• Title/Summary/Keyword: Cottrell equation

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Application of Fractal Geometry to Interfacial Electrochemistry - I. Diffusion Kinetics at Fractal Electrodes

  • Shin Heon-Cheol;Pyun Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.4 no.1
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    • pp.21-25
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    • 2001
  • This article is concerned with the application of the fractal geometry to interfacial electrochemistry. Especially, we dealt with diffusion kinetics at the fractal electrodes. This article first explained the basic concepts of the Sacral geometry which has proven to be fruitful for modelling rough and irregular surfaces. Finally this article examined the electrochemical responses to various signals under diffusion-limited reactions during diffusion towards the fractal interfaces: The generalised forms, including the fractal dimension of the electrode surfaces, of Cottrell, Sand and Randles-Sevcik equations were theoretically derived and explained in chronoamperomety, chronopotentiometry and linear sweep/cyclic voltammetry, respectively.

Creep Characteristics of Mudstone According to Stress Level and Water Content (응력수준 및 함수비에 따른 이암의 Creep 특성에 관한 연구)

  • Lee, Younghuy;Jeong, Ghangbok
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.3
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    • pp.39-51
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    • 2012
  • The time-dependent characteristics of mudstone in this study were analyzed by performing creep tests for the mudstone in Pohang. The creep tests were conducted on various boundary conditions to observe the time-dependent behavior of mudstone and the results were compared with values predicted by established visco-elastic model and empirical equations. As a result of analysis for empirical equations proposed by Griggs(1936), Cottrell(1952) and Singh(1975), the creep constants generally tend to increase as increasing the stress level and water content. Moreover, the values predicted by Singh's equation were well fitted for the test results. Therefore, it is expected to be reasonable that creep behavior of mudstone is analyzed using Singh's equation. As a result of analysis for a Burger's model, the predicted values were well fitted for the test results. Therefore, it is expected be reasonable that the creep behavior of mudstone by a rheological model is analyzed using Burger's model.

Ionization and Attachment Coefficients in Mixtures of $SF_6$ and He ($SF_6-He$ 혼합기체의 전리와 부착계수)

  • Kim, Sang-Nam
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2005.05a
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    • pp.342-345
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    • 2005
  • This paper describes the electron energy distribution function characteristics in $SF_6-He$ gas calculated for range of E/N values from $50{\sim}700[Td]$ by the Monte Carlo simulation(MCS) and Boltzmann equation(BE) method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters are obtained by time of flight(TOF) method. The results gained that the values of the electron swarm parameters such as the electron drift velocity, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients agree with the experimental and theoretical for a range of E/N. The results of Boltzmann equation and Monte carlo simulation have been compared with experimental data by Pollock, Ohmori, cottrell and Walker.

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The Analysis of Electron Transport Characteristics in $SiH_4$ Plasma ($SiH_4$ 플라즈마중의 전자수송특성 해석)

  • Lee, Hyoung-Yoon;Ha, Sung-Chul;Kim, Dae-Yeon
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.925-928
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    • 1998
  • In this paper, the electron transport characteristics in $SiH_4$ has been analysed over the E/N range $0.5{\sim}300[Td]$ and Pressure value 0.5, 1, 2.5 [Torr] by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity. diffusion coefficient, electron ionization, mean energy and the electron energy distribution function. The electron energy distribution function has been analysed in $SiH_4$ at E/N=30, 50[Td] for a case of the equilibrium region in the mean electron energy and respective set of electron collision cross sections. The results of Boltzmann equation and Monte carlo simulation have been compared with experimental data by Pollock, Ohmori, cottrell and Walker.

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Electron Transport Characteristics in $SiH_4$ by MCS-BEq (MCS-BEq에 의한 $SiH_4$ 전자수송특성(電子輸送特性))

  • Seong, Nak-Jin;Kim, Sang-Nam
    • Proceedings of the KIEE Conference
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    • 2005.10a
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    • pp.97-100
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    • 2005
  • This paper describes the electron transport characteristics in SiH4 has been analysed over the E/N range 0.5${\sim}$300[Td] and Pressure value 0.5, 1, 2.5 [Torr] by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, diffusion coefficient, electron ionization, mean energy and the electron energy distribution function. The electron energy distribution function has been analysed in $SiH_4$ at E/N=30, 50[Td] for a case of the equilibrium region in the mean electron energy and respective set of electron collision cross sections. The results of Boltzmann equation and Monte carlo simulation have been compared with experimental data by Pollock, Ohmori, cottrell and Walker.

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Diagnosis of Diabetes Using Voltage Analysis Based on EIS (Electro Interstitial Scan) (EIS 기반 전압신호 분석을 통한 당뇨병 진단 가능성 평가)

  • Bae, Jang-Han;Kim, Soochan;Kaewkannate, Kanitthika;Jun, Min-Ho;Kim, Jaeuk U.
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.11
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    • pp.114-122
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    • 2016
  • EIS (Electro interstitial scan) is a non-invasive and simple method to find the physio-pathological information inferred by electric current response with respect to low direct current applied between remote sites of the body. Although a few EIS-based devices for diagnosing diabetes were commercialized, they were not successful in offering clinical validity nor in confirming diagnostic principle. In this study, we measured the voltage responses of diabetic patients and normal subjects with a commercialized EIS device to test the usefulness of EIS in screening diabetes. For this purpose, voltage was measured between pairs of electrodes contacted at both palm, both soles of the feet and left and right forehead above both eyes. After feature extraction of voltage signals, the AUC (area under the curve) between the two groups was calculated and we found that seven variables were appropriately shown above 60% of accuracy. In addition, we applied the k-NN (k-nearest neighbors) method and found that the accuracy of classification between the two groups reached the accuracy of 76.2%. This result implies that the voltage response analysis based on EIS has potential as a diabetics screening method.

Evaluation of Clinical Usefulness of EIS(Electro Interstitial Scan) (EIS(Electro Interstitial Scan) 방법의 임상적 유효성 연구)

  • Kim, Soochan;Bae, Jang-Han;Jun, Min-Ho;Kim, Jaeuk U.
    • Journal of the Institute of Electronics and Information Engineers
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    • v.52 no.12
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    • pp.124-133
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    • 2015
  • Electro interstitial scan shows potential as a non-invasive screening method. It can discriminate some diseases based on electric current response to induce low intensity direct current to limbs or local area of body. DDFAO was invented in France and it is claimed that multi-channel EIS(Electro Interstitial Scan) is useful for various diseases, especially, diagnoses of endocrine system such as diabetics are very effective. In this study, we verified the repeatability and sensitivity of DDFAO by using a RC phantom model and its clinical usefulness using data obtained from normal and diabetes subject groups. As a result, it showed the repeatability and the output change according to change of phantom characteristic, but it was hard to distinguish normal and patient groups non-invasively with just six surface electrodes of DDFAO. The repeatability and the clinical accuracy was not sufficient for screening or diagnostic purposes, as well. In spite of the results with low repeatability and accuracy conducted in this study, we still need further investigations to improve the EIS-based measurement method; EIS is very convenient and simple and it shows potential as a screening tool of the whole body health conditions rather than localized disease diagnosis.