• 제목/요약/키워드: Cross-diffusion

검색결과 334건 처리시간 0.029초

Tapered 방향성 가중 결합 음향파 도파로 구조를 이용한 음향광학형 파장가변 광 필터에 관한 연구 (A Study on the Acousto-Optical Wavelength Tunable Filters Utilizing Tapered Directional Coupler SAW Guides)

  • 정기조;김정희;정홍식
    • 대한전자공학회논문지SD
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    • 제39권1호
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    • pp.58-66
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    • 2002
  • Tapered 방향성 가중 결합 음향파 도파로를 이용하여 음향광학형 파장가변 광 필터를 LiNbO₃와 Ti 이중 확산 공정 기술을 이용하여 제작하였다. 1551.1㎚ 파장의 TE, TM 입사 편광모드와 173.58㎒ 35㎽ RF구동 신호에 대해서 각각 -14.29㏈, -14.99㏈ 부 모드 억압과 61%, 86% 변환효율이 측정되었다. 파장변화율과 통과 대역폭은 8.6㎚/㎒ 1.8㎚로 측정되었으며, 스위칭 속도는 2.82㎲로 측정되었다. 2.5㎚ 채널 간격에 대해서 약 -l4㏈누화 레벨이 측정되었으며, 부 모드와 채널 간격이 누화에 매우 큰 영향을 미치고있음을 확인하였다.

인산염계 주형재와 치과주조용 Ti-Zr-Cr계 합금의 계면반응 (Surface Reaction between Phosphate bonded Investment and Ti-Zr-Cr based Alloy for Dental castings)

  • 정종현;주규지
    • 대한치과기공학회지
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    • 제27권1호
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    • pp.73-78
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    • 2005
  • The surface-reacted layer of titanium castings greatly affects their mechanical properties. This study analyzed the interfacial zone of Ti-20%Zr-5%Cr alloy castings obtained from phosphate bonded investment and examined the relationship between the surface-reacted layer and hardness. The Vickers hardness of cast disks were tested at 20$\mu m$ intervals from the surface to 120$\mu m$ in depth. The cross-section was observed metallurgically, and line profile of the reacted layer was conducted under the EDX. The surface-reacted layer of Ti-20%Zr-5%Cr alloy is showed a similar tendency to Ti-6%Al-4%V alloy in thickness, and also Si diffusion in multiple reacted layer of Ti-20%Zr-5%Cr alloy is less than cp Ti and similar to Ti-6%Al-4%V alloy. The Vickers hardness in the surface layer was greater than in the inner part, and the Vickers hardness of Ti-20%Zr-5%Cr alloy ranged 650 to 390 and cp Ti ranged 810 to 160, Ti-6%Al-4%V alloy ranged 710 to 530 respectively.

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고분자 전해질 연료전지 가스켓 및 GDL의 구조 해석 (Structural Analysis of Gasket and GDL for Enhanced Performance of PEMFC)

  • 윤진영;박정선
    • 한국항공우주학회지
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    • 제36권7호
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    • pp.642-650
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    • 2008
  • 고분자 전해질 연료전지 스택의 성능향상과 안전성 확보를 위하여 스택의 체결하중으로 인한 가스켓과 GDL의 구조적 거동을 살펴보았다. 가스켓 구조 해석의 경우 하중과 변위의 초탄성 거동을 표현하기 위하여 Mooney-Rivlin의 변형률에너지 함수를 사용하였으며, 재료물성을 구하기 위하여 단축 인장 및 등가 이축 인장 시험을 수행하였고 유한요소 해석과 비교하였다. GDL의 물성측정을 위하여 압축 하중의 변화에 따라 두께변화를 측정하였고 단위 셀을 제작하여 하중의 변화에 따른 채널의 압력차를 측정하였다. 실험 데이터를 바탕으로 채널 단면적의 변화를 계산, 유한요소 해석결과와 비교하였다.

Effects of prenatal cocaine exposure on the developing rat :Pharmacological and neurobehavioral studies

  • Park, Sun-Ju
    • 한국응용약물학회:학술대회논문집
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    • 한국응용약물학회 1996년도 제4회 추계심포지움
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    • pp.171-172
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    • 1996
  • Cocaine is a powerful reinforcer that has become a popular drug of abuse in man. CNS effects that are related to the abuse of cocaine include feeling of well-being and euphoria. Brain dopamine systems are thought to mediate reinforcement and it is often assumed that cocaine's inhibition of dopamine uptake is the mechanism underlying its reinforcing effects. With increase in cocaine use among general population in recent years, adverse effects of the drug have occurred in all social strata and age groups. Therefore, it has been recognized that the epidemic of cocaine abuse is a growing major concerning public health. One of the most troubling aspects of cocaine abuse is its use by pregnant women. Drug abuse during pregnancy puts two lives at risk. Cocaine produces toxic effects on the fetus at concerntrations that are apparently nontoxic to the mother. Not only does cocaine cross the placenta via diffusion and via rapid penetration to mucous membranes, due to its high lipid solubility, but cocaine can also be found in breast milk, the effects of the cocaine can persist long after the child is born. Although it is known that prenatal cocaine exposure is associated with developmental risk to the fetus ana newborn, few studies have been conducted to assess the mechanisms whereby either short-term or long-term administration of cocaine can exert its harmful effects on the mother or the child. Therefore, it was our great interest to investigate the pharmacological and neurobehavioral changes in offspring that are prenatally exposed to cocaine.

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0.5Tm 이하에서의 AZ31 마그네슘합금의 크리이프 변형과 단시간 파단수명예측 (Prediction of Creep Deformation and Short Time Rupture Life of AZ31 Magnesium Alloy below 0.5Tm)

  • 강대민;안정오;전성호;구양;심성보
    • 소성∙가공
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    • 제17권8호
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    • pp.558-563
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    • 2008
  • The initial strain, the applied stress exponent, the activation energy, and rupture time in AZ31 magnesium alloy have been measured in order to predict the deformation mechanism and rupture life of creep over the temperature range of 423-443K. Creep tests were carried out under constant applied stress and temperature, and the lever type tester and automatic temperature controller was used for it, respectively. The experimental results showed that the applied stress exponent was about 9.74, and the activation energy for creep, 113.6KJ/mol was less than that of the self diffusion of Mg alloy including aluminum. From the results, the mechanism for creep deformation seems to be controlled by cross slip at the temperature range of 423-443K. Also the higher the applied stress and temperature, the higher the initial strain. And the rupture time for creep decreased as quadratic function with increasing the initial strain in double logarithmic axis.

우레탄-아크릴레이트 올리고머의 광경화 거동 (Photopolymerization Kinetics of Urethane-acrylate Oligomer)

  • 김인범;송봉진;이명천
    • 공업화학
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    • 제17권1호
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    • pp.33-36
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    • 2006
  • 광경화 접착제로 많이 사용되는 우레탄-아크릴레이트 올리고머의 광경화 거동을 자체촉매화 반응모델식을 통해 중합온도 및 올리고머의 관능성에 따른 영향을 확인하여 보았다. 중합온도가 증가함에 따라 최대중합속도는 감소하여 중합온도가 경화 거동에 대한 영향인자임을 확인할 수 있었으며, 반응속도상수 k는 온도증가에 따라 거의 일정한 값을 보이나 반응차수 m과 n은 증가하는 경향을 보였는데 이는 가교구조에 의한 반응성 기의 확산제한 및 유동성의 제한으로 인한 것으로 판단되어진다. 온도증가에 따른 중합속도의 감소는 주로 반응차수 n의 증가에 의해 진행되었다.

Preparation and Characterization of Crosslinked Sodium Alginate Membranes for the Dehydration of Organic Solvents

  • Goo, Hyung Seo;Kim, In Ho;Rhim, Ji Won;Golemme, Giovanni;Muzzalupo, Rita;Drioli, Enrico;Nam, SangYong
    • Korean Membrane Journal
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    • 제6권1호
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    • pp.55-60
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    • 2004
  • In recent years, an increasing interest in membrane technology has been observed in chemical and environmental industry. Membrane technology has advantages of low cost, energy saving and environmental clean technology comparing to conventional separation processes. Pervaporation is one of new advanced membrane technology applied for separation of azeotropic mixtures, aqueous organic mixtures, organic solvent and petrochemical mixtures. Sodium alginate composite membranes were prepared for the enhancement of long-term stability of pervaporation performance of water-ethanol mixture using pervaporation. Sodium alginate membranes were crosslinked with CaCl$_2$ and coated with polyelectrolyte chitosan to protect washing out of calcium ions from the polymer. The surface structures of PAN and hydrolysed PAN membrane were confirmed by ATR Fourier transform infrared (FT-IR). A field emission scanning electron microscopy (FE-SEM; Jeol 6340F) operated at 15 kV. Concentration profiles for Ca in the membrane surface and membrane cross-section were taken by an energy dispersive X-ray (EDX) analyser (Jeol) attached to the field emission scanning electron microscopy (Jeol 6340F). Pervaporation experiments were done with several operation run times to investigate long-term stability of the membranes.

Process Performance and Bacterial Community Structure Under Increasing Influent Disturbances in a Membrane-Aerated Biofilm Reactor

  • Tian, Hailong;Yan, Yingchun;Chen, Yuewen;Wu, Xiaolei;Li, Baoan
    • Journal of Microbiology and Biotechnology
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    • 제26권2호
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    • pp.373-384
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    • 2016
  • The membrane-aerated biofilm reactor (MABR) is a promising municipal wastewater treatment process. In this study, two cross-flow MABRs were constructed to explore the carbon and nitrogen removal performance and bacterial succession, along with changes of influent loading shock comprising flow velocity, COD, and NH4-N concentrations. Redundancy analysis revealed that the function of high flow velocity was mainly embodied in facilitating contaminants diffusion and biosorption rather than the success of overall bacterial populations (p > 0.05). In contrast, the influent NH4-N concentration contributed most to the variance of reactor efficiency and community structure (p < 0.05). Pyrosequencing results showed that Anaerolineae, and Beta- and Alphaproteobacteria were the dominant groups in biofilms for COD and NH4-N removal. Among the identified genera, Nitrosomonas and Nitrospira were the main nitrifiers, and Hyphomicrobium, Hydrogenophaga, and Rhodobacter were the key denitrifiers. Meanwhile, principal component analysis indicated that bacterial shift in MABR was probably the combination of stochastic and deterministic processes.

각형 전기이중층 커패시터의 산업 안전성 (Industry safety characteristic of Prismatic EDLCs)

  • 김경민;장인영;강안수
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2004년도 춘계학술대회
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    • pp.247-257
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    • 2004
  • Electrodes were fabricated based on activated carbon powder BP-20, conducting agent such as Super P, vapor grown carbon fiber (VGCF) and acetylene black (AB), and the mixed binders of flexible poly(vinylidenefluoridehexafluoropropylene) [P(VdF-co-HFP)] and cross linking dispersion agent of polyvinylpyrrolidone (PVP) to increase mechanical strength. According to impedance measurement of the electrode with the addition of conducting agent, we found that it was possible to charge rapidly by the fast steady-state current convergence due to low equivalent series resistance (AC-ESR, fast charge transfer rate at interface between electrode and electrolyte and low RC time constant. The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. We found that the 2.3V/230F grade EDLC would be applied to industrial safety usage such as uninterrupted power supply (UPS) because of the constant DC-ESR by IR drop regardless of discharge current.

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抵溫에서의 固體 重合體의 力學的 에너지 緩和에 對한 線形反應 理論 (Linear Response Theory for the Mechanical Energy Relaxation of Solid High Polymers at Low Temperature)

  • 유병찬
    • 대한화학회지
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    • 제20권5호
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    • pp.340-350
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    • 1976
  • 글라스(glass) 전이온도 이하에서 고체 중합체들의 역학적 분광학의 여러 현상들을 이론적으로 기술하는 데 적용된 線形 반응 이론을 제안하였다. 시료에 의한 에너지 분산을 어떤 시간 相關函數들로 나타내었다. Liouville 연산자를 Kirkwood의 확산식 연산자로 대치하면, 여기에서 시간은 결과로부터 다리결합을 한 중합체들의 에너지 상실과 완화에 대한 Kirkwood의 결과가 나옴을 보였다. 완화시간을 계산하는 방법을 보이기 위하여 상관함수들을 계산하는 근사법을 고찰하였다. 여기에서 제안한 이론과 저온에서 매달린 (pendant) 시클로헥실기들을 가진 고체 중합체들의 역학적 에너지 완화 현상을 기술하는 데 사용된 한 모형 이론과의 관련성을 찾아 보기 위해, 이 근사법을 써서 二重우물 퍼텐셜 모형을 고찰하였다.

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