• Korean Journal of Environmental Agriculture
• /
• v.41 no.2
• /
• pp.95-100
• /
• 2022

BACKGROUND: This study was aimed to determine characteristics of residues of the soil-treated boscalid and pyraclostrobin within Hylomecon vernalis and to evaluate the risks from intake of the residual pesticides in the crop. METHODS AND RESULTS: The pesticides were treated to soils at two different concentrations, and the plant samples were collected 57 days after seeding. The samples were extracted using the QuEChERS extraction kit (MgSO₄ 4 g, NaCl 1 g). The quantitative methods for boscalid and pyraclostrobin were validated using linearity, recovery, and CV (coefficient of variation). Risk assessment of the pesticides was performed using Korea national nutrition statistics 2019. CONCLUSION(S): The residual levels of boscalid were 0.02-0.05 mg/kg (for the treatment at 6 Kg/10a) and 0.05-0.08 mg/kg (for the treatment at 12 Kg/10a), respectively. The residual concentrations of pyraclostrobin were below the LOQ. The amounts of pesticides were less than Maximum Residue Limits specified by the Korean Ministry of Food and Drug Safety. The maximum hazard indices of boscalid in chwinamul and amaranth for consumers were 0.0075% and 0.1525%, respectively, and it indicates that the risk of the pesticides from the crop is considered to be low.

• Korean Journal of Environmental Agriculture
• /
• v.36 no.4
• /
• pp.230-240
• /
• 2017

BACKGROUND: To evaluate residues of environmentally concerned pesticides in water system, this monitoring was conducted over three rivers. The residual characteristics and discharging condition of these residues on water system was investigated. METHODS AND RESULTS: Total twenty nine sampling sites were selected through main streams and branch streams of Keum, Mangyung and Dongjin rivers, and the water samples from them were regularly collected one month interval, especially biweekly from May to August in 2002. Of the pesticides monitored, six fungicides which include hexaconazole, isoprothiolane and iprobenfos were detected with frequencies of 0.3-50.9% and in their residue level of $0.1-4.7{\mu}g/L$. Sixteen insecticides which include nine organophosphoruses, three carbamates, endosulfan, cypermethrin, buprofezin and fipronil were detected with frequencies of 0.3-32.5% and in their residue level of $0.01-2.8{\mu}g/L$. Nine herbicides which include alachlor molinate, anilofos, butachlor, dimepiperate, metolachlor, oxadiazon, pretilachlor and thiobencarb were detected with frequencies of 0.8-22.9% and in their residue level of $0.01-9.07{\mu}g/L$. CONCLUSION: Detection frequencies and residue levels of insecticides and herbicides were the highest in waters sampled in May and June. Almost pesticides detected were for the paddy rice and their residue levels were very low to compare with standard values.

• The Korean Journal of Pesticide Science
• /
• v.8 no.3
• /
• pp.198-209
• /
• 2004

In order to elucidate the behavior of the fungicide hexaconazole in soil and rice plants, rice plants were grown for 42 days in a microecosystem (pot) containing fresh and 28 day-aged soil residues of $[^{14}C]$hexaconazole. The amount of $^{14}CO_2$ evolved during 28 days of aging was 0.11 % of total $^{14}C$-radioactivity treated and the averaged weekly degradation rate was 0.03%. Mineralization rates for 42 days of rice cultivation on fresh and aged paddy soils were 0.67% of the total $^{14}C$ in case of non-rice planting on aged soil and 1.17% in case of rice planting on aged soil, whereas 1.25% in non-rice planting on fresh soil and 1.72% in case of rice planting on fresh soil, suggesting that the amounts of $^{14}CO_2$ were evolved higher from fresh soils than aged ones and from rice-planting soils than non-planting ones. The amounts of volatiles collected were very low as background levels. Most of $^{14}C$-Radioactivity was remained in soil after 42 days of rice cultivation and $^{14}C$ absorbed through rice roots was distributed more in shoots than roots and translocated into the edge of shoots of rice plants. Amounts of non-extractable $^{14}C$ in soils were higher in rice planted soil than in non-planting soil. The distribution of non-extractable $^{14}C$ was increased in the order of humin>fulvic acid>humic acid. The amounts of $^{14}C$ translocated into rotational crop Chinese cabbage were 2.36 and 3.69% of the total $^{14}C$ in case of rice planted soil containing fresh and aged residues, respectively, suggesting that small amounts of $[^{14}C]$hexaconazole and its metabolite(s) were absorbed and their bound residues were more available than their fresh ones to Chinese cabbage.

• Korean Journal of Soil Science and Fertilizer
• /
• v.49 no.1
• /
• pp.7-11
• /
• 2016

Winter crops have been recognized as an alternative to soil management for fertility and crop productivity in paddy soil. Recently, rape has been produced at winter season and there is little research results on reduction of N fertilizer by adding rape residues for rice cultivation. In this study, we investigated the productivity and quality of rice by applying with 0, 27, 63, $90kg\;ha^{-1}$ of N fertilizer after input of rape residues into soil for two years. The highest yield of rice was average $4.68Mg\;ha^{-1}$ at the treatment applied with the $90kg\;N\;ha^{-1}$ with rape residue. It was reduced to N rate from 31.6 to $43.2kg\;N\;ha^{-1}$ in comparison to $4.53Mg\;ha^{-1}$ of maximum yield in treatment added $90kg\;N\;ha^{-1}$ with rape. Amylose content in rice was similar among treatments with/without rape residue, but protein content was lower in treatment with rape residue than in those without rape residue. In conclusion, input of rape residue in rice cultivation could be alternative to reduction of N fertilization and improvement of quality by adjusting rice productivity in paddy soil under cropping system.

• Korean Journal of Environmental Agriculture
• /
• v.42 no.3
• /
• pp.177-183
• /
• 2023

Rendering, is attracting attention as a technology that can stably and quickly process livestock carcasses. However, large amounts of livestock carcass solid residues are discharged in this process and limited methods are available for recycling them. In this study, rendered animal carcass solid residues were pyrolyzed to produce carbonized materials (350℃; RACR-C) and their chemical properties were investigated. Further, RACR-C were applied to cabbage cultivation for investigating their crop growth characteristics and soil improvement effects. RACR-C contained large amounts of fertilizer components such as nitrogen and phosphorus, and showed no toxic effects on the seedling growth of crops. The content of water-soluble nutrients released from RACR-C under the reaction time increased rapidly within 30 min, but was insignificant compared to the total content. Thus, most fertilizer components in RACR-C were not readily soluble in water. The optimal application amount for applying RACR-C to cabbage cultivation based on the changes in cabbage growth, inorganic content, and soil chemistry was 200 kg/10a. Overall, pyrolysis of solid residues after rendering livestock carcass to produce carbonized material as a soil improver is an effective method to recycle the waste discharged from the rendering process.

• Korean Journal of Environmental Agriculture
• /
• v.42 no.4
• /
• pp.427-434
• /
• 2023

Large amounts of organic wastes generated in agricultural environments such as crop residues and livestock manure adversely affect the environment. Anaerobic digestion can reduce the amount of organic wastes and convert them into energy at the same time. Efforts are being made to further increase the energy conversion efficiency by using co-anaerobic digestion using two or more substrates. Tomatoes, rice straw, cattle manure, and cattle feces (CF) were used as substrates for anaerobic digestion. Each substrate was subjected to anaerobic digestion and the cumulative biochemical methane production potential was measured, and the biodegradability was calculated. Based on the methane production, CF and tomato were further used for co-anaerobic digestion at different mixing ratios. Among the CF:tomato ratios of 1:1, 1:2, and 2:1, 1:2 produced the most methane and the synergy index was greater 1 indicating that the co-digestion of CF and tomato improved the methane production. Overall, the results showed that the methane production from cattle manure can be improved using tomato residues.

• Korean Journal of Weed Science
• /
• v.32 no.2
• /
• pp.107-114
• /
• 2012

This study was conducted to evaluate the weed suppressing effects of different cropping system including hairy vetch (Vicia villosa) and rye (Secale cereale) cover crops, polyethylene plastic film, and transplanting film mulching in direct sowing and transplanted sorghum field in 2011. Crop growth and development and weed occurrences in the fields were examined to know the efficiency of proposed cropping system. In polyethylene film mulching treatment, heading date of sorghum was earlier by 3 days than control, on the other hands, rye cover crop mulching delayed heading date by 11 days. Besides the effect of cover crop on the heading of sorghum, the residues changed growth characteristics. Plant height of sorghum was increased by 27.3% at hairy vetch treatment although it was reduced by 47.5% in the rye cover crop treatment. Hairy vetch treatment showed beneficial effects on sorghum growth reduced the occurrences of grasses and broadleaf weeds to 84% and 96%, respectively, as compared to control in sorghum fields. While rye cover crop treatment showed poor sorghum growth reduced less strongly grasses and broadleaf weeds by 35% and 71%, respectively. At harvest, yield of sorghum was greater in order of hairy vetch cover crop > polyethylene film mulching > rye cover crop ${\fallingdotseq}$ control in both transplanted and direct sown fields.

• Korean Journal of Environmental Agriculture
• /
• v.3 no.2
• /
• pp.1-8
• /
• 1984

The present study was performed to elucidate pesticide residues in paddy rice applied with different application schedules and frequencies of pesticide formulations. Pungsanbyeo($Japonica{\times}Indica hybrid$) of rice(Oryza sativa L.) was chosen as target crop. Isoprothiolane(diisopropyl-l,3-dithiolan-2-ylidene malonate) 40EC (emulsifiable concentrates), 12G (granular), and chlorpyriphosmethyl [0,0-dimethyl 0-(3,5,6-trichloro-2-pyridyl) phosphorothioate] 25EC, 3G were selected as pesticide formulations. The closer the isoprothiolane EC application to harvest, the higher the residues in rice straw retained at harvest; however the G application on 30 days before harvest resulted in highest residue. Chlorpyriphosmethyl residues were higher as it was applied nearby to harvest. Degradation rate of chlorpyriphos-methyl in husked rice was quite similar to in rice straw, on the other hand isoprothiolane in the rice was more stable than that in rice straw. Translocated amount of applied G formulation to husked rice was meager irrespective to the chemicals. Percent reduction of isoprothiolane residues in husked rice by polishing was not related to application frequencies but to application date before harvest. Residual portions in rice straw, husked rice and polished rice of total input amount during rice cultivation were ranged from 0.19% to 0.99%, 0.01% to 0.48%, and 0.15%, respectively.

• Korean Journal of Food Science and Technology
• /
• v.28 no.3
• /
• pp.490-496
• /
• 1996

This study was undertaken in order to elucidate the elimination of phenthoate residues by washing and cooking processes of rice which if the most important food crop in Korea. When contaminated rice was washed with distilled water three times, the removal rate of total phenthoate was 51%. The removal rate in the successive washings was 37.3% (wash filtrate 7.8%, wash sediment 29.5%) in the first, 14.3% (wash filtrate 6.2%, wash sediment 8.1%) in the second and 8.9% (wash filtrate 5.8%, wash sediment 3.1%) in the third washings. More than half of the residue was removed by the first washing and most residues were found in the sediment rather than in the filtrate of the rice washings. The residue rate of phenthoate after cooking by an electric rice cooker was 41%, indicating that the removal rate after cooking was 59%, because phenthoate is thermally stable at the cooking temperature. In conclusion, phenthoate residues contaminated in rice grains are grcatly removed in the washing process and it is desirable to wash the grains before cooking in order to decrease the hazards from pesticide residues such as phenthoate. Reduction factor of phenthoate in rice cooking is proposed to be 0.4.

• Korean Journal of Environmental Agriculture
• /
• v.37 no.2
• /
• pp.104-116
• /
• 2018

BACKGROUND: This experiment was conducted to establish a simultaneous analysis method for 7 kinds of herbicides in 3 different classes having similar physicochemical property as diphenyl ether(bifenox and oxyfluorfen), dinitroaniline (ethalfluralin and trifluralin), and chloroacetamide (metolachlor, pretilachlor, and thenylchlor) in crops using GC-ECD/MS. METHODS AND RESULTS: All the 7 pesticide residues were extracted with acetone from representative samples of five raw products which comprised apple, green pepper, Kimchi cabbage, hulled rice and soybean. The extract was diluted with saline water and directly partitioned into n-hexane/dichloromethane(80/20, v/v) to remove polar co-extractives in the aqueous phase. For the hulled rice and soybean samples, n-hexane/acetonitrile partition was additionally employed to remove non-polar lipids. The extract was finally purified by optimized Florisil column chromatography. The analytes were separated and quantitated by GLC with ECD using a DB-1 capillary column. Accuracy and precision of the proposed method was validated by the recovery experiment on every crop samples fortified with bifenox, ethalfluralin, metolachlor, oxyfluorfen, pretilachlor, thenylchlor, and trifluralin at 3 concentration levels per crop in each triplication. CONCLUSION: Mean recoveries of the 7 pesticide residues ranged from 75.7 to 114.8% in five representative agricultural commodities. The coefficients of variation were all less than 10%, irrespective of sample types and fortification levels. Limit of quantitation (LOQ) of the analytes were 0.004 (etahlfluralin and trifluralin), 0.008 (metolachlor and pretilachlor), 0.006 (thenylchlor), 0.002 (oxyfluorfen), and 0.02 (bifenox) mg/kg as verified by the recovery experiment. A confirmatory technique using GC/MS with selected-ion monitoring was also provided to clearly identify the suspected residues. Therefore, this analytical method was reproducible and sensitive enough to determine the residues of bifenox, ethalfluralin, metolachlor, oxyfluorfen, pretilachlor, thenylchlor, and trifluralin in agricultural commodities.