• Title/Summary/Keyword: Crystal shape

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Thermal Stresses Near the Crystal-Melt Interface During the Floating-Zone Growth of CdTe Under Microgravity Environment (미세중력장 CdTe 흘로우팅존 생성에서 결정체-용융액 계면주위의 열응력)

  • Lee Kyu-Jung
    • Journal of computational fluids engineering
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    • v.3 no.1
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    • pp.100-107
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    • 1998
  • A numerical analysis of thermal stress over temperature variations near the crystal-melt interface is carried out for a floating-zone growth of Cadmium Telluride (CdTe). Thermocapillary convection determines crystal-melt interfacial shape and signature of temperature in the crystal. Large temperature gradients near the crystal-melt interface yield excessive thermal stresses in a crystal, which affect the dislocations of the crystal. Based on the assumption that the crystal is elastic and isotropic, thermal stresses in a crystal are computed and the effects of operating conditions are investigated. The results show that the extreme thermal stresses are concentrated near the interface of a crystal and the radial and the tangential stresses are the dominant ones. Concentrated heating profile increases the stresses within the crystal, otherwise, the pulling rate decreases the stresses.

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Powder synthesis and morphology changes of strontium barium niobate by molten salt method (용융염법에 의한 strontium barium niobate 분말 합성 및 분말의 형상 변화)

  • 윤상옥;박상엽
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.4
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    • pp.501-508
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    • 1996
  • Strontium barium niobate powders were prepared by NaCl-KCl molten salt, and reaction process and morphology change of strontium barium niobate were investigated as a function of reaction temperature, time, and amount of molten salt. With increasing the reaction temperature and time, the reacted fraction was increased and the morphology of powder was changed from lumpy shape into meedle-like shape. With increasing the amount of molten salt, reacted fraction was increased rapidly, but the morphology of powder was changed from needle-like shape into spherical shape. Strontium barium niobate powder, over 90 % in fraction reacted, was obtained from the reaction conditions at $1000^{\circ}C$ for small flux ratio (=1) and at $650^{\circ}C$ for large flux ratio (=4).

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Dislocation behavior in the ZnSe crystal (ZnSe 단결정내에서의 전위거동)

  • 이성국;박성수;김준홍;한재용;이상학
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.4
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    • pp.560-566
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    • 1997
  • Dislocation behavior in the ZnSe crystal grown by seeded vapor transport was investigated. Etch pit shape with the ZnSe plane and dislocation arrangement were shown. Also the variation of the dislocation density in the crystal was disclosed. The dislocation density along the lateral growth direction was not changed but the dislocation density along the vertical growth direction was reduced as the crystal grew. The average dislocation density of the grown crystal was $4{\times}10^4 /\textrm{cm}^2$.

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Comparison of numerical simulation and experiment for the OiSF-Ring diameter in czochralski-grown silicon crystal

  • Oh, Hyun-Jung;Wang, Jong-Hoe;Yoo, Hak-Do
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.5
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    • pp.356-361
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    • 2000
  • The radial position of OiSF-ring has been meaningful data in industry. Thus it's position was calculated by application of (V/G)/sub crit/ = 0.138 ㎟/minK and point defect dynamics for industrial scale grower with various pull rates. After the calculation, compared with experimental result. OiSF-ring diameters expected with calculation were good agreement with experimental results. In order to show validity of the predicted temperature distribution using STHAMAS which is one of the global simulator for Cz crystal growing, temperature was measured along the axis of crystal using thermocouples, and compared with the calculated temperature. We found the effective thermal conductivity K/sub m/ (r) which gives in accordance with the temperature distribution at the axis of crystal and crystal/melt interface shape between experimental and computational results. Therefore, effective thermal conductivity K/sub m/ (r) was applied instead of solving melt convection problem.

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Crystal growth from melt in combined heater-magnet modules

  • Rudolph, P.;Czupalla, M.;Dropka, N.;Frank-Rotsch, Ch.;KieBling, F.M.;Klein, O.;Lux, B.;Miller, W.;Rehse, U.;Root, O.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.5
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    • pp.215-222
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    • 2009
  • Many concepts of external magnetic field applications in crystal growth processes have been developed to control melt convection, impurity content and growing interface shape. Especially, travelling magnetic fields (TMF) are of certain advantages. However, strong shielding effects appear when the TMF coils are placed outside the growth vessel. To achieve a solution of industrial relevance within the framework of the $KRISTMAG^{(R)}$ project inner heater-magnet modules(HMM) for simultaneous generation of temperature and magnetic field have been developed. At the same time, as the temperature is controlled as usual, e.g. by DC, the characteristics of the magnetic field can be adjusted via frequency, phase shift of the alternating current (AC) and by changing the amplitude via the AC/DC ratio. Global modelling and dummy measurements were used to optimize and validate the HMM configuration and process parameters. GaAs and Ge single crystals with improved parameters were grown in HMM-equipped industrial liquid encapsulated Czochralski (LEC) puller and commercial vertical gradient freeze (VGF) furnace, respectively. The vapour pressure controlled Czochralski (VCz) variant without boric oxide encapsulation was used to study the movement of floating particles by the TMF-driven vortices.

Electro-optics of liquid crystals of bent-shape molecules

  • Jakli, A.;Fodor-Csorba, K.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1108-1111
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    • 2003
  • We consider geometrical conditions of liquid crystals of bent-shape molecules that result in optically isotropic antiferroelectric structure that can be reversibly switched to birefringent states. An example of an ester based banana-shape substance is discussed that almost fulfills the ideal conditions and provides fast electro-optical switching with or without crossed polarizers.

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Characteristics of Raman scattering spectroscopy for $ZnS_{1-x}Te_x$ alloy semi- conductor ($ZnS_{1-x}Te_x$ 삼원 화합물 반도체의 라만 산란 특성)

    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.5
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    • pp.223-228
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    • 2002
  • We have studied the characteristics of Raman scattering spectroscopy from $_ZnS{1-x}Te_x$ alloys in the whole range of Te composition x. The Raman spectra showed two-mode behaviors for those alloys. The Raman line shape showed the changes of an asymmetry and broadening of that with Te composition x. The asymmetric broadening of the line shape could be explained with a spatial correlation model.

Oriented Barium Titanate Ceramics Made from Fiber State Powder (섬유상 분말로 제조된 배향성을 가진 $BaTiO_3$ 세라믹)

  • 서용교;야나기다히로아끼
    • Journal of the Korean Ceramic Society
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    • v.30 no.12
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    • pp.1066-1070
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    • 1993
  • When looked upon as a polycrystalline, ceramics have two basic differences from a single crystal. One is that there exist grain boundaries, the other is that the crystal axes of each small crystal are arranged in random directions. But the crystal axes fo small crystals which compose ceramics may be made to have the tendency of being arranged in a specific direction. This is called that the crystal axes are oriented. The degree of the direction arrangement of the crystal axes is called orientation. In order to orient the crystal axes effectively, the fiberous barium titanates were made through KDC method and the ion exchange method. And then they were arranged through pressing, doctor blade, and syringe. As the result of Lotgering evaluation, the sample oriented through syringe showed the highest orientation. After sintering, though the most particles that had been fiberous shaped became global shape viewed through SEM, the orientation of the crystals was reinforced by means of sintering.

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Shape control of calcium carbonate prepared from shell resources (패각의 제조한 탄산칼슘의 형상제어)

  • 김판채
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.2
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    • pp.166-170
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    • 2000
  • Amorphous calcium carbonate was prepared by wet chemical method and performed the control of their shape using crystalline calcium carbonate that prepared from oyster shell by the $CO_2$ gas blowing method. As a result, amorphous calcium carbonate was obtained by the dissolution process of crystalline calcium carbonate in the dil-HC1 solution, mixing of sodium carbonate solution, precipitation and filtering with high speed. And using the amorphous calcium carbonate of mud type, crystalline calcium carbonates with cubic, needle, spindle, spherical and plate shape were obtained in the temperature rang of 2~$85^{\circ}C$ and reaction time range of 5~60 minute.

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