• Title/Summary/Keyword: Counter Electrode

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High Efficiency Dye-Sensitized Solar Cells: From Glass to Plastic Substrate

  • Go, Min-Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.294-294
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    • 2010
  • Over the last decade, dye-sensitized solar cell (DSSC) has attracted much attention due to the high solar-to-electricity conversion efficiency up to 10% as well as low cost compared with p-n junction photovoltaic devices. DSSC is composed of mesoporous TiO2 nanoparticle electrodes coated with photo-sensitized dye, the redox electrolyte and the metal counter electrode. The performances of DSSC are dependent on constituent materials and interface as well as device structure. Replacing the heavy glass substrate with plastic materials is crucial to enlarge DSSC applications for the competition with inorganic based thin film photovoltaic devices. One of the biggest problems with plastic substrates is their low-temperature tolerance, which makes sintering of the photoelectrode films impossible. Therefore, the most important step toward the low-temperature DSSC fabrication is how to enhance interparticle connection at the temperature lower than $150^{\circ}C$. In this talk, the key issues for high efficiency plastic solar cells will be discussed, and several strategies for the improvement of interconnection of nanoparticles and bendability will also be proposed.

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Basic Study on an Aftertreatment System of Diesel Particulate Matters with Electrostatic Precipitator and Cyclone (전기집진기와 사이클론을 응용한 디젤 입자상 물질의 후처리장치 기초연구)

  • 최인수
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.6
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    • pp.8-15
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    • 2001
  • An aftertreatment system of diesel exhaust gas was attempted to extract particulate matters. The system consisted of a corona-less electrostatic precipitator to agglomerate soot particles and a counter-flow cyclone to collect them. When the effect of high voltage was examined at different configuration of electrode plates, the case of positive 15kV at both plates showed the maximum reduction of 38% in diesel smoke level. However, the back pressure became quite high as engine speed increased, so that minimizing pressure drop in cyclone should be studied with improving collection efficiency of soot particles.

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Study of PEO Process for Al 7075 and Effect of additives (알루미늄 7075 합금의 PEO 처리 기술 및 첨가제 영향 분석)

  • Jin, Yun-Ho;Yang, Jae-Kyo
    • Journal of the Korean institute of surface engineering
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    • v.53 no.2
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    • pp.53-58
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    • 2020
  • In this study, we developed plasma electrolytic oxidation (PEO) process for aluminum 7075 alloy to improve the corrosion and mechanical properties. The electrolyte consists of potassium hydroxide and sodium silicate. Additionally, sodium stannate was added into the electrolyte to investigate its effect on PEO film formation. Titanium was used as the counter electrode. Plasma generation voltage reduced from 300V to 150 V by adding 4 g/L of sodium stannate. The thin oxide films were observed by SEM(Scanning Electron Microscopy)/EDS (Energy Dispersive Spectroscopy) for quantitative and qualitative analyses. XRD (X-ray diffraction) and XRF (X-ray Fluorescences) analyses were also carried out to identify oxide layer on aluminum 7075 surface. Vicker's hardness test was performed on the PEO-treated aluminum 7075 surface.

Closed-type Barrier Ribs of PDP via Micro-Molding Process

  • Son, Hyeon-Min;Kim, Sung-Jin;Koh, Min-Soo;Kim, Jin-Seok;Kim, Yong-Seog;Choi, Byung-Do
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.710-713
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    • 2005
  • In this study, waffle type barrier ribs for counter electrode discharge cells were prepared via micro-molding process. The master mold was prepared by UV lithography and working mold was manufactured by replicating the master mold. The UV paste used in this study consisted of ceramic powders for the barrier ribs, binder, hardener, and dispersant was filled into cavities of a polymeric mold by action of capillary pressure developed between mold and paste. The results demonstrated a possibility of one-step process for the manufacturing of waffle type barrier ribs embedded with sustaining electrodes.

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Electrical and Optical Properties of Electrochromic Window with Both Lithium and Proton Conducting Polymer Electrolytic Media (리튬 및 프로톤 전도성 고분자전해질을 사용하여 제작한 Electrochromic 창의 전기 및 광학적 특성)

  • 박성용;이철환;김형선;조원일;조병원;윤경석;안춘호;우경근
    • Journal of the Korean institute of surface engineering
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    • v.28 no.1
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    • pp.46-54
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    • 1995
  • An electrochromic(EC) cell was constructed using $WO_3$ as a electrochromic material and NiO as a counter electrode, deposited onto ITO-coated glass by the implementation of electron beam evaporation. The electrolytic media were both lithium and proton conducting polymers such as poly-acrylonitrile(PAN)-$LiClO_4$, poly-ethylene oxide(PEO)-$LiClO_4$, poly-vinyl butyral(PVB)-LiCl and PVB-H$_3$$PO_4$. Potentiodynamic cycling of the cells using PAN-$LiClO_4$, or PVB-$H_3$$PO_4$ electrolyte yielded a transmission variation of more than 40% at the wavelength of 632.8 nm within less than 10 sec response time at room temperature. These results indicate that these electrolytes, transparent in gel type, are premising for the application in large area electrochromic windows.

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Methods to Improve Light Harvesting Efficiency in Dye-Sensitized Solar Cells

  • Park, Nam-Gyu
    • Journal of Electrochemical Science and Technology
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    • v.1 no.2
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    • pp.69-74
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    • 2010
  • Methodologies to improve photovoltaic performance of dye-sensitized solar cell (DSSC) are reviewed. DSSC is usually composed of a dye-adsorbed $TiO_2$ photoanode, a tri-iodide/iodide redox electrolyte and a Pt counter electrode. Among the photovoltaic parameters of short-circuit photocurrent density, open-circuit voltage and fill factor, short-circuit photocurrent density is the collective measure of light harvesting, charge separation and charge collection efficiencies. Internal quantum efficiency is known to reach almost 100%, which indicates that charge separation occurs without loss by recombination. Thus, light harvesting efficiency plays an important role in improvement of photocurrent. In this paper, technologies to improve light harvesting efficiency, including surface area improvement by nano-dispersion, size-dependent light scattering efficiency, bi-functional nano material, panchromatic absorption by selective positioning of three different dyes and transparent conductive oxide (TCO)-less DSSC, are introduced.

Experimental Investigation of Electrostatic Dripping and Atomization Mode through Non-MEMs based Nozzle Design

  • Choi, Kyung-Hyun;Dang, Hyun-Woo;Rehmani, M.A. Ali
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.13.2-13.2
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    • 2009
  • Electrostatic printing either it is drop-on-demand or continuous has immense applications in non-contact printing systems such as solar cells, flexible printed circuits, RFIDs and bio applications. In this paper a laboratory manufactured nozzle has been designed for the experimental investigation of electrostatic dripping and atomization of liquid. Dripping and atomization conditions such as voltage, nozzle tip diameter, distance between counter electrode and flowrate has been indentified for the designed nozzle. Furthermore it is also demonstrated that the diameter of a generated droplet could be reduced from a significantly large size to a narrow size distribution which can be controlled by volumetric flow rate and applied voltage. This study will help in classify the conditions between different electrostatic dripping mode such as drop-on-demand formation, jet mode and finally the atomization mode based on the laboratory fabricated nozzle head.

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Development of Quartz Crystal Microbalance-Based Immunosensor for the Determination of Low-Density Lipoprotein (Quartz Crystal Microbalance 시스템을 이용한 저밀도 지질단백질측정용 면역센서의 개발)

  • 김상현;윤현철;감학성
    • KSBB Journal
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    • v.13 no.4
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    • pp.337-342
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    • 1998
  • Immunosensor for the determination of LDL(Low-Density Lipoprotein), a good indicator for the diagnosis of atherosclerosis and hypercholesterolemia, was developed by using quartz crystal microbalance(QCM). The immunosensor consists of flow-through cell, oscillating circuit, oscilloscope, and frequency counter. FIA(Flow Injection Analysis) was applied to the QCM system for the measurement of LDL in liquid phase. Antibody showing binding affinity against LDL was immobilized on the gold electrode of a quartz crystal by covalent coupling via polyethylenimine / glutaredehyde. LDL was injected and bound to the antibody immobilized on the QCM immunosensor. The response of the immunosensor (F0 - F1) was found to be proportional to the LDL concentration from 200 $\mu\textrm{g}$/ml to 800 $\mu\textrm{g}$/ml. Operational conditions for the operation of immunosensor were also investigated in terms of sensitivity and non-specific binding.

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Pulsed Electrochemical Deposition for 3D Micro Structuring

  • Park, Jung-Woo;Ryu, Shi-Hyoung;Chu, Chong-Nam
    • International Journal of Precision Engineering and Manufacturing
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    • v.6 no.4
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    • pp.49-54
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    • 2005
  • In this paper, micro structuring technique using localized electrochemical deposition (LECD) with ultra short pulses was investigated. Electric field in electrochemical cell was localized near the tool tip end region by applying pulses of a few hundreds of nano second duration, Pt-Ir tip was used as a counter electrode and copper was deposited on the copper substrate in mixed electrolyte of 0.5 M $CuSO_4$ and 0.5 M $H_2SO_4$, The effectiveness of this technique was verified by comparison with ECD using DC voltage. The deposition characteristics such as size, shape, surface, and structural density according to applied voltage and pulse duration were investigated. The proper condition was selected based on the results of the various experiments. Micro columns less than $10{\mu}m$ in diameter were fabricated using this technique. The real 3D micro structures such as micro spring and micro pattern were made by the presented method.

Electrochemical Behavior of Vanadium Trungsten Oxide Thin Films Deposited by Sputtering (스퍼터링으로 증착한 바나듐 텅스텐 산화물 박막의 전기화학적 거동)

  • 박영신;이병일;주승기
    • Journal of the Korean institute of surface engineering
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    • v.30 no.2
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    • pp.121-127
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    • 1997
  • Vanadium tungsten oxide thin films were formed by RF magnetron sputtering and the effects of tungsten addition on the crystallinity and on the electrochemical behavior were investigated. X-ray analysis revealed that amorphized films could be obtained by tungase addition. In order to investigate the electrochemical behavior of the vanadium tungsten oxide films, electrochemical insertion and extraction of lithium were out in 1m $LiCIO_4$-PC-DME electrolyte using litium metal as a counter electrode. When the tungsten was added to the $V_2O_5$ films, cycling reversibility was considerably improved. Electrochemical test showed the cell capacity of about $70\mu\;Ah/\textrm{cm}^2-\mu\textrm{m}$ when the amount of additive tungseten reached 30 atomic percent. No appreciable degradation of the cell capacity could be observed after hundred cycles of insertion and extration od Li.

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