS. The particles being mainly crustal minerals, large quantity of spherical fly ashes were also observed. In order to identify the origin of trace metals in atmospheric particulates, enrichment factor, interelemental correlation and factor analysis were performed. Based upon these analysis, the twelve elements can be classified into three groups; the elements dominantly present in soil particles (Al, Mn, Fe, Co, and Ni), those in sea salt aerosols (Na and Mg), and those in air pollution-derived particles (Cu, Cd, Pb, Ag and Zn).

• 대한예방한의학회지
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• 제6권2호
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• pp.66-85
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• 2002

Traditional herbal medicine is used extensively among the Korean populations, and other Asian countries employ similar therapies as well In recent years, extensive focus was laid on adulteration of the herbal medicine with heavy metals. This may be mainly due to a soil contamination by an environmental pollution. The objective of this study is to identify the contents of various heavy metals in the blood from OhJeokSan-Decoction (OD) treated-rats. For this study, 13 kinds of metals including essential and heavy metals, i.e. Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Se and Zn were analyzed by a slight modification of EPA methods and the following results are obtained. ; 1. There is no significant difference between the OD-treated groups and control group in liver, kidney, bone, brain, weight, food intake. 2. The amount of each metal analyzed in the liver are as follows; Al ; $0.235{\sim}4.215mg／kg$, As ; $0.103{\sim}0.461mg／kg$, Cd ; $0.005{\sim}0.010mg／kg$, Co ; $0.017{\sim}0.046mg／kg$, Cr ; $0.137{\sim}0.403mg／kg$, Cu ; $1.736{\sim}4.827mg／kg$, Fe ; $54.472{\sim}381.447mg／kg$, Hg ; not detected, Mn ; $1.159{\sim}2.803mg／kg$, Ni ; $0.007{\sim}0.095mg／kg$, Pb ; not detected, Se ; $0.682{\sim}1.887mg／kg$, Zn ; $10.213{\sim}26.119mg／kg$, by groups, respectively. In control and other experimental group, several metal (Co, Cu, Mn, Zn, As, Cr) has a significant difference, but in experimental I and other experimental II, III, IV, V groups, there are no significant difference. 3. The amount of each metal analyzed in the kidney are as follows; Al ; $1.712{\sim}31.230mg／kg$, As ; $0.062{\sim}0.439mg／kg$, Cd ; $0.010{\sim}0.062mg／kg$, Co ; $0.000{\sim}0.101mg／kg$, Cr ; $0.125{\sim}0.636mg／kg$, Cu ; $3.385{\sim}12.502mg／kg$, Fe ; $41.148{\sim}99.709mg／kg$, Hg ; $0.000{\sim}0.270mg／kg$, Mn ; $0.433{\sim}2.301mg／kg$, Ni ; $0.000{\sim}0.221mg／kg$, Pb ; $0.000{\sim}0.584mg／kg$, Se ; $0.540{\sim}1.600mg／kg$, Zn ; $8.775{\sim}17.060mg／kg$, by groups, respectively. The concentration of Cu, Se, Cr, and Hg are variated significantly in control and other experimental group, and Cu, Se, Cd, Cr are variated significantly in experimental I and other experimental II, III, IV, V groups. 4. The amount of each metal analyzed in the bone(tibia and fibula) are as follows; Al ; $9.557{\sim}119.464mg／kg$, As ; $0.139{\sim}12.250mg／kg$, Cd ; $0.000{\sim}0.295mg／kg$, Co ; $0.022{\sim}0.243mg／kg$, Cr ; $0.239{\sim}1.999mg／kg$, Cu ; $0.000{\sim}2.291mg／kg$, Fe ; $240.249{\sim}841.956mg／kg$, Hg ; $0.000{\sim}0.983mg／kg$, Mn ; $0.214{\sim}7.353mg／kg$, Ni ; $5.473{\sim}11.453mg／kg$, Pb ; $0.000{\sim}8.502mg／kg$, Se ; $0.000{\sim}3.005mg／kg$, Zn ; $61.158{\sim}195.038mg／kg$, by groups, respectively. The concentration of Se, Cd are variated significantly in control and other experimental groups, and Se is variated significantly in experimental I and other experimental II, III, IV, V groups. 5. Exceptionally several metal concentration is increased or decreased. but there is no significant harmful difference of metal concentration in the liver, kidney and bone, from the OD-treated-rats compared to those of the control group even if higher dosage($1{\sim}8$ times dosage of person) of OD was administered. Thus, it is expected that the herbal decoction in the traditional herbal medicine would not lay any burden on the body and the heavy metal toxins would not affect our physiological system. However, other kinds of herbal treatment, such as i.v. and i.p. should be considered in terms of metal toxicity in the body since the level of certain metal.