• Applied Chemistry for Engineering
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• v.20 no.6
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• pp.685-691
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• 2009

Dispersions of fumed silica are made in 6 kinds of mono-solvents and mixed solvents which have hydroxyl group, non hydroxyl group, different polarity, and different molecular size. The viscosity and rheology behaviors of the each dispersion are investigated according to the viewpoint of solvent characteristic. The silica dispersion in polar solvent with hydroxyl group is stable and low viscous sol. The silica dispersion in non-polar solvent with non-hydroxyl group is high viscous gel. When the solvent with hydroxyl group is added to the silica dispersions with non-polar solvents, they show the reduction of viscosity with solvent content. They have minimum critical content which shows no viscosity change. The minimum critical solvent content is decreased according to the polarity of solvents with no hydroxyl group. The solvation layer which is formed on the silica surface through hydrogen bonding between hydroxyl-containing solvent and the silanol group of silica surface is the reason of stable and low viscous sol. In case of non-polar solvent, silanol on adjacent silica particles interacted directly by hydrogen bonding show high viscous and flocculated gel.

• Journal of the Korean Society of Marine Environment & Safety
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• v.20 no.2
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• pp.172-178
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• 2014

This study suggests the minimum critical external forces based on the assessment of anchoring safety to single anchor situation for representative 8 number of ships in E-group anchorage of Ulsan port. Assessment of anchoring safety is compared holding powers of anchor with external forces of wind, wave and current. Holding powers was reflected materials of seabed, equipment numbers regarding anchor and chain weight, also external forces acting on a hull was calculated considering projected wind area and wetted surface area to the full and ballast conditions respectively. The results of anchoring safety assessments to single anchor showed that the minimum criteria of dragging anchor is a little different from ship's type, size and loading conditions. Bulk carrier can be dragged over the 15m/s of winds and Tanker can be dragged over the 13m/s of winds in case of less than 2knots of currents speed.

• Structural Engineering and Mechanics
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• v.66 no.5
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• pp.583-594
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• 2018

A theoretical formulation based on the linearized potential theory, the Descartes' rule and the extremum optimization method is presented to calculate the critical distance of lifting points of the fully balanced hoist vertical ship lift, and to study pitching stability of the ship lift. The overturning torque of the ship chamber is proposed based on the Housner theory. A seven-free-degree dynamic model of the ship lift based on the Lagrange equation of the second kind is then established, including the ship chamber, the wire rope, the gravity counterweights and the liquid in the ship chamber. Subsequently, an eigenvalue equation is obtained with the coefficient matrix of the dynamic equations, and a key coefficient is analyzed by innovative use of the minimum optimization method for a stability criterion. Also, an extensive influence of the structural parameters contains the gravity counterweight wire rope stiffness, synchronous shaft stiffness, lifting height and hoists radius on the critical distance of lifting points is numerically analyzed. With the Runge-Kutta method, the four primary dynamical responses of the ship lift are investigated to demonstrate the accuracy/reliability of the result from the theoretical formulation. It is revealed that the critical distance of lifting points decreases with increasing the synchronous shaft stiffness, while increases with rising the other three structural parameters. Moreover, the theoretical formulation is more applicable than the previous criterions to design the layout of the fully balanced hoist vertical ship lift for the ensuring of the stability.

• The Journal of Engineering Geology
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• v.19 no.3
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• pp.313-321
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• 2009

The relationship between precipitation and groundwater level and the correlation between the moving average of precipitation and goundwater level were analyzed for the Han river watershed in Korean peninsular. Fourteen regions in the watershed were selected and there were somewhat different patterns of seasonal fluctuation of groundwater level data. The groundwater level data tends to decrease in dry spell and increase in wet spell however the range between maximum and minimum values is quite different for each gauging point. We could have stronger correlation between groundwater level for fractured rock aquifer and the moving average of precipitation than the groundwater level for alluvial aquifer. The critical infiltration, which is the maximum daily infiltration averaged throughout watershed, value is turned out to have the range of 10 to 90 mm. We could have stronger correlation when we consider critical infiltration and modify the original precipitation data than we use original precipitation data. We also could have higher correlation coefficient when we consider snowmelt effect for the watershed that has considerable snow event.

• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.579-586
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• 2018

In this study, surfactants were synthesized using fatty alcohols of 8, 10, 12 and 14 carbon chains length. The structures of the synthesized surfactants was confirmed by FT-IR and $^1H$-NMR analysis. The surface tension of the diluted surfactant was measured as 26~32 mN/m depending on the carbon length and the critical micelle concentration was measured as $10^{-3}{\sim}10^{-5}mol/L$.The minimum value per molecule of the synthesized sulfonic acid surfactant is 1.68 to $1.30nm^2$. The physical properties of the synthesized surfactants were determined by measuring the critical micelle concentration, foaming power, emulsifying stability, and contact angle.

• Journal of Environmental Science International
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• v.16 no.4
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• pp.523-532
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• 2007

This study utilized the 1/25,000 topographic map of the upper area from the Geum-ho watermark located at the middle of Geum-ho river from the National Geographic Information Institute. For the analysis, first, the influence of the size of critical area to the hydro topographic factors was examined changing grid size to $10m{\times}10m,\;30m{\times}30m\;and\;50m{\times}50m$, and the critical area for the formation of a river to $0.01km^2{\sim}0.50km^2$. It is known from the examination result of watershed morphology according to the grid size that the smaller grid size, the better resolution and accuracy. And it is found, from the analysis result of the degree of the river according to the minimum critical area for each grid size, that the grid size does not affect on the degree of the river, and the number of rivers with 2nd and higher degree does not show remarkable difference while there is big difference in the number of 1st degree rivers. From the results above, it is thought that the critical area of $0.15km^2{\sim}0.20km^2$ is appropriate for formation of a river being irrelevant to the grid size in extraction of hydro topographic parameters that are used in the runoff analysis model using topographic maps. Therefore, the GIUH model applied analysis results by use of the river level difference law proposed in this study for the explanation on the outflow response-changing characters according to the decision of a critical value of a minimum level difference river, showed that, since an ogival occurrence time and an ogival flow volume are very significant in a flood occurrence in case of not undertow facilities, the researcher could obtain a good result for the forecast of river outflow when considering a convenient application of the model and an easy acquisition of data, so it's judged that this model is proper as an algorism for the decision of a critical value of a river basin.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.25 no.8
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• pp.575-579
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• 2012

Heteroepitaxial InP films have been grown on GaAs substrates to study the effects of the nucleation layer's surface roughness on the epitaxial layer's quality. For this, InP nucleation layers were grown at $400^{\circ}C$ with various ethyldimethylindium (EDMIn) flow rates and durations of growth, annealed at $6200^{\circ}C$ for 10 minutes and then InP epitaxial layers were grown at $550^{\circ}C$. It has been found that the nucleation layer's surface roughness is a critical factor on the epitaxial layer's quality. When a nucleation layer is grown with an EDMIn flow rate of 2.3 ${\mu}mole/min$ for 12 minutes, the surface roughness of the nucleation layer is minimum and the successively grown epitaxial layer's qualities are comparable to those of the homoepitaxial InP layers reported. The minimum full width at half maximum of InP (200) x-ray diffraction peak and that of near-band-edge peak from a 4.4 K photoluminescence are 60 arcmin and 6.33 meV, respectively.

• Journal of Power System Engineering
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• v.11 no.2
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• pp.51-57
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• 2007

As a shot sleeve in die casting plays a critical role in delivering molten metal to a die cavity, any disruption to its function in the injection stage results in deterioration of the quality of final castings. To guarantee a smooth operation of a shot sleeve, its structural stability should be maintained. Despite the simple geometry, design of shot sleeve is based on individual engineer's experience and no agreement on the design is present. In this study, we newly propose a systematic methodology to determine a minimum wall thickness of a shot sleeve to prevent yielding or plastic deformation. Analytical calculations incorporating numerical analysis produce a rational design rule for minimum thickness of a shot sleeve subject to metal intensification pressure and geometric die constraint. To validate the proposed design guideline, authors present real data on a collection of actual shot sleeves. Upon checking their conformity to the new design rule, we discovered a strong correlation between the design of wall thickness and premature failures.

• Structural Engineering and Mechanics
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• v.5 no.4
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• pp.415-431
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• 1997

Stability equations that evaluate the elastic critical axial load of stepped columns under extreme and intermediate concentrated axial loads in any type of construction with sidesway totally inhibited, partially inhibited and uninhibited are derived in a classical manner. These equations can be utilized in the stability analysis of framed structures (totally braced, partially braced, and unbraced) with stepped columns with rigid, semirigid, and simple connetions. The proposed column classification and the corresponding stability equations overcome the limitations of current methods which are based on a classification of braced and unbraced columns. The proposed stability equations include the effects of: 1) semirigid connections; 2) step variation in the column cross section at the point of application of the intermediate axial load; and 3) lateral and rotational restraints at the intermediate connection and at the column ends. The proposed method consists in determining the eigenvalue of a $2{\times}2$ matrix for a braced column at the two ends and of a $3{\times}3$ matrix for a partially braced or unbraced column. The stability analysis can be carried out directly with the help of a pocket calculator. The proposed method is general and can be extended to multi-stepped columns. Various examples are include to demonstrate the effectiveness of the proposed method and to verify that the calculated results are exact. Definite minimum bracing criteria for single stepped columns is also presented.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.7
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• pp.564-569
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• 2002

Heteroepitaxial GaN films were grown on sapphire substrates in order to study the effects of the buffer layer's surface roughness and thermal treatment on the epitaxial layer's quality. For this, GaN buffer layers were grown at $550^{\circ}C$ with various TMGa flow rates and durations of growth, and annealed at $1010^{\circ}C$ for 3 min after the temperature was raised by 23 ~ $92^{\circ}C/min$, and then GaN epitaxial layers were grown at $1000^{\circ}C$. It has been found that the buffer layer's surface roughness and the thermal treatment condition are critical factors on the quality of the epitaxial layer. When a buffer layer was frown with a TMGa flow rate of $24\mu mole/min$ for 30 sec, the surface roughness of the buffer lather was minimum and when the thermal ramping rate was $30.6^{\circ}C/min$ on this layer, the successively grown epitaxial layer's crystalline and optical qualities were optimized with a specular morphology. The minimum full width at half maximum(FWHM) of GaN(0002) x-ray diffraction peak and that of near-band-edge(NBE) peak from a room temperature photoluminescence (PL) were 5 arcmin and 9 nm, respectively.