• 제목/요약/키워드: Crude oils

검색결과 128건 처리시간 0.024초

Changes on the Nature of Crude Oil and Heavy Fuel Oil exposed on the Sea Surface (해상에서 원유 및 중유의 경시변화 특성연구)

  • 김영희;이창섭
    • 한국해양학회지
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    • 제20권1호
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    • pp.74-82
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    • 1985
  • Exposed on the sea, the oils are affected by the combined effects of evaporation, solution, chemical oxidation, and biological decomposition. Therefore the samples were taken after artificial weathering, and they were analyzed by gas chromatography for sulfur and hydrocarbons. The measurement results of gas chromatography have shown characteristic patterns. The peaks of the lower hydrocarbons in pollutant oil decreased with time. But the chromatograms for sulfur compound analysed by FPD showed little changes with lapse of time. The hydrocarbon and sulfur compound analysis by gas chromatography can be effectively used for analyzing oils for comparative identification.

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Production of Bioemulsifier from a Marine Bacterium Achromobacter sp. M-1220 (해양세균 Achromobacter sp. M-1220 균주를 이용한 생물유화제 물질의 생산)

  • 박중연;홍용기
    • Microbiology and Biotechnology Letters
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    • 제17권3호
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    • pp.252-256
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    • 1989
  • A marine bacterium which was isolated from the enrichment culture for the emulsification of Bunker-C oil produced a bioemulsifier potently. The strain identified as an Achromobacter sp. M-1220. The bioemulsifier was produced during mid-logarithmic phase in hexadecane oil medium at 18$^{\circ}C$. It appeared to be a cationic peptidolipid substance and showed an active stabilizing effect on the emulsion of crude oils and a few vegetable oils.

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$Einflu{\beta}$ der Extraktionsmethode und Losungsmittel auf einige Minorbestandteile in den rohen Olen und die Autoxydationsbereitschaft der Ole (추출 방법과 용매가 채종유 중 수종 미량성분의 그 자동산화능에 미치는 영향)

  • ;Artur Seher
    • Journal of Food Hygiene and Safety
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    • 제2권2호
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    • pp.83-88
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    • 1987
  • Effects of the extraction-methods and solvents on some minor components in crude rapeseed-oil and the autooxidation of the oils were examined in this study. The contents of unsaponifiable matters and sterols were not significantly variied depending on the extraction-methods and solvents. Chlorophyll-contents were elevated with the increasing molecular weights of extractionsolvents. Any significant effect of the extraction-temperature on the yield of chlorophyll was not observed. Autoxidation-tendency of the oils was found to be dependent on the boiling points of extraction-solvents.

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Volatile Flavor Constituents in the Rhizoma of Gastrodia elata (천마의 휘발성 향기성분)

  • Kim, Young-Kyoo;Lee, Jong-Won
    • Applied Biological Chemistry
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    • 제40권5호
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    • pp.455-458
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    • 1997
  • Crude oils in the rhizoma of fresh and dried Gastrodia elata were obtained by a simultaneous steam distillation and extraction(SDE) method using n-pentane/diethyl ether (1 : 1) as solvent, and their volatile constituents were analyzed by gas chromatography-mass spectrometry(GC/MS) A total of 39 volatile flavor constituents (11 acids, 13 alcohols,6 hydrocarbons,7 carbonyls,2 esters) and 25 constituents (6 alcohols, 13 acids, 4 hydrocarbons, 1 carbonyl, ester) were identified in the fresh and dried Gastrodia elate respectively. The major volatile components of the fresh and dried sample were hexadecanoic acid(66.78%, 50.72%), 9-hexadecenoic acid(8.07%, 9.58%), heptadecanoic acid(2.01%, 0.13%), pentadecanoic acid(6.41%, 4.94%), p-cresol(1.43%,0.52%) and cyclododecene(1.83%, 6.00%).

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Application of Clustering Methods for Interpretation of Petroleum Spectra from Negative-Mode ESI FT-ICR MS

  • Yeo, In-Joon;Lee, Jae-Won;Kim, Sung-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제31권11호
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    • pp.3151-3155
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    • 2010
  • This study was performed to develop analytical methods to better understand the properties and reactivity of petroleum, which is a highly complex organic mixture, using high-resolution mass spectrometry and statistical analysis. Ten crude oil samples were analyzed using negative-mode electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). Clustering methods, including principle component analysis (PCA), hierarchical clustering analysis (HCA), and k-means clustering, were used to comparatively interpret the spectra. All the methods were consistent and showed that oxygen and sulfur-containing heteroatom species played important roles in clustering samples or peaks. The oxygen-containing samples had higher acidity than the other samples, and the clustering results were linked to properties of the crude oils. This study demonstrated that clustering methods provide a simple and effective way to interpret complex petroleomic data.

The Oxidation Stability of Soybean, Palm Fish oil and Lard affected by Crude Gingerol (대두유. 팜유, 돈지 및 어유의 산화 안정성에 미치는 Crude gingerol의 영향)

  • 백숙은
    • Korean journal of food and cookery science
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    • 제9권4호
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    • pp.298-302
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    • 1993
  • The Crude ginerol from ginger was collected to investigate the possibility of application to food products as a natural antioxidant. The antioxidant activity of gingerols according to fatty acid composi-tion of several oils, were examined by measuring peroxide value(POV). The induction period(If) of fish oil, sdybean oil, lard and palm oil was 5.0, 17.0, 38.4 and 57.6 hours respectively by measuring POV during storge at $85^{\circ}C$. The relative antioxidant effectiveness(RAE) of gingerol group was lard ; 219, soybean oil; 176, fish oil; 160 and palm oil; 146%, while the RAE of'BHT group was lard; 238, palm oil; 158, soybfan oil; 132 and fish oil; 122%.

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Chemical Composition of Lutus Seed(Nelumbo nucifera Gaertner) and Their Lipid and Protein Composition (연밥의 유지와 단백질의 구성에 관한 연구)

  • Shin, Dong-Hwa;Kim, In-Won;Kwon, Kyoung-Soohn;Kim, Myoung-Sook;Kim, Mi-Ra;Choi, Ung
    • Journal of the Korean Society of Food Science and Nutrition
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    • 제28권6호
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    • pp.1187-1190
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    • 1999
  • Lotus seed(Nelumbo nucifera Gaertner), known as traditional medicine as an antifebrile, antipsychotic, and cantihypertensive agent, was analyzed the chemical composition of lipid and protein. The seed com posed of 12.2% moisture, 2.3% crude lipid, 19.5% crude protein, 61.3% carbohydrate, 2.1% crude fibre, and 4.1% ash. The lipid showed iodine value of 97.9 that is lower than that of soybean oil and sesame oil, and similar to peanut oil and cotton seed oil. The fatty acid composition of the oil were the highest in content of linoleic acid which occupied 58.3% and saturated vs unsaturated fatty acid was 20.9:79.1. Especially behenic acid content, 6.9%, was higher than other plant oils. Sixteen amino acids were detected in the protein from the seed and glutamic acid content was the highest as 4.5% in dehulled kernel. The portion of essential amino acid was 31.1%.

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Antibacterial Activity of Essential Oil from Abies holophylla against Respiratory Tract Bacteria

  • Lee, Su-Yeon;kim, Seon-Hong;Park, Mi-Jin;Lee, Sung-Suk;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • 제42권5호
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    • pp.533-542
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    • 2014
  • We extracted essential oils from four species (Pinus densiflora, Larix kaempferi, Pinus koraiensis, and Abies holophylla) in the family Pinaceae to investigate their antibacterial activities against respiratory tract bacteria (Klebsiella pneumoniae, Haemophillus influenzae, Streptococcus pyogenes, Streptococcus pneumonia, and Neisseria meningitides). Among the tested oils, that from A. holophylla was showed strong activity based on disc diffusion and broth medium dilution (minimum inhibitory concentration, MIC) assays. Qualitative analysis of A. holophylla oil was carried out by GC-MS; ${\alpha}$-pinene, camphene, ${\beta}$-pinene, 3-carene, limonene, bornyl acetate, borneol, ${\beta}$-caryophyllene, ${\alpha}$-caryophyllene, caryophyllene oxide, and ${\alpha}$-bisabolol were identified as its major constituents. Fractionation by silica gel chromatography was performed to analyze the active constituents of the crude oil. In particular, one fraction containing caryophyllene oxide as the major constituent showed stronger antibacterial activity than the crude oil of A. holophylla. Growth rates of bacterial strains exposed to fraction D were explored by optical density (OD600) measurements while morphology was examined by optical microscopy observations ( ${\times}1000$). OD600 of K. pneumoniae decreased from 0.2582 to 0.005 in response to treatment with fraction D at a MIC value of $0.31{\mu}{\ell}/m{\ell}$.

Total replacement of dietary fish oil with alternative lipid sources in a practical diet for mandarin fish, Siniperca scherzeri, juveniles

  • Sankian, Zohreh;Khosravi, Sanaz;Kim, Yi-Oh;Lee, Sang-Min
    • Fisheries and Aquatic Sciences
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    • 제22권4호
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    • pp.8.1-8.9
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    • 2019
  • A 12-week feeding trial was designed to evaluate the effect of total replacement of fish oil (FO) with terrestrial alternative oils on growth, feed utilization, body composition, hematological parameters, and fillet fatty acid profile of mandarin fish juveniles. Four iso-nitrogenous (56% crude protein) and iso-lipidic (13% crude lipid) practical diets were formulated. A control diet contained 6% FO and three other experimental diets were prepared by replacing FO with linseed oil, soybean oil, and lard (designed as FO, LO, SO, and lard, respectively). Each diet was randomly allocated to triplicate groups of 25 fish ($1.8{\pm}0.03g/fish$) in a circular tank. Complete replacement of FO by three tested alternative oils had no remarkable impact on growth performance, feed utilization efficiency, and morphological and hematological parameters of juvenile mandarin fish. However, daily feed intake was found to be significantly higher for fish fed the SO diet compared with those fed the FO and LO diets. Fish fed LO and SO diets exhibited significantly higher levels of the whole body lipid compared to fish fed diet containing FO. Fillet fatty acid composition reflected dietary fatty acid profile. The highest level of ${\alpha}$-linolenic acid, linoleic acid, and oleic acid was observed in fish fillet fed LO, SO, and lard, respectively. Although the eicosapentaenoic acid level of fish fillet fed diet FO was higher than other treatments, no significant difference was found in docosahexaenoic acid content among all dietary groups. The results of the present study clearly demonstrate that the complete replacement of FO in mandarin fish diets is achievable. These findings are useful in dietary formulation to reduce feed costs without compromising mandarin fish growth.

Chemical Compositions of Schizandra nigra Maxim. (흑오미자의 성분분석)

  • 현규환;김학진;신수철
    • Korean Journal of Plant Resources
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    • 제13권1호
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    • pp.35-40
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    • 2000
  • The results from the determination of contents of components in Schizandra nigra are as follows. The contents of malic acid and citric acid in Schizandra nigra was 38,691 and 3,330 ppm/dry weight 100g. The contents of total phenolic compounds in Schizandra nigra was 1.560%. The predominating phenolic acid was cinnamic acid, gentisic acid, coumalic acid, chlorogenic acid and ferulic acid. Contents of crude lipids in Schizandra nigra was 160.5mg/g. Most of fatty acid in lipids was oleic acid, linoleic acid and linolenic acid as a unsaturated fatty acid, and palmitic acid as a saturated fatty acid. In case of essential oils, The predominating components in Schizandra nigra was caryophyllene, calarene, cubebene, acoradiene and $\beta$-himachalene.

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