• Transactions of the Korean Society of Automotive Engineers
• /
• v.14 no.4
• /
• pp.99-106
• /
• 2006

High velocity oxygen-fuel thermal spray coating of the WC-Co cermet material is a well-established process for modifying the surface properties of the structural components exposed to the corrosive and wear attacks, and also these coating are well-known method to improve the fatigue strength of material. In this study, HVOF coated SM490B are prepared to evaluation of the effect of coating on tension and fatigue crack growth behavior. The pre-crack of the fatigue crack growth test specimens machined at deposited material area, heat affected zone and boundary, respectively. Through these test, the following results are obtained: 1) Tensile strength was about 498 MPa, and fracture occurred on base metal area. 2) The fatigue crack of coated specimens propagated more rapidly than non-coated specimen in all specimens. 3) In the same coating thickness specimens, the specimens with pre-crack at boundary more rapidly propagated than the specimens with pre-crack at HAZ and deposited material area. These results can be used as basic data in a structural integrity evaluation of rolled SM490B weldments considering HVOF coating.

• Journal of Advanced Navigation Technology
• /
• v.12 no.6
• /
• pp.653-658
• /
• 2008

The automotive environment is particularly demanding on connector performance, and is characterized by large temperature changes, high humidity and corrosive atmospheres. Fretting is a contact damage process that occurs between two contact surfaces. Fretting corrosion refers to corrosion damage at the asperities of contact surfaces. This damage is induced under load and in the presence of repeated relative surface motion, as induced for example by vibration. This paper critically reviews the works published previously on fretting corrosion of electrical connectors. Various experimental approaches such as testing machines, material selection, testing environments, acceleration testing techniques and preventing methods are addressed. Future research prospects arc suggested.

• Korean Journal of Metals and Materials
• /
• v.50 no.11
• /
• pp.809-815
• /
• 2012

Recently, as the interest in improving energy efficiency has grown, the demand for vehicle and machine parts that are resistant in high temperature corrosive conditions and abrasive environments has increased. Pack chromizing treatment of sintered steels is a profitable method that satisfies both corrosion resistance and low friction properties. Since austenitic stainless steels have good corrosion resistance but low mechanical hardness, if they are replaced by sintered steel parts with pack chromizing treatment, all the desirable properties such as low price, easy molding, high hardness, low frictional coefficient, and high corrosion resistance, can be obtained. The higher corrosion resistance of the chromized parts over that of the austenitic stainless steels was acquired by coating chromium carbides and a thin chromium oxides layer on the surface. Moreover, the surface morphology of chromized parts, which were composed of chromium rich phases and hardened chromium carbides by diffusing and alloying, had a peak-and-valley shape so that the dimple effect by the wrinkled morphology and high hardness induced a low friction coefficient.

• Journal of Korea Foundry Society
• /
• v.43 no.2
• /
• pp.55-63
• /
• 2023

Due to the importance of the surface on the final slab quality, it is essential to maintain a smooth segment roll surface that is in touch with the thin solid shell during solidification. In this paper, the surface of the used continuous casting guide roll was analyzed to realize the mechanism of its surface deterioration. Surface analysis has revealed severe corrosion at two distinct areas leading to deep roughness occurring on the guide roll. Firstly, the severe corrosion follows prior austenite grain boundary due to exposure with acidic environment. Also, in heat affected zone (HAZ) where two cladding beads overlap, more severe corrosion takes place. The overheat input results in local ferritization without full melting which increases retained δ-ferrite content almost 10 times higher than surrounding area. Corrosion was observed to happen at the δ-γ interface where Cr depletion takes place.

• Journal of Advanced Marine Engineering and Technology
• /
• v.39 no.5
• /
• pp.542-547
• /
• 2015

Since the oil price has been significantly jumped for several years, a heavy oil of low quality has been mainly used in the diesel engine of the merchant ship. Thus, a combustion chamber of the engine has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of the combustion chamber has been getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the engine parts such as exhaust valve, piston crown and cylinder head surrounded with combustion chamber are more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these engine parts is very important to prolong their lifetime in a economical point of view. In this study, Inconel 625 filler metal were welded with GTAW method in the cast steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected and base metal zones were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% $H_2SO_4$ solution. The weld metal and base metal zones exhibited the highest and lowest values of hardness respectively. Furthermore, the corrosion current density of the weld metal zone revealed the lowest value, having the highest value of hardness. The corrosive products with red color and local corrosion like as a pitting corrosion were considerably observed at the base metal zone, while these morphologies were not wholly observed in the weld metal zone. In particular, the polarization characteristics such as impedance, polarization curve and cyclic voltammogran associated with corrosion resistance property were well in good agreement with each other. Consequently, it is suggested that the mechanical and corrosion characteristics of the piston crown can be predominantly improved by repair welding method using the Inconel 625 electrode.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2016.11a
• /
• pp.105-105
• /
• 2016

Recently, high power impulse magnetron sputtering (HIPIMS) has attracted considerable attentions due to its high potential for industrial applications. By pulsing the sputtering target with high power density and short duration pulses, a high plasma density and high ionization of the sputtered species can be obtained. HIPIMS has exhibited several merits such as increased coating density, good adhesion, microparticle-free and smooth surface, which make the HIPIMS technique desirable for synthesizing hard coatings. However, hard coatings present intrinsic defects (columnar structures, pinholes, pores, discontinuities) which can affect the corrosion behavior, especially when substrates are active alloys like steel or in a wear-corrosion process. Atomic layer deposition (ALD), a CVD derived method with a broad spectrum of applications, has shown great potential for corrosion protection of high-precision metallic parts or systems. In ALD deposition, the growth proceeds through cyclic repetition of self-limiting surface reactions, which leads to the thin films possess high quality, low defect density, uniformity, low-temperature processing and exquisite thickness control. These merits make ALD an ideal candidate for the fabrication of excellent oxide barrier layer which can block the pinhole and other defects left in the coating structure to improve the corrosion protection of hard coatings. In this work, CrN/Al2O3/CrN multilayered coatings were synthesized by a hybrid process of HIPIMS and ALD techniques, aiming to improve the CrN hard coating properties. The influence of the Al2O3 interlayer addition, the thickness and intercalation position of the Al2O3 layer in the coatings on the microstructure, surface roughness, mechanical properties and corrosion behaviors were investigated. The results indicated that the dense Al2O3 interlayer addition by ALD lead to a significant decrease of the average grain size and surface roughness and greatly improved the mechanical properties and corrosion resistance of the CrN coatings. The thickness increase of the Al2O3 layer and intercalation position change to near the coating surface resulted in improved mechanical properties and corrosion resistance. The mechanism can be explained by that the dense Al2O3 interlayer acted as an excellent barrier for dislocation motion and diffusion of the corrosive substance.

• Tribology and Lubricants
• /
• v.39 no.1
• /
• pp.1-7
• /
• 2023

Fluid pumps in chemical processes are typically driven by electric motors. Even if the motor is separated from the pump with seals, wear resulting from friction and misalignment can lead to leakage of chemical fluid, causing corrosion in the bearing supporting the motor, and, eventually, failure of the motor. It is thus a standard procedure to replace bearings at regular intervals. In this article, we propose 3D-printed plastic ball bearings for use as an alternative to commercial stainless-steel ball bearings. The plastic bearings are easy to manufacture, require less time to replace, and are chemically resistant. To validate the applicability of the plastic bearings, we first conducted chemical resistance tests. Bearings were immersed in 30 caustic acid and 30 nitric acid for 30 min and 24 h, respectively. The test results showed no corrosive damage to the bearings. A test rig was set up to compare the performance of the plastic bearings with that of the commercially equivalent deep-groove ball bearings. Loading test results showed that the plastic bearings performed as well as the commercial bearing in terms of vibration level and load-handling capability. Finally, a plastic bearing was subjected to a clean-in-place process for three months. It actually outperformed the commercial bearing in terms of chemical resistance. Thus, 3D-printed plastic bearings are a viable alternative to stainless-steel ball bearings.

• Proceedings of the Korean Vacuum Society Conference
• /
• 1999.07a
• /
• pp.122-122
• /
• 1999

Graphite with its advantages of high thermal conductivity, low thermal expansion coefficient, and low elasticity, has been widely used as a structural material for high temperature. However, graphite can easily react with oxygen at even low temperature as 40$0^{\circ}C$, resulting in CO2 formation. In order to apply the graphite to high temperature structural material, therefore, it is necessary to improve its oxidation resistive property. Silicon Carbide (SiC) is a semiconductor material for high-temperature, radiation-resistant, and high power/high frequency electronic devices due to its excellent properties. Conventional chemical vapor deposited SiC films has also been widely used as a coating materials for structural applications because of its outstanding properties such as high thermal conductivity, high microhardness, good chemical resistant for oxidation. Therefore, SiC with similar thermal expansion coefficient as graphite is recently considered to be a g행 candidate material for protective coating operating at high temperature, corrosive, and high-wear environments. Due to large lattice mismatch (~50%), however, it was very difficult to grow thick SiC layer on graphite surface. In theis study, we have deposited thick SiC thin films on graphite substrates at temperature range of 700-85$0^{\circ}C$ using single molecular precursors by both thermal MOCVD and PEMOCVD methods for oxidation protection wear and tribological coating . Two organosilicon compounds such as diethylmethylsilane (EDMS), (Et)2SiH(CH3), and hexamethyldisilane (HMDS),(CH3)Si-Si(CH3)3, were utilized as single source precursors, and hydrogen and Ar were used as a bubbler and carrier gas. Polycrystalline cubic SiC protective layers in [110] direction were successfully grown on graphite substrates at temperature as low as 80$0^{\circ}C$ from HMDS by PEMOCVD. In the case of thermal MOCVD, on the other hand, only amorphous SiC layers were obtained with either HMDS or DMS at 85$0^{\circ}C$. We compared the difference of crystal quality and physical properties of the PEMOCVD was highly effective process in improving the characteristics of the a SiC protective layers grown by thermal MOCVD and PEMOCVD method and confirmed that PEMOCVD was highly effective process in improving the characteristics of the SiC layer properties compared to those grown by thermal MOCVD. The as-grown samples were characterized in situ with OES and RGA and ex situ with XRD, XPS, and SEM. The mechanical and oxidation-resistant properties have been checked. The optimum SiC film was obtained at 85$0^{\circ}C$ and RF power of 200W. The maximum deposition rate and microhardness are 2$mu extrm{m}$/h and 4,336kg/mm2 Hv, respectively. The hardness was strongly influenced with the stoichiometry of SiC protective layers.

• Journal of Advanced Marine Engineering and Technology
• /
• v.38 no.4
• /
• pp.409-417
• /
• 2014

Since the oil price has been significantly jumped for recent some years, the diesel engine of the merchant ship has been mainly used the heavy oil of low quality. Thus, it has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas in a combustion chamber is getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of most parts surrounded with combustion chamber is more serious compared to the other parts of the engine. Therefore, an optimum weldment for these parts is very important to prolong their lifetime in a economical point of view. In this study, four types of filler metals such as Inconel 625, 718, 1.25Cr-0.5Mo and 0.5Mo were welded with SMAW and GTAW methods in the forged steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected zone and base metal were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% H2SO4 solution. The weld metal and base metal exhibited the best and worst corrosion resistance in all cases of filler metals. In particular, the weld metal welded with filler metals of Inconel 718 revealed the best corrosion resistance among the filler metals, and Inconel 625 followed the Inconel 718. Hardness relatively indicated higher value in the weld metal compared to the base metal. Furthermore, Inconel 625 and 718 indicated higher values of hardness compared to 1.25cr-0.5Mo and 0,5Mo filler metals in the weld metal.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.20 no.5
• /
• pp.7-12
• /
• 2019

The naval surface vessels, which were often exposed to harsh marine environment, tended to be corrosive due to military operations on various sea-areas and courses. Although R.O.K Navy applied various methods to protect further corrosion, the hull corrosion occurred due to cavitation were found on the naval surface vessels at regular and occasional docking. Hull corrosion was a critical factor directly to affect the lifetime of ships and their operational capabilities adversely. In this paper, EH 2350, which was the main anticorrosion paint used by R.O.K. Navy, was compared with DuraTough DL by used by the U.S Navy to collect materials related to anti-corrosion paint. In addition, the paint compatibility verification was conducted through wear abrasion test. Assuming that it was exposed to sea-environment various both abrasion cycle and weight for objective verification. by varying both the abrasion cycles and weights. In this study, the reliability of the EH 2350 conformity, which was used in Naval surface vessels, was secured.