• Title/Summary/Keyword: Critical materials

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The humidity effect of YBCO film by TFA-MOD process (TFA-MOD법으로 제조된 YBCO 박막의 습도분압 효과)

  • Jang, Seok-Hern;Lim, Jun-Hyung;Yoon, Kyung-Min;Lee, Seung-Yi;Kim, Kyu-Tae;Lee, Chang-Min;Joo, Jin-Ho;Nah, Wan-Soo;Lee, Hee-Gyoun;Hong, Gye-Won
    • Progress in Superconductivity
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    • v.8 no.1
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    • pp.65-70
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    • 2006
  • We fabricated $YBa_2Cu_33O_{7-x}$(YBCO) films on(00l) $LaAlO_3$ substrates prepared by metal organic deposition(MOD) method using trifluoroacetate(TFA) solution and evaluated the effects of the humidity on the microstructure, phase purity, and critical properties. The films calcined at $430^{\circ}C$ were fired at $775^{\circ}C$ at 0%, 4.2%, 12.1%, and 20.0% humidified As gas mixed with 0.1% $O_2$. We observed that the amount of $BaF_2$ phase was effectively reduced and that a sharp and strong biaxial texture formed under a humidified atmosphere, leading to increased critical properties. For the films fired at 0% humidity, the $T_c\;and\;I_c$ were undetectably small. When the humidity was increased to 4.2%, the corresponding $T_c$(onset) and $I_c$ were increased to 90.5 K and 8 A/cm-width, respectively. For the films at the humidity range of 12.1-20.0%, the $I_c$ was found to be 35 A/cm-width. According to the results of the XRD, pole-figure, and SEM, these improved critical properties are probably attributed to the formation of a purer YBCO phase, larger grain size, and stronger c-axis orientation.

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Effect of Plasma Treatment on Mechanical Properties of Carbon Fibers-reinforced Composites (플라즈마 처리가 탄소섬유강화 복합재료의 기계적특성에 미치는 영향)

  • Oh, Jin-Seok;Lee, Jae-Rock;Park, Soo-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.80-83
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    • 2005
  • In this work, effects of oxygen plasma on surface characteristics of carbon fibers were investigated in mechanical properties interfacial of carbon fibers-reinforced composites. The surface properties of the carbon fibers were determined by acid/base values, FT-IR, and X-ray photoelectron spectroscopy (XPS). Also, the mechanical properties of the composites were studied in and critical stress intensity factor ($K_{IC}$) and critical strain energy release rate mode II ($G_{IIC}$) measurements. As experimental results, the $O_{lS}/C_{lS}$ ratio of the carbon fiber surfaces treated by oxygen plasma was increased compared to that of untreated ones, possibly due to development of oxygen-containing functional groups. The mechanical properties of the composites, including $K_{IC}$ and $G_{IIC}$ had been improved in the oxygen plasma on fibers. These results could be explained that the oxygen plasma was resulted in the increase of the adhesion of between fibers and matrix in a composite system.

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Influence of Magnesium Powder and Heat Treatment on the Superconducting Properties of $MgB_2/Fe$ Wires ($MgB_2/Fe$ 선재의 초전도성에 대한 열처리 조건과 Mg 분말의 영향)

  • Tan, Tan Kai;Kim, N.K.;Kim, Y.I.;Jun, B.H.;Kim, C.J.
    • Progress in Superconductivity
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    • v.9 no.1
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    • pp.1-4
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    • 2007
  • The most common technique to fabricate $MgB_2$ superconducting wire is by powder-in-tube (PIT) technique. Therefore, the starting powder for the processing of $MgB_2$ superconductors is an important factor influencing the superconducting properties and performance of the conductors. In this study, the influence of magnesium precursor powders and annealing temperatures on the transition temperatures ($T_c$) and critical current densities ($J_c$) of $MgB_2/Fe$ wires was investigated. All the $MgB_2/Fe$ wires were fabricated by in situ PIT process. It was found that higher $J_c$ was obtained for $MgB_2$ wires with smaller particle size of magnesium precursor powders. The $J_c$ also increases with decreasing annealing temperatures.

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Diffusion of CO2 Molecules in Polyethylene Terephthalate/Polylactide Blends Estimated by Molecular Dynamics Simulations

  • Liao, Li-Qiong;Fu, Yi-Zheng;Liang, Xiao-Yan;Mei, Lin-Yu;Liu, Ya-Qing
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.753-758
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    • 2013
  • Molecular dynamics (MD) simulations have been used to study the diffusion behavior of small gas molecules ($CO_2$) in polyethylene terephthalate (PET)/polylactide (PLA) blends. The Flory-Huggins interaction parameters (${\chi}$) determined from the cohesive energy densities are smaller than the critical value of Flory-Huggins interaction parameters (${\chi}_{critical}$), and that indicates the good compatibility of PET/PLA blends. The diffusion coefficients of $CO_2$ are determined via MD simulations at 298 K. That the order of diffusion coefficients is correlated with the availably fractional free volume (FFV) of $CO_2$ in the PET/PLA blends means that the FFV plays a vital role in the diffusion behavior of $CO_2$ molecules in PET/PLA blends. The slopes of the log (MSD) as a function of log (t) are close to unity over the entire composition range of PET/PLA blends, which confirmes the feasibility of MD approach reaches the normal diffusion regime of $CO_2$ in PET/PLA blends.

Studies on Cure Behavior and Thermal Stability of Epoxy/PMR-15 Polyimide Blend System (에폭시/PMR-15 폴리이미드 블렌드계의 경화동력학 및 열안정성에 관한 연구)

  • Lee, Jae-Rock;Lee, Hwa-Young;Park, Soo-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.265-268
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    • 2002
  • In this work, the blend system of epoxy and PMR-15 polyimide is investigated in terms of the cure behaviors and thermal stabilities. The cure behaviors are studied in DSC measurements and thermal stabilities are also carried out by TGA analysis. DDM (4, 4'-diamino diphenyl methane) is used as curing agent for EP and the content of PMR-15 is varied within 0, 5, 10, 35, and 20 phr to neat EP. As a result, the cure activation energy ($E_a$) is increased at 10 phr of PMR-15, compared with that of neat EP. From the TGA results of EP/PMR-15 blend system, the thermal stabilities based in the initial decomposed temperature (IDT) and integral procedural decomposition temperature (IPDT) are increased with increasing the PMR-15 content. The fracture toughness, measured in the context of critical stress intensity factor ($K_{IC}$) and critical strain energy release rate ($G_{IC}$), shows a similar behavior with $E_a$. This result is probably due to the crosslinking developed by the interactions between intermolecules in the polymer chains.

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$MgB_2$ Sheets using Mixture of Mg and B Powders by Powder Roll Compaction (Mg과 B 혼합분말을 이용하여 분말압연 공정으로 제조된 $MgB_2$ 초전도 판재연구)

  • Chung, K.C.;Chang, S.H.;Sinha, B.B.;Kim, J.H.;Dou, S.X.
    • Progress in Superconductivity
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    • v.13 no.3
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    • pp.184-188
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    • 2012
  • $MgB_2$ superconducting sheets have been fabricated by powder rolling method using mixture of Mg and B powders. Sheet-type $MgB_2$ bulk samples of ~10 mm width and 50-100 mm long were squeezed out after compacted by two rotating rolls of 130 mm diameter with gap distance of 0.5 mm and speed of ~40 cm/min (~1 rpm). The nominal composition of Mg, which is ductile metal, was added up to 30% to facilitate forming the $MgB_2$ sheets. The annealed samples at $900^{\circ}C$ and 3 hrs showed superconducting transition temperature of ~32 K and critical current densities at zero fields were ${\sim}10^5A/cm^2$ at 5 K and ${\sim}5{\times}10^4A/cm^2$ at 20 K.

Molten Salt-Based Carbon-Neutral Critical Metal Smelting Process From Oxide Feedstocks

  • Wan-Bae Kim;Woo-Seok Choi;Gyu-Seok Lim;Vladislav E. Ri;Soo-Haeng Cho;Suk-Cheol Kwon;Hayk Nersisyan;Jong-Hyeon Lee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.1
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    • pp.9-22
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    • 2023
  • Spin-off pyroprocessing technology and inert anode materials to replace the conventional carbon-based smelting process for critical materials were introduced. Efforts to select inert anode materials through numerical analysis and selected experimental results were devised for the high-throughput reduction of oxide feedstocks. The electrochemical properties of the inert anode material were evaluated, and stable electrolysis behavior and CaCu generation were observed during molten salt recycling. Thereafter, CuTi was prepared by reacting rutile (TiO2) with CaCu in a Ti crucible. The formation of CuTi was confirmed when the concentration of CaO in the molten salt was controlled at 7.5mol%. A laboratory-scale electrorefining study was conducted using CuTi(Zr, Hf) alloys as the anodes, with a Ti electrodeposit conforming to the ASTM B299 standard recovered using a pilot-scale electrorefining device.

Advances in Non-Interference Sensing for Wearable Sensors: Selectively Detecting Multi-Signals from Pressure, Strain, and Temperature

  • Byung Ku Jung;Yoonji Yang;Soong Ju Oh
    • Journal of Sensor Science and Technology
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    • v.32 no.6
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    • pp.340-351
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    • 2023
  • Wearable sensors designed for strain, pressure, and temperature measurements are essential for monitoring human movements, health status, physiological data, and responses to external stimuli. Notably, recent research has led to the development of high-performance wearable sensors using innovative materials and device structures that exhibit ultra-high sensitivity compared with their commercial counterparts. However, the quest for accurate sensing has identified a critical challenge. Specifically, the mechanical flexibility of the substrates in wearable sensors can introduce interference signals, particularly when subjected to varying external stimuli and environmental conditions, potentially resulting in signal crosstalk and compromised data fidelity. Consequently, the pursuit of non-interference sensing technology is pivotal for enabling independent measurements of concurrent input signals related to strain, pressure, and temperature, ensuring precise signal acquisition. In this comprehensive review, we present an overview of the recent advances in noninterference sensing strategies. We explore various fabrication methods for sensing strain, pressure, and temperature, emphasizing the use of hybrid composite materials with distinct mechanical properties. This review contributes to the understanding of critical developments in wearable sensor technology that are vital for their ongoing application and evolution in numerous fields.

A Study on Detection of a Critical Spot and the Securing Safety Method of CFRP Bicycle Forks by Finite Element Method (유한요소법을 이용한 CFRP 자전거 포크의 취약부 탐색 및 안전성 확보 방안 연구)

  • Lee, Su-Yeong;Lee, Nam Ju;Choi, Ung-Jae;Kim, Hong Seok;Shin, Ki-Hoon;Cheong, Seong-Kyun
    • Journal of the Korean Society of Safety
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    • v.31 no.6
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    • pp.1-5
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    • 2016
  • A bicycle is one of the most popular sporting goods in view of a sport activity and a human health. Metallic materials such as steel, aluminum, etc. were mainly used to the bicycle fork in the past. Nowadays, the carbon fiber reinforced composite materials are widely used to the manufacturing of a bicycle fork to reduce the weight and to increase the efficiency. Safety is a most important design parameter of a bicycle fork even if the weight and cost reduction are important. Bicycle failure may happen at the critical spot of a bicycle fork and cause the accident. In this paper, the composite bicycle fork will be analyzed to secure the safety and detect a critical spot by using the finite element method with Tsai-Wu failure criterion. The stress data were obtained for the laminated composites with various number of plies and fiber orientation under the bending load. Thus, design concept of a bicycle fork was proposed to secure the safety of a bicycle. The finite element analysis results show that the connection area between a steer tube and a fork blade is critical spot, and 75 or more layers of 0 degree are needed to secure the safety of a bicycle fork.