• 제목/요약/키워드: Corrosion of alumina

검색결과 67건 처리시간 0.021초

금속용사피막을 갖는 강재의 시멘트 모르타르 내 부식거동에 관한 실험적연구 (An Experimental Study on the Corrosion Behavior in the Steel Meterial Embedded in Cement Mortar with Metal Spray Method)

  • 박장현;김인수;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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    • pp.105-106
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    • 2017
  • The metal spray method, one of the surface anti-corrosion methods to prevent the corrosion of the steel material, does little effects on the material, while it can be used on a wider surface. However, metal spraying is used only in a limited environment, and research on the case of using with concrete is lacking. The purpose of this study was to observe the corrosion behavior of steels with metal spray coatings in concrete using electrochemical methods And to evaluate the performance of the method according to the type of metal used in the metal spray. As a result, the Al metal spray coating showed the best performance, because Aluminum is oxidized in the cement mortar and forms alumina oxide film.

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졸-겔법에 의한 알루미나 화이버의 ${\gamma}-LiAlO_2$ 코팅 (${\gamma}-LiAlO_2$ Coating on Alumina Fibers by the Sol-Gel Method)

  • 현상훈;홍성안;김완식;신현철
    • 한국세라믹학회지
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    • 제31권11호
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    • pp.1271-1282
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    • 1994
  • The surface of commercial alumina fibers used for reinforcing the MCFC matrix has been coated with ${\gamma}$-LiAlO2 being the same material as the matrix, by the sol-gel method in order to enhance the corrosion resistivity of alumina fibers. Stable LiAlO2 complex polymeric sols for coating was synthesized by mixing aluminum alkoxide polymeric sols with LiNO3 solution. It was found that the LiAlO2 polymeric sol prepared by adding the mixed chelate of acethylacetone and triethanolamine (the mole ratio of AA/TEA = 0.125/0.75) to the 1 mole of the aluminum alkoxide had the excellent stability and coating behavior. The crystalline structure of the dried gel from the ${\gamma}$-LiAlO2 sol was completely transformed into the ${\gamma}$-LiAlO2 at $600^{\circ}C$. The optimum viscosity of the sol for coating the alumina long fibers was 30~40 cP, while it was 12~20 cP in case of the short fiber coating. The ${\gamma}$-LiAlO2 coated alumina fibers without defects fully densified when heat-treated at 120$0^{\circ}C$.

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열 생성 알루미나 박막의 크리프 및 인장 특성 (Creep & Tensile Properties of Thermally Grown Alumina Films)

  • 고경득;선신규;강기주
    • 대한기계학회논문집A
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    • 제31권6호
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    • pp.665-670
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    • 2007
  • Alpha-phase alumina TGO(Thermally Grown Oxide) forms on the interface between zirconia top coat and bond coat of thermal barrier coating system for superalloys during exposure to high temperature over $1000^{\circ}C$. It is known to provide a good protection against hot corrosion and to cause surface failure such as rumpling and cracking due to difference in thermal expansion coefficient from the substrate metal and the lateral growth. Consequently, mechanical properties of the alumina TGO at the high temperature are the key parameters determining the integrity of TBC system. In this work, by using Fecralloy foils as the alumina forming substrate, creep tests and tensile tests have been performed with various TGO thicknesses$(h=0{\sim}4{\mu}m)$ and yttrium contents(0, 200ppm) at $1200^{\circ}C$. Displacement-time curves and load-displacement curves for each TGO thickness(h=1,2,..) were measured from the creep and tensile tests, respectively, and compared with the curves without TGO thickness(h=0). As the result, the intrinsic tensile and creep properties of TGO itself were determined.

소형선박용 프로펠러의 부식 녹 제거장치 개발 (Development of Corrosion Rust Removing Unit for Small Ship Propeller)

  • 김귀식;한세웅;현창해
    • 한국해양공학회지
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    • 제19권6호통권67호
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    • pp.72-77
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    • 2005
  • The materials used in a ship screw propeller are commonly made with brass. The seawater corrosion and seawater cavitation of the screw propeller reduces the propulsive performance of the ship. In screw manufacturing, the corrosion rust of the screw propeller is removed through a hand grinding method. The grinding process produces dust of the heavy metals from the brass. The dust creates a poor working environment that is harmful to the health of the workers. An automatic corrosionrust removing apparatus, using a blasting method, was developed for the improvement of screw polishing conditions and its working environment. The performance of this apparatus was investigated by surface roughness, weight loss rate, hardness, electrochemical corrosion resistance, and cavitation erosion, after removing of the corrosion rust under various blasting conditions. Two medias of alumina and emery were used in this experiment. The surface roughness and hardness of the screw were improved by this apparatus. The electrochemical corrosion potential (Ecorr) and current density (Icorr) were measured by the dynamic polarization method, using a potentiostat,under the conditions of surface polishing with grinding, blasting, wire brushing, and fine sand papering. The test results prove that the new corrosion rust-removing apparatus improves the surface performance of a screw propeller.

불소 첨가/미첨가 인공타액 용액에서 연마 및 마스킹 조건이 적층제조 Ti-6Al-4V 합금의 동전위분극시험 결과에 미치는 영향 (Effects of Grinding and Masking Conditions on the Potentiodynamic Polarization Curves of Additively Manufactured Ti-6Al-4V Alloy in Artificial Saliva Solution with or Without Fluoride Ions)

  • 안경빈;장희진
    • Corrosion Science and Technology
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    • 제20권6호
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    • pp.475-483
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    • 2021
  • Additively manufactured titanium alloy is one of the promising materials in advanced medical industries. However, these additively manufactured alloys show corrosion properties different from those of conventional materials due to their unique microstructure. In this study, the effect of surface roughness and masking conditions on the results of the potentiodynamic polarization tests on additively manufactured or conventional Ti-6Al-4V alloys in artificial saliva solution with or without fluoride was investigated. The results showed that the corrosion potential was slightly lower with a flat cell with an O-ring than with masking tape. The corrosion rate was decreased with decreases in the surface roughness. Localized corrosion involving delamination of the surface layer occurred at 7 ~ 9 V (SSC) on the additively manufactured alloy in solution with or without fluoride when the samples were finished with 1000-grit SiC paper, whereas localized corrosion was not observed in the specimens finished with 1-㎛ alumina paste.

고Alumina질 다공성 세라믹스의 내열충격성 및 내Slag성 (기공크기에 따른) (Thermal Spalling and Resistance to Slag Attack in Porous High Alumina Ceramic (According to Pore Size))

  • 김병훈;나용한
    • 한국세라믹학회지
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    • 제30권9호
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    • pp.747-753
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    • 1993
  • The investigation was carried out to study the behaviors of the pore size and porosity, the mechanical strength, the resistance to thermal spallings and slag attacks according to particle sizes of starting raw materials in porous high Alumina ceramics. This porous ceramics have been used in processing of the clean steel by the blowing of the inert gas. The required properties in the practice are the suitable pores size, the sharp pores distribution for a uniform blowing of the gas, the strong corrosion resistance to slags and molten metals and the resistance to thermal spalling. The optimized properties in porous high alumina ceramics of the specimen No. 3 was found to be the very low slag intrusion and the superior resistance to thermal spalling because of the suitable pore size of 2.5${\mu}{\textrm}{m}$, the porosity of 30% and the high sinterability.

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알루미나 시멘트 콘크리트의 철근 부식 저항성 (The corrosion behaviour of steel in high alumina cement concrete)

  • 이호재;김재환;안기용;송하원
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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    • pp.289-290
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    • 2009
  • 본 연구는 알루미나 시멘트 콘크리트(CAC)를 이용하여 염화물의 대한 철근 부식의 저항성을 압축 강도, 염분 침투, 부식을 각각 실험을 통하여 측정하였다. 알루미나 시멘트가 보통 포틀랜드 시멘트(OPC)보다 철근 부식 저항성이 뛰어난 결과가 나왔다.

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소형 스크류 프로펠라의 부식제거장치 개발 (Development of Corrosion Removing Unit for Small Screw Propeller)

  • 김귀식;한세옹;현창해
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.260-265
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    • 2004
  • The materials of ship screw propeller are commonly the manganese bronze. The seawater corrosion and cavitation of the screw propeller reduce tire propulsive performance of ship. In screw manufactory, tire corrosion rust of tire screw propeller is removed by a hand grinding. The grinding work makes the dust of the heavy metals from the manganese bronze. The dust makes indoor working environment poor. A friendly-environmental and automatic corrosion removing apparatus was developed for the improvement of screw processing and working environment. The corrosion rust of a screw propeller was remarkably removed by using apparatus. And the screw surface roughness was improved by a blasting effect of the apparatus performance test. Anode polarization curves on jour processing conditions, that is to say, grinding, blasting, wire-brushing, fine sand papering, were confirmed by a potentiostat. Especially, two kinds of medias, alumina and emery, were used in the blasting processing. Then, investigated tire cavitation erosion of specimen. This result proved that tire blasting work has considerably improved the corrosion resistance of a screw propeller.

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산화물 피복강재의 밀착성과 내식성에 관한 연구 ( 1 ) (Studies on the Adherence and Corrosion Resistance of Oxide Coated Materials ( 1 ))

  • 이종락;임우조
    • 수산해양기술연구
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    • 제32권2호
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    • pp.157-163
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    • 1996
  • To ceramic film, $SiO_2$ and $Al_2O_3$, coated on pure Fe and stainless steel(SUS41O) by RF magnetron sputtering, the adherence between mm and substarte was studied. The adherence index (${\chi}$) was determined by the measure of micro hardness test. Also, the corrosion resistance on oxide coatings was studied using electrochemical measurement. The main results obtained are as the following: 1) In the micro-hardness test, with $1{\mu}m$ thickness mm, it has only one the value of ${\chi}$. Above $2{\mu}$thickness fIlm, however, get another value of ${\chi}$as the cracks in fIlm. 2) The oxide fIlm adhere well on the mild materials such as pure steel than high intensity materials like stainless. 3) Alumina($Al_2O_3$) coated materials have better corrosion resistance than silica($SiO_2$)coated materials

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Assessment Corrosion and Bioactive Behavior of Bioglass Coating on Co-Cr-Mo Alloy By Electrophoretic Deposition For Biomedical Applications

  • Areege K. Abed;Ali. M. Mustafa;Ali M. Resen
    • Corrosion Science and Technology
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    • 제23권3호
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    • pp.179-194
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    • 2024
  • A layer-by-layer coating was produced using electrophoretic deposition for a HA/Al2O3 coating layer and a bioglass coating layer on Co-Cr-Mo alloy with a roughness of 0.5 ㎛ (400 emery paper SiC). The corrosion behaviour was analyzed by assessing the coating layers' exceptional corrosion resistance, which outperformed the substrate. Cr ion release test using AAS was carried out, indicating that factional graded coating inhibited ion release from the uncoated substrate to coated sample. The porosity was expressed as a percentage, representing the extent of imperfections on the surface of all coatings. These imperfections fell within an acceptable range of 1% to 3%. The roughness of the coated surface was measured using atomic force microscopy, which revealed an excellent roughness value of 3.32 nm. Tape test technique for adhesion revealed that the removal area of the substrate coating layer varied by 11.92%. X-ray diffraction analysis confirmed the presence of all coating material peaks and verified phases of the deposited coating layers. These findings provided evidence that the coating composition remains unaffected by the electrophoretic deposition process. The bioactivity was assessed by immersion in a simulated bodily fluid, which revealed the formation of HCA during a period of 5 days.