• Title/Summary/Keyword: Cr-Al alloy

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Wear Mechanism of CrN Coating on Aluminum Alloys Deposited by AIP Method

  • Kim, Seock-Sam;Suh, Chang-Min;Murakami, Ri-ichi
    • KSTLE International Journal
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    • v.3 no.1
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    • pp.43-48
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    • 2002
  • Dry sliding wear and friction test of CrN coaling on two types of aluminum alloy substrates,6061 Al and 7075 Al deposited by arc ion plating, was peformed with a ball-on-disk tribometer. The effects of normal Bead and the mechanical properties of substrate on the friction coefficient and wear-resistance of CrN coating were investigated. The worn surfaces were observed by SEM. The results show that surface micro-hardness of CrN- coated 7075 Al is higher than that of CrN-coated 6061 Al. With an increase in normal lead, wear volume increases, while the friction coefficient decreases. The friction coefficient of CrN-coated 6061 Al is higher than that of CrN-coated 7075 Al, while the wear-resistance of CrN-coated 6061 Al is lower than the CrN-coated 7075 Al's, which indicates that the substrate mechanical properties have strong inf1uences on the friction coefficient and wear of CrN coating. The main wear mechanism was fragments of CrN coating, which were caused by apparent plastic deformation of substrate during wear test.

Electrical Characteristic of Ni-Cr-Al-Cu Alloy Thin Film Resistors (Ni-Cr-Al-Cu계 박막저항의 전기적 특성)

  • 이붕주;차성익;김철수;한정인;김종택;이덕출
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.4
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    • pp.328-335
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    • 2001
  • In this work, we made the precision thin film resistors of NiCr alloy (74wt%Ni-f18wt%Cr-4wt%Al-4wt%Cu) using DC/RF magnetron sputtering method and studied the sheet resistance and TCR(Temperature Coefficient of Resistance) etc... of the Ni-Cr-Al-Cu alloy thin film according to the change by annealing treatment to 400$\^{C}$ in air and nitrogen atmosphere and the change(power, pressure, substrate temperature) of sputtering process.

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Creep Characteristics of Ti-6Al-4V Alloy Surface Modified by Plasma Carburized/CrN Coating (복합처리(Carburized/CrN Coating)로 표면개질된 Ti-6Al-4V합금의 크리프 특성)

  • Park, Yong-Gwon;Park, Jung-Ung;Wey, Myeong-Yong
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.3
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    • pp.183-189
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    • 2005
  • The effects of duplex-treatment of plasma carburization and CrN coating onto Ti-6Al-4V alloy on its creep properties were investigated by means of a constant stress creep tester. Applying duplex-treatment, specimens having an inner carburized layer of about $150{\mu}m$ in depth and outer CrN layer of about $7.5{\mu}m$ in thickness were prepared. The hardness of duplex-treatment surface was about 1,960 VHN. It also appeared that the duplex-treatment improved the roughness of the surface significantly; $Ra=0.045{\mu}m$ for treated alloy while $Ra=0.321{\mu}m$ for untreated alloy. The steady-state creep behaviors were investigated in a temperature range of $510{\sim}550^{\circ}C$ ($0.42{\sim}0.44T_m$) under an applied stress range of 200~275 MPa. The stress exponent, n, was derived assuming the power law creep behavior. The surface treatment showed a decrease in a value from 9.32 (untreated) to 8.79 (treated). Also the activation energy obtained from an Arrhenius plot increased from 238 to 257 kJ/mol.

A Study of Thermodynamical Reaction Path in Fe-Cr-X Alloys at High Temperature Corrosion Environments (고온 부식환경에 대한 Fe-Cr-X 합금의 열역학적 반응경로에 관한 연구)

  • Lee, Byung-Woo;Kim, Woo-Yeol
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.32 no.4
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    • pp.411-420
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    • 1996
  • The structure of the scale formed on the surface of Fe - Cr - X alloys exposed to 1143K high sulfidation($Ps_2$ = 1.11$\times$$10^-7$ atm, $Po_2$ = 3.11$\times$$10^-20$ atm) or sulfidation/oxidation(($Ps_2$= 1.06$\times$$10^-7$ atm, ($Po_2$ = 3.11$\times$$10^-18$ atm) environment has been observed and analysed using XRD, SEM/EDS. To investigate the possibility of protective film formed on the surface of the alloys, Aluminium, Nickel were selected as alloying elements. Thermodynamic phase stability diagram was used to predict the reaction path of scale formed on Fe - Cr - X alloys. Parabolic rate constant($K_p$) value with 6wt% Al in Fe - 25Cr alloy decreased significantly compared with the Fe - 25Cr alloy without 6wt% Al. Since thin layer of defect free sulfide film, (Al, Cr)Sx, was formed at the alloy/scale interface. Fe - rich sulfide scale at outer layer and Cr - rich sulfide scale containing porosity at inner layer of Fe - 25Cr alloy have been observed. The reaction path for these scales could be predicted by the thermodynamic stability diagram.

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Effect of Al and Cr contents on the High Temperature Oxidation- and Sulfidation-resistance of Fe Alloys (Fe합금의 내 산화성과 황화성에 미치는 Al과 Cr 함량의 영향)

  • Kim, Seul-Ki;Lee, Dong-Bok
    • Journal of the Korean institute of surface engineering
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    • v.45 no.2
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    • pp.61-69
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    • 2012
  • Alloys of Fe-(5, 10, 15)Al and Fe-(10, 20, 30, 40)Cr were corroded at 700 and $800^{\circ}C$ for 70 hr in either atmospheric air or 1 atm of Ar+$1%SO_2$ gases. In these atmospheres, Fe-5Al and Fe-10Cr alloys displayed poor corrosion resistance. In atmospheric air, Fe-5Al alloys formed oxide nodules, while Fe-10Cr alloys formed thick scales and internal oxides. In Ar+$1%SO_2$ gases, Fe-5Al and Fe-10Cr alloys formed thick, nonadherent bi-layered scales, which grew primarily by the outward diffusion of Fe ions and inward diffusion of oxygen and sulfur ions. By contrast, in atmospheric air and Ar+$1%SO_2$ gases, Fe-(10, 15)Al and Fe-(20, 30, 40)Cr alloys displayed good corrosion resistance by forming $Al_2O_3$ and $Cr_2O_3$ layers on the surface, respectively.

The effect of Zirconium Nitride coating on shear bond strength with denture base resin in Co-Cr alloy and titanium alloy (질화 지르코늄 코팅이 코발트 크롬 합금과 타이타늄 합금에서 의치상 레진과의 전단결합강도에 미치는 영향)

  • Park, Chan;Lee, Kyoung-Hun;Lim, Hyun-Pil
    • Journal of Dental Rehabilitation and Applied Science
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    • v.32 no.3
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    • pp.194-201
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    • 2016
  • Purpose: The purpose of this study was to evaluate of Zirconium Nitride (ZrN) coating on shear bond strength with denture base resin in Co-Cr and Ti-6Al-4V alloy. Materials and Methods: Co-Cr and Ti-6Al-4V alloy disks (10 mm in diameter, 2.5 mm in thickness; each other: n = 14) were prepared and divided with 2 groups each other by ZrN coating. After primer was applied to disks surface, denture base resin with diameter 6 mm, height 5 mm was bonded on metal disk surface. After surface roughness was measured by Profiler, shear bond strength was determined with Universal testing machine and analyzed with two-way ANOVA. The specimen surfaces and failure mode were examined using a scanning electron microscope. Results: ZrN coated groups showed significantly higher rough surface than non-coated groups (P < 0.05). Irrespective of alloy materials, shear bond strength of ZrN coated groups were lower than non-coated groups (P < 0.001). The scanning electron microscope (SEM) of ZrN coated groups showed mixed and adhesive fractures. Conclusion: ZrN coating weakened bonding strength between denture base resin and Co-Cr, Ti-6Al-4V alloy.

Properties of Aluminum Clad Sheets for Condenser Fins Fabricated with Transition Elements(Cu, Cr) added to Al-1.4Mn-1.0Zn Base Alloys (Cu, Cr 등 천이원소가 첨가된 Al-1.4Mn-1.0Zn 합금을 심재로 하여 제조된 콘덴서 핀용 알루미늄 클래드 박판의 특성)

  • Euh, K.;Kim, H.W.;Lee, Y.S.;Oh, Y.M.;Kim, D.B.
    • Transactions of Materials Processing
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    • v.23 no.6
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    • pp.386-391
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    • 2014
  • In the current study, Al-Mn-Zn alloys are strip-cast and used as the base alloy for the core of aluminum clad sheets used in automotive condenser fins. Transition elements such as Cu and Cr are added to the base core alloy in order to improve the properties of the clad sheets. The AA4343/Al-Mn-Zn-X(X: Cu, Cr)/AA4343 clad sheets are fabricated by roll bonding and further cold-rolled to a thickness of 0.08 mm. Clad sheets were intermediately annealed during cold rolling at $450^{\circ}C$ in order to obtain 40% reduction at the final thickness. Tensile strength and sag resistance of the clad sheets are improved by Cu additions to the core alloy, while corrosion resistance is also increased. Cr-additions to the clad sheets enhance sag resistance and provide low enough corrosion, although tensile strength is not improved. The effect of Cu and Cr additions on the properties of the clad sheets is elucidated by microstructural analysis.

Structure and Thermal Properties of a Ternary Al-Cr-Si Quenching Ribbon Manufactured by Single Roll Method (단일 롤 방법으로 제작한 3원계 Al-Cr-Si 급냉리본의 구조 및 열 특성)

  • Han, Chang-Suk;Kim, Ki-Woong;Kim, Woo-Suk
    • Korean Journal of Materials Research
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    • v.31 no.5
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    • pp.296-300
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    • 2021
  • Al-Cr-Si ternary quench ribbons are fabricated using a single roll method and investigated for their structural and thermal properties. In particular, the sinterability is examined by pulse current sintering to obtain the following results. The Al74Cr20Si6 composition becomes a quasicrystalline single phase; by reducing the amount of Cr, it becomes a two-phase mixed structure of Al phase and quasicrystalline phase. As a result of sintering of Al74Cr20Si6, Al77Cr13Si10 and Al90Cr6Si4 compositions, the sintering density is increased with the large amount of Al phase; the sintering density is the highest in Al90Cr6Si4 composition. In addition, as a result of investigating the effects of sintering temperature and pressurization on the sintered density of Al90Cr6Si4, a sintered compact of 99% or more at 513 K and 500 MPa is produced. In particular, since the Al-Cr-Si ternary crystal is more thermally stable than the Al-Cr binary quaternary crystal, it is possible to increase the sintering temperature by about 100 K. Therefore, using an alloy of Al90Cr6Si4 composition, a sintered compact having a sintered density of 99 % or more at 613 K and 250 MPa can be manufactured. It is possible to increase the sintering temperature by using the alloy system as a ternary system. As a result, it is possible to produce a sintered body with higher density than that possible using the binary system, and at half the pressure compared with the conventional Al-Cr binary system.

Thermal Stability of Al-Fe-X Alloy System Prepared by Mechanical Alloying and Spark Plasma Sintering: II. Al-Fe-Cr and Al-Fe-Mo (기계적 합금화 및 스파크 플라즈마 소결에 의해 제조된 Al-Fe-X계 합금의 열적 안정성: II. Al-Fe-Cr and Al-Fe-Mo)

  • Lee, Hyun-Kwuon;Lee, Sang-Woo;Cho, Kyeong-Sik
    • Journal of Powder Materials
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    • v.12 no.1
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    • pp.43-50
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    • 2005
  • Mechanical alloying using high-energy ball mill and subsequent spark plasma sintering (SPS) process was applied to Al-Fe-Cr and Al-Fe-Mo powder mixture to investigate effects of Cr and Mo addition on thermal stability of Al-Fe, and thereby to enhance its thermal stability up to $500^{\circC}$. Various analytical techniques including micro-Vickers hardness test, SEM, TEM, X-ray diffractometry and corrosion test were carried out. It was found that addition of Cr and Mo to Al-Fe system played a role of grain growth inhibitor of matrix Al and some precipitates such as $Al_3Fe$ during SPS and subsequent heat treatment. The inhibition of grain growth resulted in increased Vickers hardness and thermal stability up to $500^{\circC}$ comparing to those of Al-Fe alloy system.