• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.2A
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• pp.297-304
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• 2008

It is well known that cracks in concrete decrease permeability and durability of concrete because cracks enhance the penetration of water or corrosive chemicals like as chlorides, carbon dioxides, sulfates and some others. But some of cracks in hardened cements may be sealed in case of contacting water. This phenomenon is called "self healing" and it has a close relation to hydration products newly formed on surfaces of cracks. Many studies on self healing in concretes commonly showed that CSH gel has been observed on crack surfaces. And some studies have reported that calcium hydroxides and ettringite were observed as well as CSH gel on crack surfaces. This study was carried out to investigate hydration products formed by self healing process and also examine the influence of waterproof admixture for concretes on self healing of cement. As a result of XRD, DSC, SEM and EDX analysis of crack surfaces, it was found that self healing of cement was related to CSH gel, calcium hydroxides and ettringite. And waterproof admixture increased fibrous (needle-like) hydration products which were in network form. It is estimated that such fibrous products are effective for self healing process of cement system.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.593-599
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• 2022

In this study, a crack monitoring system capable of detecting cracks based on image processing techniques was developed to effectively check cracks, which are the main damage of concrete structures, and a program capable of imaging and analyzing cracks was developed using machine vision. This system provides objective and quantitative data by replacing the appearance inspection that checks cracks with the naked eye. The verification of the development system was applied to the construction site of a self-healing concrete water tank to monitor the crack and the amount of change in the crack width according to age. In the case of crack width detected by image analysis, the difference from the measured value using a digital microscope was up to 0.036 mm, and the crack healing effect of self-healing concrete could be confirmed through the reduction of crack width.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.3
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• pp.84-89
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• 2018

Recently, study on self-healing materials have been performed to increase the life by repairing the damage of structures themselves, which are difficult to repair or require high maintenance costs. A water permeability test has been widely used for the evaluation of self-healing performance. However, in the self-healing performance test method, the initial crack width of the concrete greatly affects on the self-healing performance but it does not have a consistent standard. Therefore, in this study, the correlation between crack and permeability and that between time and permeability were analyzed based on crack width and permeability. In addition, since the initial crack width measured by optical microscope is not reliable, the value is derived from the Poiseuille flow and the tendency of time-permeability and time-crack width are analyzed.

• Elastomers and Composites
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• v.50 no.3
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• pp.167-174
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• 2015

Anionic epoxy compound was synthesized and added to asphalt aiming to prepare self-healing asphalt. Epoxy-modified asphalt showed excellent modification effect and healing effect as well. The results revealed that with 5% addition of polymer the tensile strength, impact strength and complex shear modulus of the polymer-modified asphalt increased by 65%. 64% and 35%, respectively. It seems that high interaction occurs between polymer and asphalt matrix. Self-healing efficiency of the polymer-modified asphalt based on tensile strength showed 100%, comparing to 79% of straight asphalt. In impact experiment the polymer-modified asphalt showed 99% of healing efficiency, comparing to 77% of straight asphalt. In rheological experiment the polymer-modified asphalt showed 103% of healing efficiency, comparing to 72% of straight asphalt. It appears that the ionic bonding existing in epoxy polymers contributed to high values of self-healing efficiency. The polymer which has high intermolecular force fills the crack of the asphalt, pulling the opponent side each other, and so the original properties were restored.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.1495-1498
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• 2003

Recently, self-healing methods of a cracked matrix, especially polymeric composite materials, became the center of engineering researchers. In this paper, we summarized the self-healing concept for polymeric composite materials and investigated the effect of microparticle on the crack growth behavior in colorless and transparent matrix by experimental observation to describe the crack propagation around the microparticle inside epoxy matrix composite. Compression splitting test for the specimen involving microparticle was conducted. In addition, FE analysis was pursued to present the stress contour around microparticle in the matrix. Through the experiments and FE analysis, we found that the size. relative position, bonding condition and relative stiffness of microparticle are important parameters to decide the direction of crack propagation, which is related to the rupture of microparticle for self-healing

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.600-608
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• 2022

This study investigates the effect of layered double hydroxide (LDH) on the healing performance of self-healing concrete by assessing the chloride penetration resistance of self-healing cement mortars using electrical chloride ion migration-diffusion test. Test results show that both mortars containing healing materials only and mortars containing healing materials and Ca-Al LDH together mostly had higher migration-diffusion coefficients right after cracking, but the migration-diffusion coefficients decreased more than that of OPC with increasing healing ages, and thus, they yielded higher healing capacities than OPC. Also, mortars containing Ca-Al LDH together with healing materials showed higher reduction of their migration-diffusion coefficients, and thus, higher healing capacities than mortars containing healing materials only. This suggests that as the self-healing product increases on the crack surface, the binding of chloride ions by LDH inside the crack increases.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2015.05a
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• pp.84-85
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• 2015

The aim of this study is to develop crack self-healing concrete and repair materials with the sulfate resistance using geo-materials and by-products for practical industrial application. Research has been done on the healing of cracks in aged concrete, but it seems that very little is known about the actual healing mechanism and its conditions. In this research, the essential properties of geo-materials with pozzolanic reaction for self-healing were analyzed and discussed.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.1
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• pp.67-73
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• 2020

In this study, the self-healing performance of mortar beams containing self-healing materials was evaluated through experiments. Normal mortar beams and self-healing mortar beams were used In the experiments. The self-healing performance was evaluated by comparing the mortar compressive strength, member strength, and self-healing effects of cracks. The experimental results showed that the compressive strength of mortar containing self-healing material was smaller than that of normal mortar, but the ratio of 118 days compressive strength to 28 days compressive strength was the same. The member strength tended to increase with increasing curing period. In normal mortar specimens, the member strength did not recover even if the curing period increased, but the strength of the self-healing mortar specimens tended to recover as reaction products were produced. The crack width tended to decrease after the healing periods in both specimens, but the reaction product was observed only in the self-healing mortar specimens.

• Polymer(Korea)
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• v.37 no.3
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• pp.356-361
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• 2013

Microcapsules of two different self-healing agents, 5-ethylidene-2-norbornene (ENB) and ENB with a crosslinker, surrounded by a melamine-urea-formaldehyde shell were manufactured. In this work, a red dye was incorporated into the self-healing agents as a tracer for better visual observations. It revealed that the incorporation of a red dye into self-healing agents did not disturb the formation of microcapsules from the examination of thermal resistance, particle size/size distribution and morphology of the resulting microcapsules. Releasing of self-healing liquid into the induced crack from ruptured microcapsules and filling between crack planes were observed using an optical microscope. Also observed was the reaction of filled healing agent with embedded Grubbs' catalyst in an epoxy coating layer.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.1
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• pp.59-66
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• 2020

In this study, self - healing solid capsules of crystal growth type which can be mixed directly with repair mortar were prepared, and the quality and crack healing performance of repair mortar with self - healing solid capsules were evaluated. The table flow and the air flow rate of the repair mortar material mixed with self-healing solid capsules were found to have no significant influence on table flow and air volume regardless of mixing ratio. Compressive strength tended to decrease with increasing capsule mixing ratio. As a result of evaluation of crack healing properties according to constant water head permeability test, initial water permeability decreased, and reaction products were generated over time and cracks were healed.