• Title/Summary/Keyword: Corrosion property

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Perforrmance Tests of Epoxy-coated Reinforcing Bars : Corrosion Protection Properties (에폭시 도막 철근의 내부식 성능에 관한 실험적 연구)

  • 신영수;홍기섭;최완철
    • Magazine of the Korea Concrete Institute
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    • v.6 no.6
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    • pp.173-179
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    • 1994
  • Epoxy coated bars protecting reinforcing bars from corrosion and enhancing durability of reinforced concrete structures are tested to evaluate corrosion protection properties. Tests are performed based on the relevant sta.ndards of KS and ASTM, such as chenical resistance, salt water spray, salt crock test and chloride ermeability test. with the main varlable of the coating thlckness. Test results show good chemical protection property and chloride permeability. The results of the salt water spray and the salt crock test show that epoxy coating well protects the reinforcing bars from corrosion, cornparing to the biack bars without epoxy coatmg. However, several spots on the coated bars are rusted at the pinholes or un the bars with coating thickness less thar $200{\mu}M$. Special cautions are required i n the process of blast cleanmg when applying the usion-bonded epoxy coating.

Environmentally Friendly Surface Treatments for Improvement of Corrosion of Steel Sheets: Synergy Effect by Multicoating (강판의 내식성 향상을 위한 환경 친화형 표면처리: 다중코팅에 의한 시너지 효과)

  • Jeon Sangik;Park Chan-Young;Ryou Jin-Ho;Lee Won-Ki
    • Journal of Environmental Science International
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    • v.14 no.1
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    • pp.97-103
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    • 2005
  • Because of the toxicity of hexavelant chromium ion, treatments of metallic surface with chromate compounds to retard corrosion are undesirable for safety control in industrial uses and protection of environment. In this study, we investigated several compounds such as inorganic, organic, and polymer materials in order to sub­stitute the chromate conversion treatment on steel sheet. The corrosion property was investigated in a salt spray tester with 3.5 $wt.{\%}\;NaCI\;at\;35^{\circ}C.$ The results showed that the zirconium/silane/polymer triple coatings on the galvanized steel exhibited a significant retardation of corrosion. Although the multicoating system needs a com­plexed processing, we can confirm a possibility of development of a chromate-free chemical conversion treat­ment for galvanized steel sheet.

Corrosion Resistance of SPCC, SPFC590, SPFC780 Steel by Organic/Inorganic Hybrid Solution (Case of different SiO2 polysilicate under a constant melamin) (유/무기하이브리드 용액에 의한 SPCC, SPFC590, SPFC780 강판의 내식성 (일정한 멜라민에서 SiO2 polysilicate 양이 다른 경우))

  • Nam, Ki-Woo;Jeong, Hee-Rok;Lee, Kwang-Ho
    • Journal of Power System Engineering
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    • v.21 no.2
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    • pp.5-13
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    • 2017
  • This study has developed an organic/inorganic hybrid solution according to amount of $SiO_2$ polysilicate, and the amount of melamine is constant. The three types of cold rolled steel were evaluated a corrosion resistance properties by using these solutions. $US_3M_3$ and $US_{11}M_3$ solutions were generate a lot of corrosion. $US_7M_3$ solution was excellent in corrosion resistance, regardless of the steel type. The appearance of coating by $US_3M_3$ and $US_{11}M_3$ solutions were bumpy surface, and were a lot of fine defects. $US_7M_3$ solution was made a sophisticated molecular cross-linking structure inside the coating, it was a slick surface. Other characteristics are exhibited the excellent property for all solutions.

Cu CMP Property by Addition of Corrosion Inhibitor and Complexing Agent (부식 방지제와 Complexing Agent 첨가에 따른 Cu CMP 특성)

  • Kim, In-Pyo;Kim, Nam-Hoon;Kim, Sang-Yong;Lee, Cheol-In;Eom, Joon-Cheol;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.343-346
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    • 2003
  • A systematic study of Cu CMP in terms of the effect of slurry chemicals(oxidizer, corrosion inhibitor, complexing agent) on the process characteristics has been performed. In acidic media, a corrosion inhibitor, benzotriazole(BTA) and tolytriazol(TTA) was used to control the removal rate and avoid isotropic etching. When complexing agent is added with $H_2O_2$ 2wt% in the slurry, a corrosion rate was presented very good. Most of in, it was appeared that BTA is possible to be replaced by TTA. The tartaric acid was distinguished for the effect among complexing agents. n we apply this results to copper CMP process, it is thought that we will be able to obtain better yield.

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The Effect of the Additive Elements Alloying Method on the Corrosion Resistance of Sintered STS 316L (STS 316L 소결재료의 내식특성에 미치는 합금원소 첨가방법의 영향)

  • Kim, Hye Seong;Kim, Yoo Young;Park, Dong Kyu;Ahn, In Shup
    • Journal of Powder Materials
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    • v.20 no.3
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    • pp.203-209
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    • 2013
  • In this study, STS 316L powders with 3 wt.% Cu and 1 wt.% Sn known as corrosion-resistance reinforcement elements, are prepared to make different kinds of specimens, in which, 3 wt.% Cu and 1 wt.% Sn are added in different forms by mixing, alloying and fully alloying. After sintering in the same condition, the corrosion resistance, wear resistance and their mechanical properties of specimens are tested respectively. According to the comparison, STS 316L specimen sintered at $1270^{\circ}C$ showed the most excellent mechanical property: HRB 78 (hardness), 1130.7 MPa (RCS), 26.6% (Fraction Wear), It was similar with the specimen made of STS316L and fully alloyed Cu and Sn powders, meanwhile, the latter one appears the best corrosion resistance, 75hrs-salt immersion test results. In addition, the specimens with Cu and Sn powders additive showed relatively worse wear resistance in compared with STS316L specimen.

Corrosion Behaviors of ZrN Coated on Dental Co-Cr Alloys (ZrN 코팅된 치과 주조용 Co-Cr 합금의 부식거동)

  • Lee, Sang-Hun;Nah, Jung-Sook;Jang, Jae-Young
    • Journal of Technologic Dentistry
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    • v.35 no.4
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    • pp.343-352
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    • 2013
  • Purpose: The purpose of this study was to investigate to effect of the ZrN coated on corrosion resistance and physical property of dental Co-Cr alloys using various instruments. Methods: The specimens were used, respectively, for experiment, Arc Ion plating was carried out for dental casting alloys using ZrN coated materials with nitrogen gas. ZrN coated surface of each specimen was observed with field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), vickers hardness tester, and electrochemical tester. Results: The current density of ZrN coated specimen was smaller than that of non-coated specimen in 0.9% NaCl solution. Pit nucleated at scratch of specimen. The pitting corrosion resistant |$E_{max}-E_{rep}$| increased in order of ZrN coated (110 mV), and non-coated wire (100 mV). Conclusion: The corrosion potential of the ZrN coated specimen was comparatively high. the surface of ZrN coated specimen was more smooth than that of other kinds of non-coated specimen. ZrN coated surface showed higher hardness than that of non-coated surface.

Corrosion Resistance and Low Friction Property of Sintered Steel Parts via Chromizing Treatment (크로마이징 처리 된 철계 소결 부품의 내식성 및 저 마찰특성)

  • Kim, Sang-Gweon;Park, Yong-Jin;Yeo, Kuk-Hyun;Lee, Jae-Hoon
    • Korean Journal of Metals and Materials
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    • v.50 no.11
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    • pp.809-815
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    • 2012
  • Recently, as the interest in improving energy efficiency has grown, the demand for vehicle and machine parts that are resistant in high temperature corrosive conditions and abrasive environments has increased. Pack chromizing treatment of sintered steels is a profitable method that satisfies both corrosion resistance and low friction properties. Since austenitic stainless steels have good corrosion resistance but low mechanical hardness, if they are replaced by sintered steel parts with pack chromizing treatment, all the desirable properties such as low price, easy molding, high hardness, low frictional coefficient, and high corrosion resistance, can be obtained. The higher corrosion resistance of the chromized parts over that of the austenitic stainless steels was acquired by coating chromium carbides and a thin chromium oxides layer on the surface. Moreover, the surface morphology of chromized parts, which were composed of chromium rich phases and hardened chromium carbides by diffusing and alloying, had a peak-and-valley shape so that the dimple effect by the wrinkled morphology and high hardness induced a low friction coefficient.

Electrochemical Corrosion Damage Characteristics of Aluminum Alloy Materials for Marine Environment (해양환경용 알루미늄 합금 재료의 전기화학적 부식 손상 특성)

  • Kim, Sung Jin;Hwang, Eun Hye;Park, Il-Cho;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.51 no.6
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    • pp.421-429
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    • 2018
  • In this study, various electrochemical experiments were carried out to compare the corrosion characteristics of AA5052-O, AA5083-H321 and AA6061-T6 in seawater. The electrochemical impedance and potentiostatic polarization measurements showed that the corrosion resistance is decreased in the order of AA5052-O, AA5083-H321 and AA6061-T6, with AA5052-O being the highest resistant. This is closely associated with the property of passive film formed on three tested Al alloys. Based on the slope of Mott-Schottky plots of an n-type semiconductor, the density of oxygen vacancies in the passive film formed on the alloys was determined. This revealed that the defect density is increased in the order of AA5052-O, AA5083-H321 and AA6061-T6. Considering these facts, it is implied that the addition of Mg, Si, and Cu to the Al alloys can degrade the passivity, which is characterized by a passive film structure containing more defect sites, contributing to the decrease in corrosion resistance in seawater.

A Study on Wear and Corrosion Properties of Plasma Carburized Austenitic Stainless Steel (플라즈마 침탄된 오스테나이트계 스데인리스강의 마모 및 부식 특성에 관한 연구)

  • Shin, Dong-Myung;Lee, Chang-Youl;Lee. Kyung-Sub
    • Korean Journal of Materials Research
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    • v.12 no.10
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    • pp.776-783
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    • 2002
  • Austenitic stainless steel (STS304) has been carburized using glow discharge plasma and its microstructure, wear resistance and corrosion property have been investigated. A repeat boost-diffuse carburizing was used as an effective plasma carburizing method. The effective case depth of the plasma carburized specimens was increased with the carbon concentration at the surface area. The specimens prepared by 3 hours plasma carburizing under $600^{\circ}C$ did not have the standard hardness for the effective case depth, but the specimen prepared by 11 hours plasma carburizing at $500^{\circ}C$ had nearly the same hardness with the specimen plasma carburized for 3 hours at $800^{\circ}C$. The wear resistance increased with temperature but the corrosion properties of the specimens prepared over $600^{\circ}C$ decreased rapidly due to the grain boundary sensitization. However, the specimen plasma carburized for 11 hours at $500^{\circ}C$ had nearly the same wear resistance with the specimen plasma carburized for 3 hours at $800^{\circ}C$ without deterioration of corrosion property. This could be resulted from the fact that the microstructure of the specimen plasma carburized for 11 hours at $500^{\circ}C$ was composed of martensite and austenite, because a partial martensite transformation was occurred only in the specimen plasma carburized for 11 hours at 50$0^{\circ}C$.

Improvement of anti-corrosive property for alloy plated steel sheet by UV curable organic-inorganic hybrid coatings (합금도금강판 내식성 향상을 위한 UV 경화형 유무기 하이브리드 코팅)

  • Park, Jongwon;Lee, Kyunghwang;Na, Hyunju;Park, Byungkyu;Nam, Yeungsub;Hong, Shinhyub
    • Corrosion Science and Technology
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    • v.12 no.1
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    • pp.27-33
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    • 2013
  • According to its merits about high curing speed and low emission of volatile organic compounds, UV curable inorganic-organic coating technology has been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. Based on the tetra-ethylorthosilicate(TEOS) and methacryloxypropyl trimethoxysilane(MPTMS), inorganic sol was synthesized and formed hybrid networks with UV curable acrylic monomer, 6-hexanediol diacrylate(HDDA), trimethylolpropane triacrylate(TMPTA), pentaerylthritol triacrylate(PETA). Several methods were used to test their properties such as salt spray test, potentiodynamic measurement, tape peel test, etc. It was shown that anti-corrosive property and stability of storage were affected by the molecular ratios of inorganic and organic compounds. It was not only the stability of storage, but had a excellent anti-corrosive, paint adhesive, and anti-solvent properties in a final molar ratios of 0.6/0.04/0.86/0.005 (TEOS/MPTMS/Acetone/HNO3) and 0.08/0.106/0.081/0.02 (TMPTA/HDDA/PETA/photo initiator).