• Title/Summary/Keyword: Crystalline polymer

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Studies on the Development of Hard Tennis Ball (경식 정구공의 품질 개량에 관한 연구)

  • Huh, Dong-Sub
    • Elastomers and Composites
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    • v.11 no.2
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    • pp.113-121
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    • 1976
  • Fundamental and specific properties of the tennis ball on rubber ball body are surveyed to match the quality of the tennis ball now on applied in the tennis game, 1. Much dose of filler of non-crystalline or flat form applied to rubber compounding than general procedure and over vulcanization is found excellent in the resistant to gas permeability. 2. Flat curing improved characteristics of the ball on the homogenous rebounds when applied on the specified concrete surface. 3. Satisfactory adhesive power is found with Desmodur R and standard rubber recipe in case of applying on the under-vulcanizate of half sphere. 4. The stable gas-generating compounds of sodiun nitrate, ammonium chloride, water and sodium carbonate, anhydorus help controlling of optimum internal over-pressure in the tall.

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A Highly Efficient Organic Light-Emitting Diode with an Imprinted In-Cell Polarizer for Backlight Applications

  • Lee, Won-Suk;Choi, Won-Suk;Lim, Yong-Woon;Na, Yu-Jin;Lee, Sin-Doo
    • Journal of Information Display
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    • v.9 no.4
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    • pp.11-14
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    • 2008
  • A highly efficient organic light-emitting diode (OLED) with an in-cell polarizer made of an imprinted liquid crystalline polymer (LCP) layer doped with dichroic dye molecules is presented. The in-cell polarizer was found to be capable of effectively polarizing the emission light of the OLED and of significantly improving the luminance through the periodic microstructures fabricated using an imprinting method. This type of OLED with an imprinted in-cell polarizer is useful for efficient light source applications in liquid crystal displays (LCDs).

The Effect of Extensional Flow on the Morphology of Polyblends Containing a Liquid Crystalline Polymer (액정고분자를 포함한 고분자 블렌드의 형구학적 성질에 대한 신장유동의 효과)

  • 조길원
    • The Korean Journal of Rheology
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    • v.9 no.3
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    • pp.111-117
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    • 1997
  • 대표적인 신장유동의 하나인 방사공정을 통해 액정고분자를 포함한 블렌드 섬유의 신장유동의 특성과 형구학적 성질간의 관계를 고찰하였다. 신장유동에 의해 분산상인 액정 고분자는 미세섬유구조를 바뀌었고 압출온도가 높을수록 더욱 발달된 미세섬유구조를 가졌 다. 이러한 분산상의 미세구조 변화에 대한 설명은 블렌드의 신장유동특성을 나타내는 신장 점도비로서 가능하였다. 즉, 압출온도가 높을수록 방사사선에서 신장변형률속도가 z지고 신 장점도비가 작아지므로 분산상의 신장변형이 더 많이 되었다고 판단된다. 방사이전의블렌드 내의 분산상은 압출온도를달리하여도 모두 구형으로 존재함을 발견하였고 이사실로부터 분 산상의 미세섬유구조는 방사사선에서의 신장변형에 의해 주로 이루어졌음을 확인하였다.

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Sturcture-Property Relationship of a Liquid Crystalline Polymer (액정중합체의 구조.물성관계)

  • 서문호
    • The Korean Journal of Rheology
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    • v.4 no.2
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    • pp.99-106
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    • 1992
  • 전방향족 폴리에스테르계 열방성 액정중합체(Vectra A-950)를 대상으로 유로가 확 장되는 다이로의 압출을 통하여 액정 섬유상의 배향 특성을 조사하고 이들이 기계적 특성에 미치는 영향을 살펴보았다, 다이의 확장 효과에 의하여 중심에서는 유동방향과 수직방향으 로 섬유상이 이중 배향되었으며 가장자리에서는 주로 유동방향으로만 배향이 일어났다. 그 리고 배향 특성은 두께방향으로 상하 대칭성을 갖는 바깥 영역과 중간영역으로 구별되었으 며 겉층은 유동방향으로 배향되고 속층은 중심에서 멀어지면서 배향각이 점진적으로 달라졌 다. 이런한 시편의 기계적 강도는 압출다이의 확장각이 증가하거나 스크류 속도가 증가함으 로 따라 유동방향이나 그 수직방향 모두 현저한 증가를 보였으나 파단신도는 유동방향은 감 소하고 수직방향은 증가하여 증가하여 결과적으로 거의 비슷하였으며 파단신도가 배향상태 를 가장 잘 반영하는 기계적 특성임을 알 수 있었다.

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PHOTOINDUCED PHASE TRANSITION BEHAVIOR OF LIQUID CRYSTALLINE COPOLYMERS CONTAINING AZO CHROMOPHORE

  • Kang, Suk-Hoon;Samui, Asit-Baran;Choi, Dong-Hoon
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.28-31
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    • 1998
  • Photoresponsive polymers are being intensely investigated over last two decades, which can be attributed to both fundamental and applied significance. Presently the attention is being directed to these materials in view of their possible application in nonlinear optics and optoelectronics. It was demnstrated quite early that by covalent fixation of both photochromic group and the mesogenic group to the same polymer main chain high concentration of photochromic group can be attained.(omitted)

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Reactive Mesogen Mixtures for Integrated Optical Films

  • Lee, Hee-Kyu;Lee, Seung-Eun;Cumming, S.A.;Verrall, M.;Parri, O.;Harding, R.;Marden, S.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.266-269
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    • 2003
  • TFT LCD mode has some well-documented performance limitations, namely limited viewing angle, inversion of the gray scale levels and poor luminance efficiency because of the necessity of using crossed polarisers attached to the display cell. During the last few years many initiatives have been undertaken to solve these problems by incorporation birefringent films of various designs into the LCD module. Controlling the optical performance of LCDs often requires combination of liquid crystal material properties, cell parameters and optical films. Such optical films have traditionally been made with stretched polymer materials such as polycarbonate, but recently coated liquid crystalline materials have been used to give improved optical films which can greatly enhance the performance of LCDs. We have now developed reactive mesogen materials to add ultra-thin optical layers into the display structure, and these allow the potential for many new applications.

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Liquid Crystal Alignment on Treated Surfaces

  • Chung, Doo-Han;Shioda, Tatsutoshi;Okada, Yoshinori;Park, Byoung-Choo;Takezoe, Hideo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1088-1091
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    • 2003
  • We have studied liquid crystal orientation on rubbed and photoaligned polymer surfaces. The following topics will be presented; (1) visualization of nonuniformity of rubbing, (2) competition between grooves and photoalignment and (3) alignment process of 5CB evaporated on treated surfaces. Through these topics, the importance of the intermolecular liquid crystalline interaction will be emphasized.

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Structural Properties of P(VDF-TrFE) LB Films (P(VDF-TrFE) LB박막의 구조특성)

  • Kwak, Eun-Hwi;Lee, Jin-Ho;Jung, Chi-Sup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.8
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    • pp.698-703
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    • 2009
  • We report the studies on the structrural properties of Langmuir Blodgett (LB) films fabricated from the copolymer of vinylidenefluoride (VDF) with trifluoroethylene(TrFE). The formation of nanomesas induced by thermal annealing at $135\;^{\circ}C$ for 1 hour was investigated with the atomic force microscope (AFM) and the X-ray diffractometer (XRD). From the result of surface morphology change in 30 monolayer LB film, we find that the annealing treatment on the P(VDF-TrFE) LB film result in the plastic deformation of crystalline polymer. The ${\beta}$ phase crytalline structure in annealed LB film was clearly confirmed from the XRD peak at $19.7^{\circ}$.

Odd-Even Effects of the Anchoring Strength for Nematic Liquid Crystal on Rubbed Polyimide LB Surfaces (러빙처리된 폴리이미드막 LB막에 있어서 네마틱액정의 결합강도의 홀수짝수 효과)

  • Seo, Dae-Shik
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1453-1455
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    • 1996
  • The odd-even effect of the alkyl chain length of rubbed polyimide Langmuir-Blodgett (LB) surfaces on the extrapolation length of 5CB has been successfully evaluated for the first time by measuring polar anchoring strength. The extrapolation length of 5CB for rubbed PI-LB surfaces with even-numbers is small compared with odd-numbers for alkyl chain lengths of greater than 7 carbons. The extrapolation length of 5CB on rubbed PI-LB surfaces with odd-numbers increases gradually as the temperature increases but tends to diverge near the clearing temperature (Tc=$35.3^{\circ}C$). The extrapolation length diverges because of rapidly decreasing surface order near $T_c$. We suggest that the polar anchoring strength on rubbed PI-LB surfaces with even-number is strong because of relatively high surface ordering caused by more crystalline surfaces. Finally, we conclude that the odd-even effects of the polar anchoring strength in NLCs are strongly related to the character of the polymer and observed clearly for long alkyl chain lengths.

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Shrinkage of Injection Molded Part for Inorganic Additive Compositions (무기 첨가물 함량에 따른 사출성형품의 성형 수축)

  • Kim B.D.;Yoo Y.H.;Hwang B.H.;Lyu M.Y.;Kim A.S.;Park S.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.10a
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    • pp.58-64
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    • 2004
  • The shrinkages of injection molded parts are different in molding operational conditions, resins and additives. The shrinkage of injection molded part for crystalline polymer, PBT (polybutylene terephthalate) has been studied for various operational conditions of injection molding and content of additives. Mica was used as a additive to PBT to examine the part shrinkage according to the mica content. The part shrinkages of mica contained PBT decreased as mica content increases. Higher injection temperature and injection pressure resulted in a lower shrinkage. As mold temperature increases the part shrinkage decreased. The part shrinkage of flow direction was less than that of the perpendicular direction to the flow for both pure and mica contained PBT. However the shrinkage difference between flow and perpendicular to flow directions decreased as mica content increased.

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