• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.419-422
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• 1998

There are lots of researches which are using quratz crystal in order to apply it to sensors, for example, mass detect sensor, humidity sensor, gas sensor, etc. We tried to apply quartz crystal to the sensor using the resonant frequency and the resistance properties. Four kinds of fatty acid which are having the same head group are coated at the surface of quartz crystal, the shift of the resonant frequency and the resistance are observed according to length of the tail group. Myristic acid$(C_{14})$, palmitic acid$(C_16)$, stearic acid$(C_{18})$, and arachidic acid$(C_{20})$ were coated by Langmuir-Blodgett(LB) technique. As results, the resonant frequency shift was observed linearly. However, there are some difference compared with Sauerbrey's equation. It can be explained by the effect of the temperature property and/or humidity. On the other hand, the shift of the resistance was observed nonlinearly.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.05a
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• pp.100-103
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• 2005

Homogeneously aligned nematic liquid crystal modes are representatively the -FFS (fringe-field switching) mode using liquid crystal (-LC) with negative dielectric anisotropy, the +FFS mode and the IPS (in-plane switching) mode using +LC with positive dielectric anisotropy. In view of image quality evaluation standard of LCD, we compared characteristics of the brightness, the contrast ratio (CR) and color shift when the modes have respectively optimized phase retardation values $(d{\Delta}n)$. Consequently, in the most sensitively viewing angle of a man's physical vision, both FFS modes have advantage over the IPS mode from the brightness & the CR point of view. We are also confirmed that the +FFS mode out of them shows the smallest color shift according to all viewing directions in grey levels.

• Current Photovoltaic Research
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• v.5 no.2
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• pp.43-46
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• 2017

Large absorption band shift has been observed for the azo-dye (disperse red-13, DR-13) attached on the surface of silica spheres. Urethane linkage has been utilized to form covalent bond between azo-dye (-OH) and 3-isocyanatopropyltriethoxysilane (ICPTES, -N=C=O). The synthesized ICPTES-DR-13 (ICPDR) molecules were attached to the silica spheres by the hydrolysis and condensation reaction. Although the absorption peak of DR-13 in methanol is at 510 nm, the absorption peak of the ICPDR-silica spheres shifts to 788 nm. The large absorption peak shift is due to the formation of intramolecular charge-transfer band with large aggregated ICPDR.

• Bulletin of the Korean Chemical Society
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• v.12 no.6
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• pp.618-625
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• 1991

A general expression adopting a nonmultipole expansion method is derived for pseudocontact contribution to the NMR chemical shift arising from the electron orbital angular momentum and electron spin dipolar-nuclear spin angular momentum interaction of $3d^9$ system in a strong crystal field of tetragonally distorted tetrahedral symmetry. From this expression all the multipolar term are determined and the exact solution of ${\Delta}$B/B(ppm) is compared with the multipolar term. The $1/R^5$ term in the multipolar terms contributes dominantly to the NMR chemical shift but the other terms are certainly significant except that of the <111> axis. In addition, an analysis of the temperature dependence of the NMR chemical shift further illustrates that considerable care must be taken in interpeting NMR results in paramagnetic system.

• Proceedings of the Korea Institute of Convergence Signal Processing
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• 2001.06a
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• pp.89-92
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• 2001

In this paper, as a study of programmable software radio digital communication, we implemented ASK(Amplitude Shift Keying), FSK(Frequency Shift Keying), and PSK(Phase Shift Keying) modulation using programmable software(algorithm) of DSP(Digital Signal Processor). Moreover, it is possible to select one of those three modulation methods by realizing on single DSP. We adopted Motorola DSP56002 and Crystal CS4215(A/D and D/A converter) for our purpose. The DSP56002 is 24-bit and operates 20 MIPS at 40 MHz, and the CS4215 is 16-bit and supports the maximum 50 kHz sampling frequency.

• Bulletin of the Korean Chemical Society
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• v.7 no.2
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• pp.89-96
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• 1986

The NMR chemical shift arising from 4d electron angular momentum and 4d electron spin dipolar-nuclear spin angular momentum interaction for a $4d^1$ system in a strong crystal field of octahedral symmetry, when the threefold axis is chosen as the quantization axis, has been investigated. A general expression using a nonmultipole expansion method is derived for the NMR chemical shift. From this expression all the multipolar terms are determined. We find that the nonmultipolar results for the NMR chemical shift ${\Delta}B$, is exactly in agreement with the multipolar results when $R {\ge} 0.20$ nm. It is also found that the 1/$R^7$ term contributes to the NMR chemical shift almost the same as the 1/$R^5$ in magnitude. The temperature dependence analysis of ${\Delta}B$/B(ppm) at various values of R shows that the 1/$T^2$ term has the dominant contribution to the NMR chemical shift but the contributions of other two terms are certainly significant for a $4d^1$ system in a strong crystal field of octahedral symmetry when the threefold axis is chosen to be the axis of quantization.

• Journal of the Korean Magnetic Resonance Society
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• v.10 no.1
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• pp.1-37
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• 2006

General expressions for solid state NMR lines are described for transitions under static, magic angle spinning, and variable angle spinning conditions in the case where the principal axis system for the anisotropic chemical shift tensor is noncoincident with that of the quadrupole coupling tensor. It is demonstrated that solid state NMR powder pattern simulation program VMAS based on the conventional grid point method of integrating over the Euler angle space is fast enough in comparison with the POWDER simulation package and Gauss-point method.

• Journal of Information Display
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• v.8 no.3
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• pp.17-21
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• 2007

We introduce a new electrode structure for the patterned vertical alignment (PVA) mode, which has a lower color-shift at large viewing angle than the one-domain VA mode. By manipulating the period of electrode structure, we can make more multi-domains and use the existing fabrication processes without having to use additional materials.

• Bulletin of the Korean Chemical Society
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• v.25 no.4
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• pp.529-532
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• 2004

Cesium-133 NMR spectra of a single crystal of tetragonal $Cs^+ (15-crown-5)_2I^-$ were obtained as a function of crystal orientation in an applied magnetic field of 9.40T and analyzed to provide the magnitudes and orientations of the $^{133}Cs$ chemical shift and quadrupolar tensors for two magnetically nonequivalent and symmetry related sites. Chemical shift tensor components and parameters of quadrupolar interactions are obtained as ${\delta}_{11}=46(1),\;{\delta}_{22}=60(1),\;{\delta}_{33}=-30(1)$ ppm, quadrupole coupling constant QCC = 581(1) kHz, and asymmetry parameter ${\eta}$ = 0.481(1), respectively. The nonaxially symmetric NMR parameters imply that the local environment of the cesium nuclei is nonaxially symmetric. The DANTE experiment burned holes in the $^{133}Cs$ NMR line of the title compound. The hole burning of the single crystal and powder $^{133}Cs$ NMR lines showed that the NMR lines are not homogeneously broadened.

• Industry Promotion Research
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• v.1 no.1
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• pp.1-6
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• 2016

To research the correlation between the amorphous and crystal structure of oxide semiconductors, AZO and IGZO films were deposited and annealed with various temperatures in a vacuum state. AZO increased the degree of crystal structure with increasing the annealing temperature, but IGZO became an amorphous structure after the annealing process at high temperature. The series of AZO films with various annealing temperatures showed the chemical shift from the analyzer of PL and O 1s spectra, but the results of IGZO films by PL and O 1s spectra were not observed the chemical shift. The binding energy of oxygen vacancy of AZO with a crystal structure was 531.5 eV, and that of IGZO with an amorphous structure was 530 eV as a lower binding energy.