• Title/Summary/Keyword: Crystals

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Growth of $La_{2-x}$$Sr_x$Cu$O_4$Single Crystals for Device Application

  • Tanaka, Isao
    • Progress in Superconductivity
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    • v.4 no.1
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    • pp.14-18
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    • 2002
  • We had succeeded to grow bulk sing1e crystals of La/sub 2-x/Sr/sub x/$CuO_4$by the traveling solvent floating zone method (TSFZ), and to prepare La/sub 2-x/Sr/sub x/CuO$_4$single-crystalline thick films on the Zn-doped La$_2$$CuO_4$ substrate by new liquid phase epitaxial technique using an infrared heating furnace (IR-LPE). In this paper, Ireview growth of bulk single crystals and single-crystalline thick films of La/sub 2-x/Sr/sub x/$CuO_4$, and discuss on their device properties to develop high speed integrated electronic devices.

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Fabrication of Three-Dimensional Magnetophotonic Crystals:Opal Thin Films Filled with Bi:YIG

  • Fujikawa, R.;Baryshev, A.V.;Uchida, H.;Lim, P.B.;Inoue, M.
    • Journal of Magnetics
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    • v.11 no.3
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    • pp.147-150
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    • 2006
  • We have fabricated three-dimensional magnetophotonic crystals based on $\alpha$-$SiO_2$ opal films. Opal thin films grown on glass substrates were filled with bismuth substituted iron garnet (Bi:YIG). Scanning electron microscopy data, optical and magnetic properties of the synthesized samples confirm the presence of the Bi:YIG contentin the opal lattice. It is shown that the samples exhibit the (111) stop band, and transmissivity of the threedimensional magnetophotonic crystals is defined by both the film lattice and the Bi:YIG content.

Multiple-Layered Colloidal Assemblies via Dipping Method with an External Electric Field

  • Im, Sang-Hyuk;Park, O-Ok;Kwon, Moo-Hyun
    • Macromolecular Research
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    • v.11 no.2
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    • pp.110-114
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    • 2003
  • When using the dipping method for crystal formation, mono-layered colloidal crystal structures depend upon the lift-up rate of a glass substrate. The mono-layered colloidal crystals showed the highest quality when the glass substrate was raised at a rate of 3 mm/min at 25 $^{\circ}C$ in a 1 wt% polystyrene colloidal suspension (ethanol medium). In addition, in order to obtain multiple-layered colloidal crystals, an external electric Held was introduced. Multiple-layered colloidal crystals were successfully obtained via this method. The colloidal particles were well ordered over large areas and assembled into a homogeneous structure.

Growth and Characteristic Infrared Raman Spectra of Potassium Lithium Niobate Single Crystals

  • Youbao Wan;Yoo, Sang-Im
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.15-15
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    • 2002
  • Homogeneous and crack-free potassium lithium niobate (K₃Li/sub 2-x/Nb/sub 5+x/O/sub 15/, 0<x<0.5, KLN) single crystals were successfully grown by the Czochralski technique. The KLN single crystals of several different compositions were employed for the investigation of the lattice vibration spectra using infrared Raman spectroscopy. The characteristic Raman spectra of the [NbO/sub 6/]/sup 7-/ octahedral ions were strikingly influenced by the Li ion content. The symmetric stretch vibrational modes V₁, V₂ are broadened, and the symmetric bend vibration mode V/sub 5/ is broadened and even split into three peaks with increasing the Li content, supporting that the bend vibration modes of the [NbO/sub 6/]/sup 7-/ octahedrons are obviously perturbed by Li ions in the C site. Enhanced Raman peak intensities after the post annealing at 900℃ and for 24 h evidenced that a residual stress in as-grown crystals was negligible and only a defect concentration might be reduced.

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Periodically Poled $KNbO_3$ Crystals for Quasi-Phase-Matching

  • Kim, Joong-Hyun;Lee, Sooseok;Yoon, Choon-Sup
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.18-18
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    • 2002
  • Although it was suggested in 1962 that an efficient wavelength conversion could be achieved using ferroelectric crystals of periodic 180° domains, it was not until 1990's that quasi-phase-matching (QPM) became realized, as technology for periodic poling of LiNbO₃ crystals was readily available. Since ferroelectric domain inversion brings about change of the sign of second-order nonlinear susceptibility, periodically poled ferroelectric structures provide an ideal way of achieving QPM for second-harmonic generation and optical parametric oscillation. Periodically poled ferroelectric domains can also be utilized for optical devices, such as Brags electrooptic modulators. fabrication of stable periodic domain structures depends on a number of poling parameters of a ferroelectric crystal, such as coercive field, internal field and electrical conductivity. We present poling kinetics of KNbO₃ crystals, which involve domain nucleation and growth, backswitching, relaxation of internal field. Optimum poling conditions were established by designing a proper wave shape of external field. We demonstrate an efficient second-harmonic generation using QPM in a periodically poled KNbO₃ crystal.

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Photoluminescence of Undoped and $Ho^{3+}-Doped ZnSe,\; Mg_{0.15}Zn_{0.85}$Se Single Crystals (ZnSe, $ZnSe:Ho^{+3}, Mg_{0.15}Zn_{0.85}Se\; 및 Mg_{0.15}Zn_{0.85}Se:Ho^{3+}$ 단결정의 광발광 특성에 관한 연구)

  • Kim, Nam-O;Kim, Hyeong-Gon;O, Geum-Gon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.9
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    • pp.434-437
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    • 2001
  • ZnSe, ZnSe:Ho/sup 3+/, Mg/sub x/Zn/sub 1-x/Se and Mg/sub x/Zn/sub 1-x/Se:Ho/sup 3+/ crystals were grown by the chemical transport reaction method. The crystal structures and optical energy band gaps of the single crystals were investigated. Their photoluminescence(PL) spectra were measured at 10 [K]. Sharp emission peaks in the blue-green wavelength range and broad emission peaks in the yellow-red wavelength range were observed. The single crystals doped with 1.0 [mol%] of holmium did not show the sharp emission peaks because of defects which were thought to be originated to the holmium dopant.

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Single Crystals Growth of Cubic Zirconia by Skull Method (Skull법에 의한 Cubic Zirconia 단결정 성장)

  • 김석호;최종건;오근호;조영환;김영준;오봉인;강원호
    • Journal of the Korean Ceramic Society
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    • v.25 no.2
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    • pp.161-167
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    • 1988
  • Yttria-Stabilized Cubic Zirconia Crystals with Various Y2O3 amounts (6-15mol%) were grown by the Skull melting technique. The modeling of the nucleation at the Skull bottom and the best growth condition were studied. The abrupt changes in generator heating Power and lowering rate of crucible caused the dendritic growth in the grown crystal. The optimum condition of cubic Zirconia single crystals was obtained when the lowering rate was gradually increased. The effect of Y2O3 amounts on the perfection adn the color of the grown crystal were determined. The darkish color generated in the crystals added Y2O3 amounts over 12mol% was eliminated by the annealing in air at 1200$^{\circ}C$ for 24hrs.

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Floating-Zone Growth of Single Crystal Olivine $[(Mg_{1-x}Fe}_{x})_2SiO_4]$ (Floating Zone법에 의한 올리빈 $[(Mg_{1-x}Fe}_{x})_2SiO_4]$단결정 성장)

  • 정광철;강승민;신재혁;한종원;최종건;오근호;박한수;문종수
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.3 no.1
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    • pp.85-92
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    • 1993
  • Large single crystals of olivine were grown by using image furnace(floating zone furnace)under controlled partial pressure of oxygen. The transparent crystals have maximum sizes 65mm in length by 7mm in diameter. When partial pressure of oxygen was decreased, the portion of secondary phases in crystals were increased so that it made crystals dark brown. The secondary phases were proved to be solid solution of Mg, Si, and Fe by electron microprobe analysis. Mg was major portion and the rest was minor.

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The modification of materials for flexible Dye-Sensitized Solar Cells

  • Kim, Chang-Ho;Han, In-Young;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1560-1563
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    • 2009
  • We fabricated Dye-Sensitized Solar Cells(DSSCs) which are modified by using liquid crystals(LCs) and electro-deposition on cathode electrode in order to apply to flexible DSSCs. We deposited Pt metal layers on ITO electrode through the method of electro-deposition process during low-temperature. We could expect the long-term stability by using ionic liquid(IL) and liquid crystals(LCs). We can also see the enhancement of efficiency through orientation of LCs in gel-state electrolyte using liquid crystals at the DSSCs.

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Temperature Dependence of Energy Gap and Thermodynamic Function Properties of Coblt-doped $Cd_4GeS_6$Single Crystals (Cobalt를 첨가한 $Cd_4GeS_6$ 단결정에서 Energy Gap의 온도의존성 및 열역학적 함수 추정)

  • 김덕태
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.9
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    • pp.693-699
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    • 1998
  • In this work $Cd_4GeS_6:Co^{2+}$(0.5mole%) single crystals were grown by the chemical transporting reactiov(CTR) method using high purity(6N) elements. The grown single crystals crystallized in a monoclinic structure(space group Cc). The direct optical energy gap of this single crystals was found to be 2.445eV at 300K and the temperature dependence of optical energy gap was fitted well to Varshni equation. But at temperatures lower than 70K an anomalous temperature dependence of the optical energy gap was obtained. This anomalous temperature dependence accored well with the anomalous temperature dependence of the unit cell volume. Also, the entropy, enthalpy and heat capacity were deduced from the temperature dependence of optical energy gaps.

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