• Title/Summary/Keyword: Corrosive Environments

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VeKo25Cr: A Corrosion and Wear Resistant Powder Metallurgical Alloy with a Basic Hardness of 52 HRC

  • Hofer, Beat W.;Saner, Michel
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.942-943
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    • 2006
  • To meet the demands for use in extremely abrasive and corrosive environments, a new material was developed. The VeKo25Cr distinguishes itself through specifically selected amounts of carbon and carbide forming elements such as Cr, Mo, V, W and Nb. The alloy is based on a Fe matrix. The strength after heat treatment and the wear and corrosion properties are compared to those of other materials. VeKo25Cr can be combined with easy-to-process materials such that the difficult handling is minimized to those places on the piece most subjected to operational wear.

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The Evaluation of 2-25Cr-lMo Steels Degradation by the Electrochemical Polarization Method (전기화학적 분극특성을 이용한 2.25Cr-lMo 강의 열화도 평가)

  • 김지수;현양기;이재도;오세규
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2001.05a
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    • pp.314-319
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    • 2001
  • Most parts of facilities in domestic petroleum plants and power plants are needed to be abandoned, repaired or replaced, because in Korea they were built in the 1960s and, they have been used under severe conditions and exposed corrosive environments. 2.25Cr- lMo steels have excellent high-temperature mechanical properties. Therefore, the material have been widely used as heat exchanger tubes, boiler headers and its tubes in such industries. But, those microstructural evolutions in high temperature such as precipitation and carbide coarsening give a reason to degrade the material. Especially, in case of this material, carbides induced embrittlement(CIE) is the primary reason for degrading mechanical properties at over 50$0^{\circ}C$. In this paper, we introduce a electrochemical polarization method for detecting CIE quantitatively.

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Effect of Thermal Treatment Temperature on Lifespan of Conductive Oxide Electrode

  • Yoo, Y.R.;Chang, H.Y.;Jang, S.G.;Nam, H.S.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.6 no.2
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    • pp.44-49
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    • 2007
  • Dimensionally stable anodes have been widely used to cathodically protect the metallic materials in corrosive environments including concrete structure as the insoluble anode. Lifespan of the anode for concrete construction can be determined by NACE TM0294-94 method. Lifespan of conductive oxide electrode would be affected by thermal treatment condition in the process of sol-gel coatings. This work aims to evaluate the effect of thermal treatment temperature on the lifespan of the $RuO_{2}$ electrode. $450^{\circ}C$ treated conductive oxide electrode showed the excellent properties and its lifespan was evaluated to be over 88 years in 3% NaCl, 4% NaOH, and simulated pore water. This behavior was related to the formation of $RuO_{2}$.

Effect of Electrolyte Composition on Corrosion Behavior of PEO Treated AZ91 Mg Alloy

  • Park, Kyeong Jin;Lee, Jae Ho
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.227-231
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    • 2009
  • Mg and Mg alloys have been used for lots of applications, including automobile industry, aerospace, mobile phone and computer parts owing to low density. However, Mg and Mg alloys have a restricted application because of poor corrosion properties. Thus, improved surface treatments are required to produce protective films that protect the substrate from corrosive environments. Environmental friendly Plasma Electrolytic Oxidation (PEO) has been widely investigated on magnesium alloys. PEO process combines electrochemical oxidation with plasma treatment in the aqueous solution. In this study, AZ91 Mg alloys were treated by PEO process in controlling the current with PC condition and treated time, concentration of NaF, NaOH, and $Na_2SiO_3$. The surface morphology and phase composition were analyzed using SEM, EDS and XRD. The potentiodynamic polarization tests were carried out for the analysis of corrosion properties of specimen. Additionally, salt spray tests were carried out to examine and compare the corrosion properties of the PEO treated Mg alloys.

Fatigue Behavior of Catenary Wires by Environments Degradation (환경열화에 의한 가선재의 피로거동)

  • 김용기;장세기
    • Journal of the Korean Society for Railway
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    • v.7 no.1
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    • pp.14-19
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    • 2004
  • The effect of surface damage on fatigue properties of catenary wires were investigated to estimate their service lift. As surface defects of the wires caused by surface corrosion increase, surface roughness gets worse, and as roughness increases, it is easy for moisture coming from rain and dew to be condensed around uneven parts of the surface. The condensed moisture causes a locally severe corrosion which leads to damage of the wires. Corrosion of catenaty wires can make their actual lifetime shorter than that originally designed. The amount of decrease was more prominent as environmental conditions became more corrosive. They are also vibrated with some amplitude everytime pantographs touch contact line. The frequent cyclic load on the wire may result in a fatigue fracture. Surface damage by corrosion can make formation of crack initiation at fatigue. In the present study, the fatigue life of the used wire was measured 35 to 50% compared with that of new one in average.

Prediction of stress intensity factor range for API 5L grade X65 steel by using GPR and MPMR

  • Murthy, A. Ramachandra;Vishnuvardhan, S.;Saravanan, M.;Gandhi, P.
    • Structural Engineering and Mechanics
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    • v.81 no.5
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    • pp.565-574
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    • 2022
  • The infrastructures such as offshore, bridges, power plant, oil and gas piping and aircraft operate in a harsh environment during their service life. Structural integrity of engineering components used in these industries is paramount for the reliability and economics of operation. Two regression models based on the concept of Gaussian process regression (GPR) and Minimax probability machine regression (MPMR) were developed to predict stress intensity factor range (𝚫K). Both GPR and MPMR are in the frame work of probability distribution. Models were developed by using the fatigue crack growth data in MATLAB by appropriately modifying the tools. Fatigue crack growth experiments were carried out on Eccentrically-loaded Single Edge notch Tension (ESE(T)) specimens made of API 5L X65 Grade steel in inert and corrosive environments (2.0% and 3.5% NaCl). The experiments were carried out under constant amplitude cyclic loading with a stress ratio of 0.1 and 5.0 Hz frequency (inert environment), 0.5 Hz frequency (corrosive environment). Crack growth rate (da/dN) and stress intensity factor range (𝚫K) values were evaluated at incremental values of loading cycle and crack length. About 70 to 75% of the data has been used for training and the remaining for validation of the models. It is observed that the predicted SIF range is in good agreement with the corresponding experimental observations. Further, the performance of the models was assessed with several statistical parameters, namely, Root Mean Square Error (RMSE), Mean Absolute Error (MAE), Coefficient of Efficiency (E), Root Mean Square Error to Observation's Standard Deviation Ratio (RSR), Normalized Mean Bias Error (NMBE), Performance Index (ρ) and Variance Account Factor (VAF).

Corrosion Characteristics of Fe-Si, Ni-Ti and Ni Alloy in Sulfuric Acid Environments (황산 환경에서 Fe-Si, Ni-Ti계 및 Ni 합금의 내부식성 특성)

  • Kwon, Hyuk-Chul;Kim, Dong-Jin;Kim, Hong-Pyo;Park, Ji-Yeon;Hong, Seong-Deok
    • Korean Journal of Materials Research
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    • v.21 no.1
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    • pp.1-7
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    • 2011
  • Methods of producing hydrogen include steam reforming, electrochemical decomposition of water, and the SI process. Among these methods, the Sulfur iodine process is one of the most promising processes for hydrogen production. The thermochemical sulfur-iodine (SI) process uses heat from a high-temperature-gas nuclear reactor to produce $H_2$ gas; this process is known for its production of clean energy as it does not emit $CO_2$ from water. But the SI-process takes place in an extremely corrosive environment for the materials. To endure SI environments, the materials for the SI environment will have to have strong corrosion resistance. This work studies the corrosion resistances of the Fe-Si, Ni-Ti and Ni Alloys, which are tested in SI-process environments. Among the SI-process environments, the conditions of boiling sulfuric acid and decomposed sulfuric acid are selected in this study. Before testing in boiling sulfuric acid environments, the specimens of Fe-4.5Si, Fe-6Si, Ni-4.5Si, Ni-Ti-Si-Nb and Ni-Ti-Si-Nb-B are previously given heat treatment at $1000^{\circ}C$ for 48 hrs. The reason for this heat treatment is that those specimens have a passive film on the surface. The specimens are immersed for 3~14 days in 98wt% boiling sulfuric acid. Corrosion rates are measured by using the weight change after immersion. The corrosion rates of the Fe-6Si and Ni-Ti-Si-Nb-B are found to decrease as the time passes. The corrosion rates of Fe-6si and Ni-Ti-Si-Nb-B are measured at 0.056 mm/yr and 0.16 mm/yr, respectively. Hastelloy-X, Alloy 617, Alloy 800H and Haynes 230 are tested in the decomposed sulfuric acid for one day. Alloy 800H was found to show the best corrosion resistance among the materials. The corrosion rate of Alloy 800H is measured at -0.35 mm/yr. In these results, the corrosion resistance of materials depends on the stability of the oxide film formed on the surface. After testing in boiling sulfuric acid and in decomposed sulfuric acid environments, the surfaces and compositions of specimens are analyzed by SEM and EDX.

Corrosion effects on mechanical behavior of steel fiber reinforced concrete, including fibers from recycled tires

  • Ansari, Mokhtar;Safiey, Amir
    • Computers and Concrete
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    • v.26 no.4
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    • pp.367-375
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    • 2020
  • Today, the use of special technologies in the admixture of concrete has made tremendous progress, but the problem that has always existed in the construction of concrete members is the brittleness and lack of loading bearing after cracking, which leads to reduced strength and energy absorption. One of the best ways to fix this is to reinforce the concrete with steel fibers. Steel fibers also control cracks due to dry shrinkage, reduce structural crack width, and improve impact resistance. In this study, recycled steel fibers from worn tires have been used in the manufacture of concrete samples, the secondary benefits of which are the reduction of environmental pollution. One of the disadvantages of steel fiber reinforced concrete is the corrosion of steel fibers and their deterioration in harsh environments such as coastal areas. Corrosion caused by chlorine ions in metal fibers causes deterioration and early decommissioning of structures in corrosive environments. In this study, the effect of the dosage of steel fibers (dosages of 15, 30, and 45 kg of fibers per cubic meter of concrete) and aspect ratio of fibers (aspect ratio of 25 and 50) on compressive and flexural strength of concrete samples are investigated. In the following, the effect of fiber corrosion on the results of the mechanical properties of concrete samples is examined. The results show that the increase in fiber causes a relative increase in compressive strength, and a significant increase in flexural strength, and corrosion of steel fibers without reducing workability reduces compressive strength and flexural strength by up to 6 to 11%, respectively.

Sedimentary Environment Change in Mid-channel Bar of the Lower Geum River Using Multi-temporal Satellite Data (다중시기 영상자료를 이용한 금강하류의 하중도 퇴적환경 변화)

  • Hong, Ki-Byung;Jang, Dong-Ho
    • Journal of Environmental Impact Assessment
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    • v.18 no.3
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    • pp.171-183
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    • 2009
  • This study aims to analyze the sedimentary environment change in mid-channel bar of the lower Geum river basin after the construction of the estuary barrage using multi-temporal satellite data and GIS. The sedimentary environment changes were observed in mid-channel bar areas. The mid-channel bar F was found to have been newly formed for 10 years(1996-2006), whereas the mid-channel bar B located between mid-channel bar A and C has disappeared by erosion during the same periods. When examined by section, the areas of the mid-channel bar in the upper stream section from the Yipo's reference point generally increased due to the prevailing sedimentary environments, and those of the downstream section decreased where corrosive environments are dominant. In ternms of the centroid movement, the mid-channel bars grew up toward the downstream by switching erosion and accumulation, as sedimentation was prevailing in the downstream area of mid-channel bars and corrosion was dominant in the upper stream. Through grain size analysis, the study areas are divided into three sections according to the average grain size. In Section I, the mid-channel bars were formed as a result of sedimentary process of tides in the past. In Section II, the mid-channel bars were formed partly through the sedimentary process of rivers although the sedimentary process of tides is prevailing. In Section III, the mid-channel bars were formed mainly through the sedimentary process of rivers, even if it showed the sedimentary process of tides in the past.

Design of Pultruded I-shape FRP Compression Member (펄트루젼 I형 FRP 압축재의 설계)

  • Joo, Hyung-Joong;Lee, Seung-Sik;Yi, Jong-Seok;Yoon, Soon-Jong
    • Composites Research
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    • v.25 no.2
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    • pp.46-53
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    • 2012
  • Using pultrusion process, FRP composite structural members having various cross-section shapes can be produced with unlimited lengths. Because of such reasons, these members are suitable for the application in the construction field. Especially, this material is highly appreciated if the material is to be used in the corrosive environments such as aquatic or oceanic environments due to its high corrosion resistance. However, design criteria for the FRP structural member are not developed yet. So, the research on the development of design guideline is needed ungently. In order to use the pultruded structural FRP member efficiently, the members are composed of thin plate components, and thus, the member is prone to buckle easily and the buckling is one of the governing strength limit states for the design. In this paper, we present the analytical study results pertaining to the buckling behavior of I-shape FRP compression member. In addition, design procedure and flow-chart are also proposed based on the study results including previous experimental results. Proposed design procedure is similar to that in ANSI/AISC 360-10 with minor modification. Therefore, it is convinced that the structural design of pultruded FRP compression member could be done easily by following design procedure proposed in this paper.