• 전기의세계
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• v.25 no.2
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• pp.100-106
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• 1976

A comparative study on thermal, static mechanical and dielectric characteristics were made over a temperature range of ca.20.deg.C to 320.deg.C and a frequency range of KHZ to MHZ band on low density polyethylene specimens crosslinked, respectively, by radiation and chemical method. The thermal property of both specimens shows that softening point appears to unchange by crosslinking, however, melting and liquidizing temperatures attain rapid increase at the imitiation of crosslinking. Mechanical properties show little difference to both specimens crosslinked by different method, further the behaviors were discussed in connection with the relaxation of molecular segments in amorphous phase. Dose dependent dielectric characteristics observed at ambient temperature under several fixed frequencies exhibit extremities at ca. 20 Mrad and the behaviors also were interpreted qualitatively by taking into consideration of dipole concentration change in amorphous phase together with the role of specimen geometry to the depth of oxidative layer. Observing frequency dependent dielectric characteristics, it was also proved that ionic conduction loss is appreciably greater in the specimen prepared by chemical method than that by radiation.

• Polymer(Korea)
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• v.31 no.1
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• pp.25-30
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• 2007

The characteristics of crosslinking and physical properties in partially crosslinked waste high density polyethylene (HDPE) were studied by introducing reactive melt processing with perbutyl peroxide (PBP). It was found that impurities in waste HDPE affected the crosslinking kinetics. Decrease in density and heat of fusion were observed in partially crosslinked HDPE while its melt viscosity increased. It was explained that impurities in waste HDPE enhanced the crosslinking compared to pure HDPE As a result, dramatic mechanical property improvement was achieved in the waste HDPE by crosslinking reaction.

• Textile Coloration and Finishing
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• v.22 no.3
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• pp.214-219
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• 2010

Polyethylene(PE) films were photocrosslinked by continuous UV irradiation. Benzophenone addition as low as 1wt% into the PE film increased the gel fraction up to 96%. The photocrosslinking was attributed to the recombination of PE radicals generated upon UV irradiation, which was enhanced by the hydrogen abstraction of the added benzophenone. Also the crossliked PE showed higher thermal stability and decreased crystallinity with increasing UV energy as shown by TGA, XRD and DSC analysis. It was also possible to fix 5.4% octadecane into PE by the photocrosslinking. The crosslinked PE film containing octadecane showed lower tensile strength and modulus coupled with higher extension compared to that without octadecane, which can be used as a new plasticizing method for the crosslinked PE film.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.49 no.8
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• pp.455-461
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• 2000

The inhibiting effects of electrical treeing and insulation properties of LDPE contained with treeing inhibitors was studied under radiation environment. Barbituric acid and its derivatives were selected as treeing inhibitors. The inception voltage and growth of tree, AC breakdown strength, volume resistivity, high frequency capacitance, and dissipation factor were observed as a function of dose(up to 1000 kGy). And also, measurements of thermo-luminescence(TL), and gel content were carried out. Crosslinked low density polyethylene(XLPE) contained with treeing inhibitors shows better insulation characteristics such as electrical tree propagation, AC breakdown strength, and volume resistivity than those of pure LDPE. The most effective treeing inhibitor was found on the barbituric acid contained XLPE.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.32 no.3
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• pp.107-114
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• 2022

Carboxymethyl cellulose/poly(ethylene glycol) (CMC/PEG) hydrogels crosslinked with citric acid (CA) are synthesized to evaluate the effect of CMC molecular weight (Mw), PEG and CA concentration on the optical property, swelling rate (SR), degradation rate (DR), and cytotoxicity and cell proliferation of hydrogels. For crosslinked CMC/PEG hydrogels, the FT-IR peak intensity associated with hydroxyl groups decreases due to PEG intercalation (esterification crosslinking) between CMC chains in a similar manner as the concentration of CA crosslinker increases. Crosslinked CMC (Mw = 90,000)/PEG hydrogels with 10 % CA dissolve regardless of PEG content. However, the SR of the CMC (Mw = 250,000)/PEG hydrogels decrease from 4923 % to 168 % with increasing PEG and CA concentrations from 0 to 20 % and from 0 to 25 %, respectively. As the Mw of CMC increases, the DR of the hydrogel is greatly improved. CMC (Mw = 250,000)/PEG10 hydrogels with 10 % CA exhibit the optimum properties of high absorbing capacity (3,200 %) with moderate DR (54 %), stiffness (1.39 ± 0.19 GPa), and cell viability (94.8 ± 1.3 %). CA-crosslinked CMC/PEG hydrogels are highly suitable for wound dressing or personal care applications due to their non-toxicity, good cell proliferation, SR, and mechanical properties.

• Applied Chemistry for Engineering
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• v.5 no.6
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• pp.1036-1043
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• 1994

The silane crosslinking method was applied for the crosslinking of polyethylene (PE). Crosslinking of PE was performed by, first grafting vinyltrimethoxysilane(VTMOS) to the main chain of PE using an extruder at $200{\sim}210^{\circ}C$, followed by exposure to three different silane crosslinking conditions (1. immersed in $80^{\circ}C$ water, 2. at $80^{\circ}C$ air forced convection oven, 3. exposed to air at room temperature ). The thermal characteristic changes of PE resins with respect to the silane crosslinking conditions were studied by measuring the crystalline melting temperature, density and crosslinking reaction rate. Because silane crosslinking was carried out at solid state, crystalline melting temperature, crystallinity, crystal growth rate, crosslinking reaction rate and the change in the density of silane crosslinked PE were affected by crosslinking condition and the type of base resin. The properties of silane crosslinked PE were different from those of Peroxide crosslinked PE which was crosslinked at the molten state. It was found, from the result of DSC analysis, that silane crosslinked linear low density polyethylene(LLDPE) crosslinked at room temperature had no secondary melting peak because the crosslinking reaction proceeds slowly as the crystalline grows. After crystallization, the melting point of PE was lowered by crystalline interruption of crosslinked site.

• Proceedings of the KIEE Conference
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• 1998.11c
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• pp.901-903
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• 1998

Crosslinked Degree is an important factor to determine dielectric property of crosslinked polyethylene(XLPE) used for the insulation material in power cables. Recently, though it is necessary to investigate electrical properties according to crosslinked degree as a part of the whole characterization of cable. it is not examined closely. In this study, crosslinked degree of samples were measured according to temperature and holding time of crosslinking, electrical tree characteristics of these samples were analyzed by crosslinked degree and applied temperature that was changed from normal temperature to operating temperature of power cables. As a result. when the crosslinked degree was low, dielectric properties were decreased and influence of temperature was increased. but the crosslinked degrees were high. initiation voltages of treeing were increased and dielectric properties were improved. It is proved that the optimum. crosslinked degree was one of most important factor for aging time and residual lifetime of power cable.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.215-218
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• 1998

XLPE/VLDPE (Crosslinked polyethylene/very low density polyethylene) blends were prepared by a twin screw extruder and their electrical properties such as water tree and breakdown characteristic were measured. it was found that both water tree and breakdown characteristics of XLPE were improved by the addition of VLDPE to polyethylene. It was also found that the extent of improvement of electrical properties by the addition of VLDPE to polyethylene depends on the type and concentration of VLDPE.

• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.88-92
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• 2012

Decrosslinking of crosslinked polypropylene(XLPP) in supercritical methanol was investigated compared with that of crosslinked polyethylene(XLPE). Effect of reaction temperature and initial gel contents was studied using a batch reactor. Gel contents of samples before and after reaction were measured for quantitative analysis. As reaction temperature and initial gel contents increased, the decrosslinking rate increased. The rate of decrosslinking reaction is dependent linearly on the gel contents. Experimental results indicated that the decrosslinking of XLPP was faster than that of XLPE, and it was confirmed quantitatively by the calculation of kinetic constants. In conclusion, it is considered that XLPP has better recyclability than XLPE.

• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.63-68
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• 2008

We investigated the recycling method to re-plasticize cross-linked polyethylene by using supercritical methanol. The cross-linked polyethylene is successfully fragmented to thermoplasticized polyethylene with little degradation reactions in supercritical fluids. The thermo-plasticization reaction was accelerated with increase in temperature in the range from $360^{\circ}C$ to $400^{\circ}C$, resulting in decrease in crosslinking density, molecular weight and mechanical properties. However, the thermoplasticized polyethylene at $360^{\circ}C$ showed comparable tensile strength and impact strength with a raw resin of crosslinked polyethylene. Chemical structure of main chain of polyethylene was not affected by reaction condition.