• Title/Summary/Keyword: Corrosion effect

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The Effect of Corrosion Inhibitors on Antimicrobial Activity of Biocide in Water-soluble Cutting Fluid (수용성 절삭유에서 방청제가 방부제의 항균효능에 미치는 영향)

  • 김현주;김성배
    • KSBB Journal
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    • v.18 no.5
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    • pp.393-397
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    • 2003
  • The effect of corrosion inhibitors on antimicrobial activity of biocides (Kathon 886 MW, Triadine 3, Triadine 10 and Grotan BK) was investigated using the Pseudomonas aeruginosa which frequency of occurrence in contaminated fluids is very high and its growth and survival is excellent. When a biocide was used with a corrosion inhibitor, the antimicrobial activity of it was affected by the corrosion inhibitor used. The antimicrobial activity of Kathon 886 MW increased when corrosion inhibitor (each of SS 510, MEA) was used. Triadine 3, Triadine 10, Grotan BK showed the similar trend of antimicrobial effect for the corrosion inhibitors used. Their antimicrobial activities increased when the corrosion inhibitor such as CP-105, CP-E-7 and MEA was used individually. The antimicrobial activity of each corrosion inhibitor was also compared. The results showed that CP-E-7 and MEA was bioresistant and the other corrosion inhibitors were biosupportive. The antimicrobial activity of biocides was in the order of Triadine 10 < Triadine 3 < Kathon 886 MW < Grotan BK.

Effect of Sigma Phase on Electrochemical Corrosion Characteristics of a Deposited Metal of ER2594 (ER2594 용착금속의 전기화학적 부식특성에 미치는 시그마상의 영향)

  • Jung, Byong-Ho;Kim, Si-Young;Seo, Gi-Jeong;Park, Joo-Young
    • Journal of Power System Engineering
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    • v.19 no.6
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    • pp.75-81
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    • 2015
  • A deposited metal specimen of ER2594 which is a super duplex steel welding wire used to investigate the effect of sigma(${\sigma}$) phase on electrochemical corrosion characteristics was prepared by gas tungsten arc welding. Aging treatment was conducted for the specimen at the temperature range of $700^{\circ}C$ to $900^{\circ}C$ for 5 to 300 minutes after annealing at $1050^{\circ}C$. Corrosion current density has decreased a little with an increase of aging time over 60 minutes at $700^{\circ}C$ to $900^{\circ}C$ and the uniform corrosion of deposited metal had more influence on the precipitation of ferrite than the precipitation of sigma phase. Therefore, the precipitation of sigma phase did not have much effect on the uniform corrosion. Pitting potential representing pitting corrosion has shown decreasing tendency as the precipitation of sigma phase increased. The degree of sensitization representing intergranular corrosion has shown increasing tendency as the precipitation of sigma phase increased at $700^{\circ}C$ to $800^{\circ}C$, while it has decreased at $900^{\circ}C$ for 60 to 300 minutes.

Effect of Welding Thermal Cycle on Microstructure and Pitting Corrosion Property of Multi-pass Weldment of Super-duplex Stainless Steel (슈퍼 듀플렉스 스테인리스강 다층용접부의 미세조직 및 공식(Pitting Corrosion)에 미치는 용접열사이클의 영향)

  • Nam, Seong-Kil;Park, Se-Jin;Na, Hye-Sung;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.28 no.4
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    • pp.18-25
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    • 2010
  • Super-duplex stainless steels (SDSS) have a good balance of mechanical property and corrosion resistance when they consist of approximately equal amount of austenite and ferrite. The SDSS needs to avoid the detrimental phases such as sigma(${\sigma}$), chi(${\chi}$), secondary austenite(${\gamma}2$), chromium carbide & nitride and to maintain the ratio of ferrite & austenite phase as well known. However, the effects of the subsequent weld thermal cycle were seldom experimentally studied on the micro-structural variation of weldment & pitting corrosion property. Therefore, the present study investigated the effect of the subsequent thermal cycle on the change of weld microstructure and pitting corrosion property at $40^{\circ}C$. The thermal history of root side was measured experimentally and the change of microstructure of weld root & the weight loss by pitting corrosion test were observed as a function of the thermal cycle of each weld layer. The ferrite contents of root weld were reduced with the subsequent weld thermal cycles. The pitting corrosion was occurred in the weld root region in case of the all pitted specimen & in the middle weld layer in some cases. And the weight loss by pitting corrosion was increased in proportional to the time exposed at high temperature of the root weld and also by the decrease of ferrite content. The subsequent weld thermal cycles destroy the phase balance of ferrite & austenite at the root weld. Conclusively, It is thought that as the more subsequent welds were added, the more the phase balance of ferrite & austenite was deviated from equality, therefore the pitting corrosion property was deteriorated by galvanic effect of the two phases and the increase of 2nd phases & grain boundary energy.

The Effect on the Wear-Corrosion Behavior of Ductile Cast Iron in the Various pH Environments (구상흑연주철재의 마멸-부식특성에 미치는 pH의 영향)

  • 임우조;박동기
    • Tribology and Lubricants
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    • v.19 no.1
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    • pp.31-35
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    • 2003
  • This paper reports the studies on the wear-corrosion behavior of ductile cast iron in the various pH environments. In the variety of pH solutions, corrosion and wear-corrosion loss of GCD 600 were investigated. Also, the anodic polarization test of GCD 600 using potentiostat/galvanostat was carried out. And rubbed surface of GCD 60 using scanning electron micrographs after immersion and wear-corrosion test was examined in the environment of various pH values. The main results are as following In alkali zone, the wear-corrosion loss of GCD 600 increases, but corrosion loss decreases. The unevenness and crack of wear-corrosion surface in neutral zone becomes duller than that in alkali zone. As the corrosive environment is acidified, wear-corrosion behavior of GCD 600 with passing immersion time becomes sensitive.

Crevice Corrosion Resistance of Stainless Steels in Natural Sea Water with different Post Welding Treatment

  • Lee, Y.H.;Kim, Y.H.;Kim, H.
    • Corrosion Science and Technology
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    • v.2 no.5
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    • pp.219-224
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    • 2003
  • Crevice corrosion of stainless steels in natural seawater was investigated for several post weld treatments; as-annealed, as-welded, pickled, and ground. The results confirmed the effect of the biofilm on the cathodic reaction leading to an ennoblement of the rest potential. The degree of ennoblement of corrosion potential depends on the surface finish. As-annealed and pickled samples show stable corrosion potential approaching to 200 ~ 300 mV (SCE) while as-welded and ground samples show the fluctuating corrosion potential. This points to a situation where there are conflicting effects determining the trend in free corrosion potential. Crevice corrosion initiation will tend to pull the free corrosion potential in the active direction, whereas the presence of biofilm will tend to ennoble corrosion potential. There was no visible attack on UNS S31803, S32550, and 2205W. Therefore, those stainless steel grades appeared to be resistant to crevice corrosion in natural seawater on condition of weld metal.

Effect of Si Addition on the Corrosion Resistance of Diamond-Like Carbon (DLC) Films

  • Kim, Woo-Jung;Kim, Jung-Gu;Park, Se-Jun;Lee, Kwang-Ryeol
    • Corrosion Science and Technology
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    • v.4 no.6
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    • pp.226-230
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    • 2005
  • Si incorporated diamond-like carbon (Si-DLC) films ranging from 0 to 2 at.% contents were deposited on STS 316L substrates for orthopedic implants by means of r.f. plasma-assisted chemical vapor deposition (r.f. PACVD) technique, using mixtures of benzene ($C_6H_6$) and silane ($SiH_4$) as the precursor gases. This study provides the reliable and quantitative data for assessment of the effect of Si incorporation on corrosion property in the simulated body fluid environment through the electrochemical test. It was found that corrosion to resistance of Si-DLC coatings with increasing Si content are improved owing to high $sp^3$ bonding.

A Study on Anti-Corrosion Effect of Powder Self Water Proof Admixture Mixed Corrosion Inhibitor for Reinforcing Steel (철근부식억제형 구체방수재의 방청효과에 관한 연구)

  • 신도철;손형호;김원화
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.409-414
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    • 2002
  • This study is intended to develop the self water proof admixture for durability concrete by anti-corrosion inhibitor. Chloride induced corrosion of reinforcement is one of the main factor which cause the deterioration of concrete structure. When the substitute anti-corrosion agents for a part of self waterproofing agent, the corrosion-proof increases for the increased water proofing capacity. And proper self waterproofing agent by cement weight in concrete was generally positive effect to concrete compressive strength, slump, freezing and thawing resistance. Also, permeability and absorption show a straight decrease when self waterproofing agent is added.

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Development of Integrity Assessment System for the Pipeline (파이프라인의 건전성 평가 시스템 개발)

  • Lee, Eok-Seop;Hwang, In-Hyeon
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.12
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    • pp.157-162
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    • 2000
  • The object of this work is to develop an assessment system for pipeline integrity. the system consists of four module applications for internal algorithm; the effect of corrosion in pipeline, crack, stress corrosion crack (SCC) and fatigue modules. Presently, the module of the external corrosion has been developed and the internal algorithm for the effect of corrosion in pipeline and the database of the system are described in this paper. The database of the system is separated to mainly four parts; geometry of pipeline, material properties, boundary conditions and general properties. Each components of the system are designed by user-friendly concept. This system may give a guideline for maintenance and modifications for the pipeline at the industrial sight. Furthermore, a procedure to evaluate an inspection interval is also provided.

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Seismic damage estimation of reinforced concrete framed structures affected by chloride-induced corrosion

  • Anoop, M.B.;Rao, K. Balaji
    • Earthquakes and Structures
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    • v.9 no.4
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    • pp.851-873
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    • 2015
  • A methodology for estimation of statistical properties (viz. mean and standard deviation) of the expected seismic damage to reinforced concrete framed structures subject to corrosion of reinforcement, over a specified reference time (typically the service life of the structure) is proposed in this paper. The damage to the structure under the earthquake loading is characterised by the damage index, determined using the modified Park and Ang damage model. The reduction in area, yield strength and strain at ultimate of steel reinforcement, and the reduction in compressive strength of cover concrete due to corrosion are taken into account in the estimation of damage. The proposed methodology is illustrated through an example problem. From the results obtained, it is noted that there is an increase of about 70% in the mean value of expected seismic damage to the reinforced concrete frame considered over a reference time of 30 years when effect of corrosion is taken into consideration. This indicates that there is a need to consider the effect of corrosion of reinforcement on the estimation of expected seismic damage.

Effect of Microstructure on Corrosion Behavior of TiN Hard Coatings Produced by Two Grid-Attached Magnetron Sputtering

  • Kim, Jung Gu;Hwang, Woon Suk
    • Corrosion Science and Technology
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    • v.5 no.1
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    • pp.15-22
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    • 2006
  • The introduction of two-grid inside a conventional process system produces a reactive coating deposition and increases metal ion ratio in the plasma, resulting in denser and smoother films. The corrosion behaviors of TiN coatings were investigated by electrochemical methods, such as potentiodynamic polarization test and electrochemical impedance spectroscopy (EIS) in deaerated 3.5% NaCl solution. Electrochemical tests were used to evaluate the effect of microstructure on the corrosion behavior of TiN coatings exposed to a corrosive environment. The crystal structure of the coatings was examined by X-ray diffractometry (XRD) and the microstructure of the coatings was investigated by scanning electron microscopy (SEM) and transmission electron spectroscopy (TEM). In the potentiodynamic polarization test and EIS measurement, the corrosion current density of TiN deposited by two grid-attached magnetron sputtering was lower than TiN deposited by conventional magnetron type and also presented higher Rct values during 240 h immersion time. It is attributed to the formation of a dense microstructure, which promotes the compactness of coatings and yields lower porosity.