• Title/Summary/Keyword: Corrosion property

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A Study on the corrosion property by post treatment in the metal dry etch (Metal 건식각 후처리에 따른 부식 특성에 관한 연구)

  • Mun, Seong-Yeol;Kang, Seong-Jun;Joung, Yang-Hee
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2007.10a
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    • pp.747-750
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    • 2007
  • This study proposes that chlorine residue after metal etch as the source of metal corrosion, and charges should be removed by optimizing etch, PR strip and cleaning condition. Charges distributed along the metal line acts as a source of tungsten (W) plug corrosion when associated with following cleaning solution. In cleaning process after metal etch and PR strip, chemical selection is significantly important in terms of metal corrosion. Optimal corrosion preventive PH, no metal attack (choice of optimal inhibitants), high by product removal efficiency and optimal de ionized water treatment condition is critical to the metal corrosion prevention.

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Investigation on surface hardening and corrosion characteristic by water cavitation peening with time for Al 5052-O alloy (5052-O 알루미늄 합금의 워터 캐비테이션 피닝 시간에 따른 표면 경화와 부식 특성에 관한 연구)

  • Kim, Seong-Jong;Hyun, Koang-Yong
    • Corrosion Science and Technology
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    • v.11 no.4
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    • pp.151-156
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    • 2012
  • The cavity formed by the ultrasonic generation in the fluid with the application of water cavitation peening collides into the metal surface. At this time, the surface modification effect such as the work hardening presents by the compressive residual stress formed due to the localized plastic deformation. In this investigation, the water cavitation peening technology in the distilled water with the lapse of time was applied to 5052-O aluminum alloy for aluminum ship of a high value. So, the optimum water cavitation peening time on the effect for surface hardening and anti-corrosion property was investigated. Consequently, the water cavitatin peening time on excellent hardness and corrosion resistance characteristic presented 3.5 min. and 5.0 min, respectively. The surface hardness in the optimum water cavitation peening time was improved approximately 45% compared to the non-WCPed condition. In addition, corrosion current density was decreased.

Corrosion Inhibition Properties of Steel bars in Reinforced Concrete Using Superplasticizer with Air Entrained Agent (고성능AE감수제를 사용한 콘크리트의 철근부식 저항성)

  • Lee, Mun-Hwan;Jung, Mi-Kyung;Oh, Se-Chul;Bae, Kyu-Woong;Seo, Chee-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.4 no.4
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    • pp.149-160
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    • 2000
  • As systematic methodologies are required for the evaluation on the durability of reinforced concrete structure, it is necessary to study and examine every factor which deteriorates the durability of structures. This paper aims to define factors affecting rebar corrosion and to establish a basis for a prediction of serviceability, regarding a state of harmful corrosion as a state when crack begins on the surface of concrete. The study results are followings; The corrosive current has changed by types of mixture, and this property enables the evaluations of corrosion resistance by mixture and concrete cover. The specimen using AE superplasticizer has better corrosion-resistance properties than non-AE specimen, as well those having low W/C and high unit cement weight. The procedure for calculation of durable year in this study is able to use as an indicator to establish mixture factors such as unit cement weight, W/C, amount of admixture, etc.

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Statistical Approach for Corrosion Prediction Under Fuzzy Soil Environment

  • Kim, Mincheol;Inakazu, Toyono;Koizumi, Akira;Koo, Jayong
    • Environmental Engineering Research
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    • v.18 no.1
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    • pp.37-43
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    • 2013
  • Water distribution pipes installed underground have potential risks of pipe failure and burst. After years of use, pipe walls tend to be corroded due to aggressive soil environments where they are located. The present study aims to assess the degree of external corrosion of a distribution pipe network. In situ data obtained through test pit excavation and direct sampling are carefully collated and assessed. A statistical approach is useful to predict severity of pipe corrosion at present and in future. First, criteria functions defined by discriminant function analysis are formulated to judge whether the pipes are seriously corroded. Data utilized in the analyses are those related to soil property, i.e., soil resistivity, pH, water content, and chloride ion. Secondly, corrosion factors that significantly affect pipe wall pitting (vertical) and spread (horizontal) on the pipe surface are identified with a view to quantifying a degree of the pipe corrosion. Finally, a most reliable model represented in the form of a multiple regression equation is developed for this purpose. From these analyses, it can be concluded that our proposed model is effective to predict the severity and rate of pipe corrosion utilizing selected factors that reflect the fuzzy soil environment.

Localized Corrosion Behavior of Inconel 718 in a Chloride-Containing Aqueous Solution (염수 환경에서 Inconel 718의 국부 부식 거동)

  • Lee, Jun-Seob;Lee, Yejin;Kwon, Soon il;Shin, Jungho;Lee, Je-Hyun
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.361-366
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    • 2021
  • Localized corrosion behavior of Ni-based Inconel 718 alloy was investigated by electrochemical anodic polarization techniques in NACE TM 0177 A solution of 5 wt% NaCl + 0.5 wt% acetic acid at room temperature. After the solution heat treated at 1080 ℃ for 2.5 h, Inconel 718 was age-hardened at 780 ℃ for 8 h. The microstructure of the alloy surface was investigated by optical microscopic or scanning electron microscopic technique. The austenitic phase with the presence of metal carbides was observed on the surface of Inconel 718. Metal-carbides such as Nb-Mo and Ti-carbide with diameters of approximately 10 and 3 ㎛, respectively, were formed in Inconel 718. Anodic polarization results revealed that localized corrosion was observed at the interface between austenitic phase of a substrate and metal carbides. Difference in electrochemical property between a metal carbide and an austenitic substrate could provide an initiation site for localized corrosion of Inconel 718 surface.

DISCOLORATION AND CORROSION RESISTANCE OF TiN-COATED ORTHODONTIC APPLIANCES PRODUCED BY ION-PLATING METHOD (Ion-plating법에 의하여 TiN 피막처리된 교정용 장치물의 변색성 및 내식성)

  • Kim, Jin-Hee;Kwon, Oh-Won;Choi, Young-Yun
    • The korean journal of orthodontics
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    • v.23 no.3 s.42
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    • pp.327-340
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    • 1993
  • The purpose of this study was to estimate the possibility of practical application of TiN ion-plating method on orthodontic appliances. TiN was coated on the surface of orthodontic stainless steel roll band by means of ion-plating method, and colorimetric properties of its obtained TiN film were investigated by using color analyzer. Also its corrosion and discoloration properties were compared with those of non ion-plated stainless steel roll band by using immersion test, which was done in 1N HCl solution for 10 days. Both weight changes and surface corrosion appearances of specimens for each day were respectively investigated by using electronic weighing machine and SEM(Scanning Electron Microscope). The discoloration degress of TiN-coated specimens immersed in 1N HCl solution were investigated by using color analyzer and then judged by N.B.S.(National Bureau of Standard) Unit. The results of this study were summarized as follows. o TiN ion-plated films showed the hue of 5Y, the value of 7, and the chroma of 3 by Munsell notations. o The weight losses and surface changes of TiN ion-plated specimens immersed in 1N HCl solution were less than those of non ion-plated specimens. It was shown, therefore, that the corrosion resistance was significantly improved by TiN ion-plating. o The discoloration degrees of non ion-plated specimens were too significant to be examined by color analyzer, while those of TiN ion-plated specimens were slight when judged by N.B.S. Unit. It was also apparent, therefore, that the anti-discoloration property was significantly improved by TiN ion-plating.

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Corrosion Resistance Characteristics of Cold Rolled Steel by Cr-free Green Organic/Inorganic Hybrid Coating Solution (크롬 프리 친환경 유/무기 하이브리드 코팅액에 의한 냉연강판의 내식특성)

  • Nam, Ki Woo;Kim, Jung Ryang;Choi, Chang Min
    • Journal of Ocean Engineering and Technology
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    • v.27 no.2
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    • pp.33-38
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    • 2013
  • In the past, a very popular method for reducing the corrosion on zinc involved the use of chemical conversion layer coatings based on $Cr^{+6}$. However, there is an important problem with using chromium salts as a result of restrictive environmental protection legislation. This study investigated the optimum condition for galvanized steel using an organic/inorganic solution with a Ti composition. In the case of a fixed heat treatment time, the corrosion resistance values of LR-0727(1) and LR-0727(2) were improved as the heat treatment temperature increased, and the optimum minimum temperature decreased with the heat treatment time. At the optimum heat treatment condition of two coating solutions, the heat treatment time of the LR-0727(1) solution was shorter than LR-0727(2) for the same heat treatment temperature. LR-0727(1) coated specimens did not show desquamation, and all of the specimens showed a good adhesive property. In contrast, in the case of the LR-0727(2) coated specimens, desquamation arose. Therefore, the adhesive property of LR-0727(1) was superior to that of LR-0727(2). The pencil hardness had a 3H average for all of the coating solutions and heat treatment conditions. In the case of a corrosion resistance test with boiling water, the coated specimens of LR-0727(1) were discolored, but LR-0727(2) was not. Finally, LR-0727(1) was more moisture proof than LR-0727(2).

Anti-Corrosion Property of Geopolymer Evaluated by an Impressed Current Cathodic Protection Method, Exposed to Marine Environment (염해환경에서 외부전원법에 의한 지오폴리머 시험체 보강철근의 방식특성 평가)

  • Lee, Hae-Seung;Cho, Ggu-Hwan;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.5
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    • pp.397-405
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    • 2014
  • There are many literatures reporting that the service life of re-bars in concrete structures is reduced in the oceanic environment due to chloride attack. To solve this problem, this study used geo-polymer as a mix material for concrete to increase its resistance to salt damage, and the external voltage method, one of the electric methods, is was applied to evaluate the likelihood of re-bars in the oceanic structure being exposed to the extreme salt environment. The items evaluated include the natural potential of re-bars and the corrosion rate. The results of the tests showed that in all of the salt environmental conditions (submerged zone, tidal zone, and crack), the tested materials were remarkably effective compared with ordinary concrete. The corrosion protective property was found not only in the evaluation of the natural potential but also in the evaluation of the corrosion rate, suggesting that the external voltage method can be used stably for geo-polymer RC structures in an extreme salt environment.

The Study on the Corrosion Property of the Zn-Mg Alloy Coatings with Various Mg Contents using EIS Measurement (EIS 분석을 통한 Mg 함량에 따른 Zn-Mg 박막의 부식 특성에 관한 연구)

  • Bae, Ki-Tae;La, Joung-Hyun;Kim, Kwang-Bae;Lee, Sang-Yul
    • Journal of the Korean institute of surface engineering
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    • v.47 no.6
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    • pp.330-334
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    • 2014
  • In this study, the Zn-Mg alloy coatings with various Mg contents were deposited using an unbalanced magnetron sputtering process. Their surface microstructure, chemical composition, phase, and corrosion property were investigated. The microstructure of the Zn-Mg coatings changed from porous microstructure to dense one with increasing Mg contents in the coatings. As Mg contents in coatings increased, intermetallic phases such as $Mg_2Zn_{11}$ and $MgZn_2$ were detected from X-ray diffraction (XRD) results. The corrosion resistance of the Zn-Mg alloy coatings was investigated quantitatively using electrochemical impedance spectroscopy (EIS) measurement with 3.5% NaCl solution. The results of EIS measurement showed that the charge transfer resistance and the phase angle of the Zn-Mg alloy coatings were increased from $162.1{\Omega}{\cdot}cm^2$ to $558.8{\Omega}{\cdot}cm^2$ and from about $40^{\circ}$ to $60^{\circ}$ with increasing Mg contents from 5.1 wt.% to 15.5 wt.% in the coatings. These results demonstrate that the Zn-Mg coatings with increasing Mg contents showed an enhanced corrosion resistance.

HCP Evaluation Considering Property of Cement Mortar and Steel Corrosion (건조 상태의 시멘트 모르타르 특성과 철근 부식량을 고려한 HCP 평가)

  • Ryu, Hwa-Sung;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.2
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    • pp.113-120
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    • 2017
  • HCP(Half Cell Potential) method has been widely used since it is recognized as a efficient NDT(Non Destructive Technique) for corrosion detection. This work is for an evaluation of relation between corrosion amount and measured HCP in dried condition through ICM(Impressed Current Method) for accelerating corrosion. For the work, cement mortar specimens with three w/c ratios and four cover depths are prepared, and corrosion test based on ICM is performed for 6 hours, 18 hour, and 42 hours with constant 20V of electrical charge, respectively. From the test, corrosion amount increases with reduced cover depth, increasing w/c ratio, and extended corrosion period, where corrosion amount is evaluated to linearly increases with measured HCP in dried condition. In order to evaluate corrosion amount through measured HCP, the measured HCP level is firstly determined and then corrosion amount is to be compared with measured HCP, which is evaluated to be more reasonable with higher C.O.V.