• Corrosion Science and Technology
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• v.8 no.4
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• pp.133-138
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• 2009

For the corrosion protection of the natural gas transmission pipelines, two methods are used, cathodic protection and coating technique. In the case of cathodic protection, defects are embrittled by occurring hydrogen at the crack tip or material surface. It is however very important to evaluate whether cracks in the embrittled area can grow or not, especially in weld metal. In this work, on the basis of elastic plastic fracture mechanics, we performed the CTOD testing with various test conditions, such as testing rate and potential. The CTOD of the base metal and the weld metal showed a strong dependence of the test conditions. The CTOD decreased with decreasing testing rate and with increasing cathodic potential. The morphology of the fracture surface showed the quasi-cleavage at low testing rate and cathodic overprotection. The low CTOD was caused by hydrogen embrittlement at crack tip.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.525-526
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• 2006

Calcium-hexaluminate phase $(CA_6)$ is known to be effective for the crack shielding due to the spinel block crystal structure. In this study, we focused to the control of $CA_6$ morphology for good damage tolerance behavior in alumina and zirconia/calcium-hexaluminate $(CA_6)$ composites. Calcium-hexaluminate $(CA_6)$ composites were prepared from zirconia, alumina and calcium carbornate powders. Calcium-hexaluminate $(CA_6)$ phase was obtained by the solid reaction through the formation of intermediate phase $(CA_2)$. $CA_6$ phase showed the column type abnormal grain grown behavior composed of small blocks. Due to the typical microstructure of $CA_6$, alumina and zirconia/calcium-hexaluminate composites provide a well controlled crack propagation behavior.

• Journal of the Korean institute of surface engineering
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• v.25 no.5
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• pp.263-269
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• 1992

To enhancing efficiency of hard chrome plating solution more highly, cathode current efficiency were surveyed connected with hardness of deposits, surface morphology, TEM analysis and corrosion test of anode materials. Efficiency war increased up to 26% values by adding catalyst and two kind of additives. With given bath composition and 6$0^{\circ}C$, 60A/d$\m^2$ electrolosis conditionss bright and micro cracked deposits were well obtained, which showed HV 1000 values. From corrosion tests, anode materials such as Pb-Te (0.02%) and Pb-Ag(1%) showed most anti-corrosive results. Through SEM micrograph observations, ef-fects of additives on levelling, brightness and micro crack properties of hard chrome deposits could be con-firmed. Also, through TEM analysis the fact that deposits from crack free solution or high speed solution were more fine than from sargent solution could be confirmed.

• Structural Engineering and Mechanics
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• v.76 no.4
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• pp.541-550
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• 2020

As a new type of concrete material, basic magnesium sulfate cement concrete (BMSC) has the advantages, such as early strength, high strength, good toughness and crack resistance. However, it is unclear about the degradation of the mechanical properties of BMSC columns, which is exposed to the natural environment for several years. In order to apply this new concrete to practical engineering, six large-eccentricity compressive columns of BMSC were studied. The mechanical properties such as the crack propagation, failure morphology, lateral displacement and bearing capacity of BMSC column were studied. The results show that the degradation rate of ultimate load of BMSC column is from 6% to 7%. The degradation rate of the stiffness of the column is from 6% to 13%. With the increase of compressive strength of BMSC, the axial displacement and lateral displacement are gradually reduced. The calculation model of bearing capacity of the BMSC column under the large eccentric compression is proposed. This paper provides a reference for the application of BMSC columns in the civil engineering.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.2
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• pp.380-386
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• 2002

Damage behaviors induced in silicon carbide by an impact of particle having different material and size were investigated. Especially, the influence of the impact velocity of particle on the cone crack shape developed was mainly discussed. The damage induced by spherical impact was different depending on the material and size of particles. Ring cracks on the surface of specimen were multiplied by increasing the impact velocity of particle. The steel particle impact produced larger ring cracks than that of SiC particle. In the case of high velocity impact of SiC particle, radial cracks were produced due to the inelastic deformation at the impact site. In the case of the larger particle impact, the damage morphology developed was similar to the case of smaller particle one, but a percussion cone was farmed from the back surface of specimen when the impact velocity exceeded a critical value. The zenithal angle of cone cracks developed into SiC material decreased monotonically with increasing of the particle impact velocity. The size and material of particle influenced more or less on the extent of cone crack shape. An empirical equation, $\theta$= $\theta$$\sub$st/, v$\sub$p/(90-$\theta$$\sub$st/)/500 R$\^$0.3/($\rho$$_1$/$\rho$$_2$)$\^$$\frac{1}{2}$/, was obtained as a function of impact velocity of the particle, based on the quasi-static zenithal angle of cone crack. It is expected that the empirical equation will be helpful to the computational simulation of residual strength in ceramic components damaged by the particle impact.

• Korean Journal of Metals and Materials
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• v.49 no.2
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• pp.112-120
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• 2011

The out-of-phase thermo-mechanical fatigue (OP TMF) in a <001> oriented single crystal nickel-based superalloy CMSX-4 has been studied. OP TMF life was less than a half of low cycle fatigue(LCF) life in spite of a small hysteresis loop area of OP TMF compared to that of LCF. The failure was caused by the initiation of a crack at the oxide-layered surface followed by its planar growth along the <100> ${\gamma}$ channel in both LCF and OP TMF. However, deformation twins appeared near the major crack of OP TMF. The multiple groups of parallel twin plates on {111} planes provided a preferential path for crack propagation, which caused a significant decrease in OP TMF life. Additionally, the analysis on the surface crack morphology revealed that the tensile strain at the minimum temperature of OP TMF was found to accelerate the crack propagation.

• Journal of the Korean institute of surface engineering
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• v.49 no.2
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• pp.111-118
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• 2016

A method to quantitatively analyze the defects formed by the hydrogen evolution during electroplating was suggested based on the theoretical approach of the small angle neutron scattering technique. In case of trivalent chrome layers, an isolated defect size due to the hydrogen evolution was about 40 nm. Direct and pulse plating conditions gave the average defect size of about 4.9 and $4.5{\mu}m$ with rod or calabash shape, respectively. Current density change of the pulse plating from $1.5A/dm^2$ to $2.0A/dm^2$ enlarged the average defect size from 3.3 to $7.8{\mu}m$. The defect morphology like rod or calabash was originated by inter-connecting the isolated defects. Small angle neutron scattering was useful to quantitatively evaluate defect morphology of the deposit.

• Journal of the Korean Society for Precision Engineering
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• v.3 no.1
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• pp.40-49
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• 1986

Crack, craze and void are common defects which may be found in the bulk of polymeric materials such as either themoplastics or thermosets. The healing phenomena, autohesion, of these defects are known to be a intrinsic material property of various polymeric materials. However, only a few experimental and theoretical investigations on crack, void and craze healing phenomena for various polymeric materials have been reported up to date [1, 2, 3]. This may be partly due to the complications of healing processes and lacking of appropriate theoretical developments. Recently, some investigators have been urged to study the healing phenomena of various polymenic materials since the significance of the use of polymer based alloys or composites has been raised in terms of specific strength and energy saving. In the earlier published reports [1, 2, 3, 4], the crack and void healing velocity, healing toughness and some other healing mechanical and physical properties were measured experimentally and compared with predicted values by utilizing a simple model such as the reptation model under some resonable assumptions. It seems, however, that the general acceptance of the proposed modeling analyses is yet open question. The crack healing processes seem to be complicate and highly dependent on the state of virgin material in terms of mechanical and physical properties. Furthermore, it is also strongly dependent on the histories of crack, craze and void development including fracture suface morphology, the shape of void and the degree of disentanglement of fibril in the craze. The rate of crack healing may be a function of environmental factors such as healing temperature, time and pressure which gives different contact configurations between two separated surfaces. It seems to be reasonable to assume that the crack healing processes may be divided in several distinguished steps like stress relaxation with molecular chain arrangement, surface contact (wetting), inter- diffusion process and com;oete healing (to obtain the original strength). In this context, it is likely that we no longer have to accept the limitation of cumulative damage theories and fatigue life if it is probable to remove the defects such as crack, craze and void and to restore the original strength of polymers or polymer based compowites by suitable choice of healing histories and methods. In this paper, we wish to present a very simple and intuitive theoretical model for the prediction of healed fracture toughness of cracked or defective polymeric components. The central idea of this investigation, thus, may be the modeling of behavior of chain molecules under healing conditions including the effects of chain scission on the healing processes. The validity of this proposed model will be studied by making comparisons between theoretically predicted values and experimentally determined results in near future and will be reported elsewhere.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.31 no.3
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• pp.133-140
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• 2018

This paper is concerned with the 2-D micostructure generation for $Ni-A{\ell}_2O_3$ dual-phase composite materials and the numerical analysis of mechanical characteristic of hierarchical models of microstructure which are defined in terms of the scale of microstructure. The microstructures of dual-phase composite materials were generated by applying the mathematical RMDF(random morphology description functions) technique to a 2-D RVE of composite materials. And, the hierarchical models of microstructure were defined by the number of Gaussian points. Meanwhile, the volume fractions of metal and ceramic particles were set by adjusting the level of RMD functions. The microstructures which were generated by RMDF technique are definitely random even though the total number of Gaussian points is the same. The randomly generated microstructures were applied to a 2-D beam model, and the variation of normal and shear stresses to the scale of microstructure was numerically investigated. In addition, through the crack analyses, the influence of RMDF randomness and Gauss point number on the crack-tip stress is investigated.

• Korean Journal of Metals and Materials
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• v.46 no.6
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• pp.329-337
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• 2008

During the continuous casting of boron-bearing steel, the corner cracks on the slab are formed by deformation with low strain rate and rapid cooling at the unbending temperature within the range of 800- $1000^{\circ}C$. Especially, the rapid cooling in the corner of slab during the continuous casting leads to as corner cracking. Therefore, in this study, the hot tensile tests applied to the different cooling rates were taken into account in order to study the effect of cooling rate on the hot ductility of boron-bearing steel. The results revealed that increasing cooling rate deteriorate the hot ductility of boron- bearing steel. Rapid decreasing of the hot ductility is caused by formation of a film-like ferrite and precipitate at the austenite grain boundaries. The morphology of the precipitates in the boron-bearing steel was monitored by PTA (Particle Tracking Autoradiography) and TEM, we observed MnS and BN compound and their morphology was quite different depending on the cooling rates. When the cooling rate is increased, rodshape MnS and BN precipitates can be formed along the austenite grain boundaries. It can cause that weakening the boundary region and decreasing the hot ductility of boron-bearing steel.