• 접착 및 계면
• /
• 제4권1호
• /
• pp.1-8
• /
• 2003

본 연구에서는 이관능성 에폭시와 PMR-15 블렌드계의 접촉각 측정과 파괴인성 측정을 통하여 PMR-15 조성비에 따른 표면자유에너지가 기계적 계면특성에 미치는 영향에 대하여 고찰하였다. 블렌드계의 FT-IR 분석 결과, PMR-15의 이미드화에 따른 특성 밴드가 1,722, $1,778cm^{-1}$ (C=O)와 $1,372cm^{-1}$ (C-N)에서 나타났고, 에폭시의 개환 반응에 따른 -OH peak는 PMR-15 phr의 함량에서 가장 크게 나타나는 것을 확인할 수 있었다. 증류수와 diiodomethane을 젖음액으로 사용하여 sessile drop 방법으로 접촉각을 측정한 결과, 표면자유에너지는 극성 요소의 증가에 의해서 PMR-15의 함량이 10 phr일 때 최고값을 나타내었다. 또한, 기계적 계면특성을 파괴인성 측정을 통하여 알아본 결과 $K_{IC}$와 $G_{IC}$ 또한 표면자유에너지와 유사한 경향을 나타내는 것을 알 수 있었는데, 이는 PMR-15 10 phr의 조성에서 수소결합의 증가에 의한 블렌드계의 극성요소가 증가함에 따라 분자들간의 계면결합력이 증가했기 때문인 것으로 관찰된다.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2004년도 춘계학술발표대회 논문집
• /
• pp.182-185
• /
• 2004

In this work, the effect of chemical treatments on surface properties of SiC was investigated in mechanical interfacial properties of carbon fibers-reinforced composites. The surface properties of the SiC were determined by acid/base values and contact angles. The thermal stabilities of carbon fibers-reinforced composites were investigated by thermogravimetric analysis (TGA). Also, the mechanical interfacial properties of the composites were studied in interlaminar shear strength (ILSS) and critical strain energy release rate mode II $(G_{IIC})$ measurements. As a result, tile acidically treated SiC (A-SiC) had higher acid value than that of untreated SiC (V-SiC) or basically treated SiC (B-SiC). According to the contact angle measurements, it was observed that chemical treatments led to an increase of surface free energy of the SiC surfaces, mainly due to the increase of the specific (polar) component. The mechanical interfacial properties of the composites, including ILSS and $(G_{IIC})$, had been improved in the specimens treated by chemical solutions. These results were explained that good wetting played an important role in improving the degree of adhesion at interfaces between SiC and epoxy resin matrix.

• 한국안전학회지
• /
• 제33권2호
• /
• pp.8-13
• /
• 2018

The light weight composite materials have been replacing in high performance structures. The object of this study is to examine the effects of the initial crack location about a delamination in a PVC foam cored sandwich composite that is used for the strength improvement of structures. The initial crack location and fiber laminates thickness were changed with several types. The MMB specimen was used for evaluating the fracture toughness and crack behaviors. The material used in the experiment is a commercial twill carbon prepreg in CFRP material and Airex in PVC foam core. Sandwich laminate composites are composed by PVC foam core layer between CFRP face sheets. The face sheets were fabricated as 2 types of 5 and 8 plies. The initial cracks were located in a PVC form core and the interface of upper CFRP sheet. From the results, the crack initiation was affected with the location of the initial crack inserted in the PVC foam core. Among them, the initial crack at 1/3 of the upper part of the PVC foam core was the most rapid progression. And the critical energy release rate was $0.40kJ/m^2$, which is the lowest value when the initial crack was inserted into the interface between a PVC foam core and CFRP laminated with 5 plies. Meanwhile, the highest value of $1.27kJ/m^2$ was obtained when the initial crack was located at the center line in case of the 8 plies.