• Title/Summary/Keyword: Crystal orientation

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Effects of Gelatin Additives on the Microstructures and Corrosion Properties of Electrodeposited Cu Thin Films (젤라틴 첨가에 의한 구리 박막의 미세구조 변화 및 부식 특성)

  • Kim, Minho;Cha, Hee-Ryoung;Choi, Changsoon;Kim, Hae-sung;Lee, Dongyun
    • Korean Journal of Metals and Materials
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    • v.48 no.8
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    • pp.757-764
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    • 2010
  • We report on the effect of additives on the microstructure and corrosion properties of electrodeposited Cu films. Copper films were fabricated by electrodeposition on various concentrations of gelatin in a copper sulfate electrolyte. The surface morphologies of the Cu films were observed using a scanning electron microscope (SEM), and crystal orientation of the Cu films was analyzed by X-ray diffraction measurement. (220) plane was the dominant orientation when the films were fabricated at ambient temperature, decreasing in dominance with addition of gelatin. On the other hand, (111) plane-Cu films were preferentially grown at $40^{\circ}C$, and were also diminished with adding additives. Corrosion rate measurements using the Tafel extrapolation method based on corrosion potential and current reveal the effect of additives on corrosion behavior. Corrosion behavior was found to be strongly related to the orientation of the films. Consequently, additives like gelatin influence crystal orientation of the films, and if a less dense crystal plane, e.g. (220), is preferentially oriented during electrodeposition, a lower corrosion rate could be produced, since the plane shows a lower current density.

A Study on the Effects on Low Cycle Fatigue Life of a High Pressure Turbine Nozzle due to the Perturbation of Crystal Orientation of Grain of DS Materials (일방향 응고 재료의 결정립 성장 방향 섭동이 고압터빈 노즐 저주기 피로 수명에 미치는 영향에 대한 연구)

  • Huh, Jae Sung;Kang, Young Seok;Rhee, Dong Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.7
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    • pp.653-658
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    • 2016
  • High pressure components of a gas turbine engine are generally made of nickel-base superalloys, using precision casting process due to complicated geometries with intricate channels and cooling holes. Turbine components manufactured from directionally solidified and single crystal materials have columnar grains; however, it is found that the crystals do not grow in its preferred direction, although the orientation can be controlled. This anisotropy can lead to the variations of elastic and Hill's parameters in constitutive equations, and they alter stress distributions and the low cycle fatigue life. We aims to evaluate the effects of perturbed crystal orientations on the structural integrity of a directionally solidified nozzle using low cycle fatigue life. We also attempt to show the necessity for the control of allowed manufacturing errors and stochastic analysis. Our approaches included conjugate heat transfer and structural analysis, along with low cycle fatigue life assessment.

Effects of Annealing and Drawing on Crystal Structure and Supermolecular Structure of Poly (L-Lactide)

  • Sawade, E.;Irie, S.;Sasaki, T.;Sakurai, K.
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.97-97
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    • 2003
  • Recently, attention has been paid to biodegradable polymers in relation to the global environment. Poly-lactide (PLA) is one of such polymers and has studied by some investigators. In this study, the changes of crystal structure, crystal orientation and supermolecular structure of Poly(L-lactide) (PLLA) during drawing or annealing have been investigated.

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Thermotropic Liquid Crystal Polymer and PBT Blend

  • Lim, Sung-Tack;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.14-19
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    • 1998
  • Increasing demand for high modulus high strength polymeric materials have drawn considerable interest in industry. Thermotropic liquid crystal polymers (TLCP), differing from lyotropic liquid crystal polymers, have excellent melt processability and mechanical property resulting from the high degree of molecular orientation under a shear flow field in the molten state with relatively low viscosity$\^$1,2/.(omitted)

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Prediction of Rolling Texture Evaolution in FCC Polycrystalline Metals Using Finite Element Method of Crystal Plasticity (결정소성 유한요소법을 이용한 FCC 다결정 금속의 압연 집합조직 예측)

  • 박성준;조재형;한흥남;오규환
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.08a
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    • pp.313-319
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    • 1999
  • The development of deformation texture in FCC polycystalline metals during rolling was simulated by the finite element analysis using a large-deformation, elaatic-plastic, rate-dependent polycrystalline model of crystal plasticity. Different plastic anisotropy due to different orientation of each crystal makes inhomogeneous deformation. Assuming plane strain compression condition, the simulation with a high rate sensitivity resulted in main component change from Dillamore at low rate sensitivity to Brass component.

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Liquid Crystal Alignment on the Multiple Photo-treated Layers by the Interfered Laser Light

  • Lee, Eun-Kyu;Kim, Jong-Hyun
    • Journal of Information Display
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    • v.8 no.1
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    • pp.6-9
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    • 2007
  • Orientational alignment patterns have been proven to be that they are very useful for realizing diverse properties of liquid crystals. Here we produced the patterns combining interfered laser beams. A photo-isomerizable polymer including azo unit, which induces nematic liquid crystal alignment to the polarized laser light, was used as the alignment to layer. Double irradiations into two orthogonal directions brought the orientation patterns similar to the checkerboard. It indicates the possibility of bistability on those patterns.

Growth of Nd : YAl3(BO3)4 Single Crystal for Green Laser (녹색 레이저 발진용 NYAB 단결정 성장)

  • 최덕용;정선태;박승익;정수진
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.270-278
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    • 1995
  • Nd : YAl3(BO3)4 (NYAB) single crystal has been developed for green laser. In this experiment, we found K2O/3MoO3/0.5B2O3 to be a suitable flux for NYAB crystal growth, and grew NYAB crystal by TSSG method using this flux. By varying the cooling rate of solution, seed orientation, and rotation speed, the effects of these growth conditions on the crystal quality and its morphology were examined. Suitable growth conditiions were a cooling rate slower than 2.4$^{\circ}C$/day, the rotation speed of 25~30 rpm, and the <001> seed orienttion. The phases of grown crystal, coexisting and volatile materials were investigated by X-ray diffraction. In addition, the possiblity of laser action was examined by UV analysis.

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