• Applied Chemistry for Engineering
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• v.27 no.3
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• pp.227-238
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• 2016

This review article highlights different types of nano-sized catalysts for the selective alcohol oxidation to form aldehydes (or ketones) with supported or immobilized metal nanoparticles. Metal nanoparticle catalysts are obtained through dispersing metal nanoparticles over a solid support with a large surface area. The nanocatalysts have wide technological applications to industrial and academic fields such as organic synthesis, fuel cells, biodiesel production, oil cracking, energy conversion and storage, medicine, water treatment, solid rocket propellants, chemicals and dyes. One of main reactions for the nanocatalyst is an aerobic oxidation of alcohols to produce important intermediates for various applications. The oxidation of alcohols by supported nanocatalysts including gold, palladium, ruthenium, and vanadium is very economical, green and environmentally benign reaction leading to decrease byproducts and reduce the cost of reagents as opposed to stoichiometric reactions. In addition, the room temperature alcohol oxidation using nanocatalysts is introduced.

• Journal of Korean Tunnelling and Underground Space Association
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• v.8 no.3
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• pp.259-271
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• 2006

This paper aims to predict the corrosion of a fully cement-grouted rockbolt induced by chloride diffusion in a cement mortar grout. From the viewpoint of the long-term durability, a rockbolt may be deteriorated by chemical components, such as sulphate and chloride, in groundwater. Especially, the steel rod of a rockbolt is corroded mainly by chloride. The rockbolt corrosion results in the volume expansion of a rod and then the cracking of a cement grout. In this study, the chloride diffusion coefficient of a cement mortar grout was used to evaluate the possibility of rockbolt corrosion by chloride, and to predict the long-term durability of a rockbolt. The electric acceleration test method was adopted to measure the chloride diffusion coefficient. In addition, a simple pullout testing system was newly proposed to measure the pullout capacity of a rockbolt more easily in a laboratory condition. From the experiments, it was showed that the chloride could diffuse in the cement grout more easily than in ordinary concrete materials. As a result, it was considered that a rockbolt might be easily corroded in a short term by the diffusion of chemical components with high concentration, although it was fully grouted.

• Clean Technology
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• v.12 no.3
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• pp.113-127
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• 2006

Waste lubricating oil(WLO)s have been recycled as energy source through direct fuel in cement kilns and fossil power plants, or as fuel oils, or re-refined lubricating base oils. In our country, they have been recycled as low grade fuel oil through chemical treatment process. In 2003, extended producer responsibility (EPR) system was adopted from deposit system on sale of lubricating oils in order to promote their recycleing rate. However, our recycling rate of WLOs have been stagnant(below 70%) for last 5 years. And there has been no research work on recycling of WLOs as re-refined base oil until now in this country. Stabilization technology of thermally cracked oils to reduce tar and malodor and to improve their color for production of high grade fuel oil, and a novel process production of high grade re-refined lubricating base oil from WLOs have been developed and commercialized recently in Canada and U.S.A., respectively. Several countries like Australia, Italy, Germany and U.S.A., etc. are encouraging recycling companies to recycle WLOs as re-refined lubricating oil by giving greater subsidies or benefits compared to other recycling methods. They also adopt a policy to purchase re-refined lubricating oil preferentially in the federal or local governments and to recommend consumers to purchase it willingly. Based on the facts that several advanced countries have adopted a policy to recycle WLOs as re-refined base oil for saving of petroleum resource and reduction of environmental pollution, it is right time to be considered that our present policy for recycling of WLOs should be reevaluated and the new policy of their environmental-friendly and sustainable recycling should be established.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.15 no.1
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• pp.95-104
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• 2002

A methods to calculate non-linear moment-curvature relations of high-strength PSC flexural members for numerical analysis has been proposed. The moment-curvature relations were calculated with assumptions of design codes and by the layer method. The results of the proposed procedures for moment-curvature relations and numerical analysis were compared with those of pre-existing tests. The absorption energy rate of the design codes was about 30% larger than that of the layer method. The ultimate load and the external work of the layer method were 90% and 85% of those of tests, respectively The ultimate load of the strength design method was 97% of that of tests, but the external work was over-estimated with 122%. The ultimate load and external work by the proposed equation of the CEB-FIP Model Code were 113% and 173% of those of tests, respectively. It show that the use of ultimate strain of 0.0035 should be over-estimated for high-strength concrete. The procedure of non-linear numerical analysis of this research could be stably simulated the behavior of concrete flexural members until the ultimate state, and calculate results of the load-deflection relation and cracking pattern were very similar with those of tests.

• Applied Chemistry for Engineering
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• v.19 no.6
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• pp.592-599
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• 2008

Oil sands had not received enough attention due to high production cost. However, as oil price significantly increases, oil sands are receiving more and more interest as unconventional crude oil. The value and applicability of oil sands can be enhanced by upgrading oil sands bitumen to produce synthetic crude oil (SCO). This study analyzed 213 oil sands upgrading patents applied between 1969 and 2006 in US, Canada, Japan, Europe, and Korea. The upgrading technologies could be classified into 9 detailed technologies; hydrocracking, coking, thermal cracking, deasphalting, supercritical technology, bio-technology, hydrotreating, gasification, and others. The number of patents applied for oil sands upgrading increased after 1970, reached a maximum in the early 1980, and slowly increases again in recent years. Korea has a lack of technologies for oil sands. Therefore, the technologies for oil sands production and application, specially, upgrading technologies based on accumulated oil refinery technologies need to be developed to increase self-development ratio of energy resource.

• Journal of the Korean Society for Nondestructive Testing
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• v.33 no.4
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• pp.368-375
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• 2013

Failure of small bore piping welds is a recurring problem at nuclear power plants. And the socket weld cracking in small bore piping has caused unplanned plant shutdowns for repair and high economic impact on the plants. Consequently, early crack detection, including the detection of manufacturing defects, is of the utmost importance. Until now, the surface inspection methods has been applied according to ASME Section XI requirements. But the ultrasonic inspection as a volumetric method is also applying to enforce the inspection requirement. However, the conventional manual ultrasonic inspection techniques are used to detect service induced fatigue cracks. And there was uncertainty on manual ultrasonic inspection because of limited access to the welds and difficulties with contact between the ultrasonic probe and the OD(outer diameter) surface of small bore piping. In this study, phased array ultrasonic inspection technique is applied to increase inspection speed and reliability. To achieve this object, the 3.5 MHz phased array ultrasonic transducer are designed and fabricated. The manually encoded scanner was also developed to enhance contact conditions and maintain constant signal quality. Additionally inspection system is configured and inspection procedure is developed.

• Journal of Korean Society of Steel Construction
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• v.28 no.1
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• pp.23-34
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• 2016

Concrete filled steel tube system has two major advantages. First, the confinement effect of steel tube improves the compressive strength of concrete. Second, the load capacity and deformation capacity of members are improved because concrete restrains local buckling of steel tube. It does, however, involve workability problem of using stud bolts or anchor bolts to provide composite effect for larger cross-sections. While the ribs inside the columns are desirable in terms of compressive behavior, they cause the deterioration in load capacity upon in-plane deformation resulting from thermal deformation. Since the ribs are directly connected with the concrete, the deformation of the ribs accelerates concrete cracking. Thus, it is required to improve the toughness of the concrete to resist the deformation of the ribs. Welding built-up tubular square columns can secure safety in terms of fire resistance if the problem are solved. This study focuses on mixing steel fiber in the concrete to improve the ductility and toughness of the columns. In order to evaluate fire resistance performance, loaded heating test was conducted with 8 specimens. The behavior and thermal deformation capacity of the specimens were analyzed for major variables including load ratio. The reliability of heat transfer and thermal stress analysis model was verified through the comparison of the results between the test and previous study.

• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.163-172
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• 2003

As concrete structures are getting larger, higher, longer, and specialized, it is more required to develop steel fiber concrete and apply to the real world. In this research, it is aimed to have fatigue strength examined, varying the steel fiber content by 0%, 0.75%, 1.00%, 1.25%, by experimental study of Two-spans Beam with Steel Fibrous with repeated loads. The ultimate load and the initial load of flexural cracking were measured by static test. In addition, the load versus strain relation, load versus strain relation, load versus deflection relation, crack pattern and fracture mode by increasing weight was observed. On the other hand, the crack propagation and the modes of fracture according to cycle number and the relation of cycle loading to deflection relation and strain relation was observed by fatigue test. As the result of fatigue test, Two-spans Beam without Steel Fibrous was failed at 60~70% of the static ultimate strength and it could be concluded that fatigue strength to two million cycle was around 67.2% by S-N curve. On the other hand, that with Steel Fibrous was failed at 65~85% of the static ultimate strength and it could be concluded fatigue strength to two million cycle around 71.7%.

• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.314-322
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• 2003

Pipe cooling method is widely used for reduction of hydration heat and control of cracking in mass concrete structures. However, in order to effectively apply pipe cooling systems to concrete structures, the coefficient of flow convection relating the thermal transfer between inner stream of pipe and concrete must be estimated. In this study, a device measuring the coefficient of flow convection was developed. Since a variation of thermal distribution caused by pipe cooling has a direct effect on internal forced flows, the developed testing device is based on the internal forced flow concept. Influencing factors on the coefficient of flow convection are mainly flow velocity, pipe diameter and thickness, and pipe material. Using experimental results from the developed device, the coefficient of flow convection was calculated. Finally, a general prediction model was proposed by theoretical procedures. The proposed prediction model is able to estimate the coefficient of flow convection with flow velocity and material properties of pipe. From comparison with experimental results, the coefficient of flow convection by this model was well agreed with those by experimental results.

• Journal of the Korea Concrete Institute
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• v.25 no.6
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• pp.631-639
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• 2013

Non-linear finite element analysis for newly developed precast concrete details for beam-to-column connection which can be used in moderate seismic region was carried out in this study. Developed precast system is based on composite structure and which have steel tube in column and steel plate in beam. Improving cracking strength of joint under reversed cyclic loading, joint area was casted with ECC (Engineering Cementitious Composites). Since this newly developed precast system have complex sectional properties and newly developed material, new analysis method should be developed. Using embedded elements and models of non-linear finite element analysis program ABAQUS previously tested specimens were successfully analyzed. Analysis results show comparatively accurate and conservative prediction. Using finite element model, effect of axial load magnitude and flexural strength ratio were investigated. Developed connection have optimized performance under axial load of 10~20% of compressive strength of column. Plastic hinge was successfully developed with flexural strength ratio greater than 1.2.