• Title/Summary/Keyword: Corrosion characteristics

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A Study on the Galvanic corrosion and its Protection on Heat Exchanger Tube Plate (열교환기 관판의 전지작용부식과 방지에 관한 연구)

  • U-J Lim;S-H Hong;B-D Yun
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.2
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    • pp.345-345
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    • 2001
  • This paper was studied on the characteristics of galvanic corrosion and its protection on heat exchanger tube plate in the sea water. In this paper, behavior of pitting corrosion of Ni-al bronze connected with Ti tube was measured af flow velocity of 0 m/s and 2.4 m/s. To protect galvanic corrosion, the protection characteristics of Ni-Al bronze connected with Ti tube by Zn-base alloys galvanic anode and hexagonal nylon insert was investigated. Main results obtained asre al follows: 1) The galvanic corrosion of Ni-Al bronze connected with Ti-tube is more active than single Ni-al bronze. 2) As the circuit resistance increase under the cathodic protection employing Zn-base alloys galvanic anode, Ni-al bronze connected with Ti tube is cathodically unpolarized. 3) The corrosion of Ni-Al bronze connected with Ti tube by nylon insert controls approximately 73% than not nylon insert.

Effect of Corrosion on Fatigue Life of Piping material under Repeating Load (반복하중을 받는 배관용 강재의 피로수명에 미치는 부식의 영향)

  • Park, Keyung-Dong;An, Jae-Pil
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.228-229
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    • 2005
  • The compressive residual stress, which is induced by shot peening process, has the effect of increasing the intrinsic fatigue strength of surface and therefore would be beneficial in reducing the probability of fatigue damage. However, it was not known that the effect of shot peening in corrosion environment. In this study, the effect of shot peening on corrosion fatigue crack growth of sping steel immersed in 6% $FeCl_3$ solution and corrosion characteristics with considering fracture mechanics. The results of the experimental study corrosion fatigue characteristics of spring steel are as follows; the fatigue crack growth rate of the shot peening material was lower than of the un peening material. And fatigue life shows more improvement in the shot peening material than un peening material. This is because the compressive residual stress of surface operate resistance of corrosion fatigue crack propagation. It is assumed that the shot peening process improve corrosive resistance and mechanical property.

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A Study on the Characteristics for AC Corrosion of Gas Pipelines (가스배관의 교류부식 특성에 관한 연구)

  • Bae Jeong-Hyo,;Ha Tae-Hyun,;Lee Hyun-Goo,;Kim Dae-Kyeong,
    • Journal of the Korean Institute of Gas
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    • v.5 no.3 s.15
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    • pp.29-35
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    • 2001
  • Direct current corrosion have being investigated by lots of scientists but alternating current corrosion was ignored because the corrosion rate by AC was very small. Recently however, AC corrosion accidents have been reported in many other countries. So the study of AC corrosion is to be necessary In these days. In this paper, several experiments which intentionally imposed the AC or DC to the specimens also imposed AC and DC at the same time was carried out in the laboratory to examine the AC corrosion characteristics and in addition applied the same way in the field. Moreover, while the field investigations of the abnormal corrosion failures, It was the AC that caused one of corrosion failures.

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Stochastic characteristics of reinforcement corrosion in concrete beams under sustained loads

  • Huang, Le;Jin, Xianyu;Fu, Chuanqing;Ye, Hailong;Dong, Xiaoyu
    • Computers and Concrete
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    • v.25 no.5
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    • pp.447-460
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    • 2020
  • This paper deals with the characteristics of reinforcement corrosion in concrete beams under the influence of sustained loads. The evolution and distribution laws of the reinforcement corrosion were measured periodically over time. The results show that sustained load exhibits a pronounced exacerbating effect on the reinforcement corrosion, and enlarges the nonuniformity level of corrosion as the load level increases. Accompanied with the continuous formation of the rust, the corrosion rate was also observed to be highly nonlinear and time-dependent. Moreover, to visually and quantitatively analyze the distribution of reinforcement corrosion, the 3D scanning technology combined with the probability statistics analysis was adopted, and the observed nonuniformity can be well described by the Gumbel distribution. Finally, an approach based on the three-phase spherical model was proposed to estimate the reinforcement corrosion, taking account of the effects of sustained load on the changes of concrete porosity and oxygen diffusivity.

Corrosion Characteristics of Welding Zones by Laser and TIG Welding of 304 Stainless Steel

  • Moon, Kyung-Man;Lee, Myung-Hoon
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.294-299
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    • 2010
  • Two types of welding methods were performed on austenitic 304 stainless steel: laser welding and TIG welding. The differences of the corrosion characteristics of the welded zones from the two welding methods were investigated with electrochemical methods, such as measurement of the corrosion potential, polarization curves, cyclic voltammogram, etc. The vickers hardness of all laser-welded zones (WM:Weld Metal, HAZ:Heat Affected Zone, BM:Base Metal) was relatively higher while their corrosion current densities exhibited a comparatively lower value than those which were TIG welded. In particular, the corrosion current density of the TIG-welded HAZ had the highest value among all other welding zones, which suggests that chromium depletion due to the formation of chromium carbide occurs in the HAZ, which is in the sensitization temperature range, thus it can easily be corroded with an active anode. Intergrenular corrosion was also observed at the TIG-welded HAZ and WM zones. Consequently, we can see that corrosion resistance of all austenitic 304 stainless steel welding zones can be improved via the use of laser welding.

A Study on Characteristics of the Electrochemical Corrosion of Weld Zone for Refrigerating and Heating Systems Pipe (냉난방용 배관 용접부의 전기화학적 부식특성에 관한 연구)

  • Lim, Uh-Joh;Yun, Byoung-Du;Kim, Hwan-Sik
    • Journal of Fisheries and Marine Sciences Education
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    • v.19 no.1
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    • pp.84-90
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    • 2007
  • This paper was studied on the electrochemical corrosion characteristics of weld zone for refrigerating and heating systems pipe. Austenitic stainless steel is widely applied to various fields of industry, because it is good to corrosion resistance and mechanical properties. But STS 304 is reliable to sensitization by heat cycle on welding. Therefore, in this study, electrochemical polarization test of STS 304 steel pipe manufactured by arc welding in tap water was carried out. And then polarization resistance behavior, uniform and local corrosion behaviors of base metal(BM), weld metal(WM) and heat affected zone(HAZ) for STS 304 pipe were investigated. The corrosion current density of STS 304 steel pipe is high in order of BM(153nA/cm2) < WM(614nA/cm2) < HAZ ($1.675{\mu}A/cm2$). The pitting potential of HAZ(238mV/SCE) for STS 304 is lower than BM(1206mV/SCE) and WM(369mV/SCE). Therefore, the local corrosion like pitting corrosion, galvanic corrosion and crevice corrosion of HAZ for STS 304 is more sensitive than BM and WM.

Corrosion Characteristics of Diffusion Barrier in Copper CMP (구리 CMP시 확산방지막의 부식특성)

  • Lee, Do-Won;Kim, Nam-Hoon;Lim, Jong-Heun;Kim, Sang-Yong;Lee, Chul-In;Chang, Eui-Gu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.162-165
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    • 2003
  • The corrosion characteristics of diffusion barrier in Copper CMP has been investigated. Key experimental variables that has been investigated are the corrosion rate by different agents containing slurry of Cu CMP. Whenever Cu and Ta films were corroded adding each oxidizer, the corrosion rate of Ta was much lower than that of Cu. That is, the difference in the corrosion rates of Ta by oxidizer was not larger as compared with Cu. As corroded by complexing agents, the corrosion rate of Ta was close to O. The corrosion rate of Ta increased as added $HNO_3$ and $CH_3COOH$ compared with the reference slurry; on the other hand, it decreased with addition of HF. In addition, resulting corrosion rate went up with lower pH of agent. The corrosion rates by agents were however significant small; hence, it doesn't affect on the removal rate of Cu CMP practically. Consequently, this can be explained by assuming that the mechanical effect dominates than the chemical effect on the polishing rate of Ta(TaN).

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Effects of Cladding and Antifreeze Solution on Cavitation Corrosion of AA3003 Tube of Heat Exchanger for Automobile

  • Young Ran Yoo;Seung Heon Choi;Hyunhak Cho;Young Sik Kim
    • Corrosion Science and Technology
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    • v.23 no.3
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    • pp.203-214
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    • 2024
  • A heat exchanger is a device designed to transfer heat between two or more fluids. In a vehicle's thermal management system, Al heat exchangers play a critical role in controlling and managing heat for efficient and safe operation of the engine and other components. The fluid used to prevent heat exchangers from overheating the engine is mostly tap water. Heat exchange performance can be maintained at sub-zero temperatures using a solution mixed with antifreeze. Although the fluid flowing through the heat exchanger can reduce the temperature inside the engine, it also has various problems such as cavitation corrosion. Cavitation corrosion characteristics in tap water and corrosion characteristics were evaluated in this study when antifreeze was added for test specimens where AA4045 was cladded on the inner surface of AA3003 tubes of a fin-type heat exchanger. The cavitation corrosion resistance of AA3003 was found to be superior to that of AA4045 regardless of the test solution due to higher corrosion resistance and hardness of AA3003 than those of AA4045. The cavitation corrosion rate of Al alloys increased with the addition of antifreeze.

Evaluation of Characteristic for SS400 and STS304 steel by Weld Thermal Cycle Simulation - 2nd Report: Corrosion Characteristics (용접열사이클 재현에 의한 SS400강 및 STS304강의 특성 평가 -제2보: 부식특성)

  • Ahn, Seok-Hwan;Choi, Moon-Oh;Kim, Sung-Kwang;Son, Chang-Seok;Nam, Ki-Wook
    • Journal of Ocean Engineering and Technology
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    • v.21 no.5
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    • pp.33-38
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    • 2007
  • The welding methods have been applied in the most structural products from multi-field of automobile, ship construction and construction, and so on. The structure steel must have enough strength of structure. In this study, SS400 steel and STS304 steel were used to estimate the corrosion characteristics of the weld thermal cycle simulated HAZ. To evaluate the corrosion characteristics, also, the materials with two conditions were used in 3.5% NaCl. The one is to the drawing with diameter of ${\Phi}10$ and the other is to the residual stress removal treatment. The electrochemical polarization test and immersion test were carried out. From test results, corrosion potential, corrosion current density, weight loss ratio and corrosion rate were measured. In the kinds of SS400 steels, corrosion potential of weld thermal cycle simulated specimens after the heat treatment showed somewhat the direction of noble potential. And in the base metal to be drawing weight loss ratio and corrosion rate occurred higher than the other kinds. In the kinds of STS304 steels, the result of base metal to be drawing was similar to results of SS400 steels, too. Two kinds of $750^{\circ}C$ and $1300^{\circ}C$ of weld thermal cycle simulation after the heat treatment were rather higher than the other kinds in weight loss ratio and corrosion rate.

Corrosion Characteristics of Gold-Coated Silver Wire for Semiconductor Packaging (반도체 패키징용 금-코팅된 은 와이어의 부식특성)

  • Hong, Won Sik;Kim, Mi-Song;Kim, Sang Yeop;Jeon, Sung Min;Moon, Jeong Tak;Kim, Youngsik
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.289-294
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    • 2021
  • In this study, after measuring polarization characteristics of 97.3 wt% Ag, Au-Coated 97.3 wt% Ag (ACA) and 100 wt% Au wires in 1 wt% H2SO4 and 1 wt% HCl electrolytes at 25 ℃, corrosion rate and corrosion characteristics were comparatively analyzed. Comparing corrosion potential (ECORR) values in sulfuric acid solution, ACA wire had more than six times higher ECORR value than Au wire. Thus, it seems possible to use a broad applied voltage range of bonding wire for semiconductor packaging which ACA wire could be substituted for the Au wire. However, since the ECORR value of ACA wire was three times lower than that of the Au wire in a hydrochloric acid solution, it was judged that the use range of the applied voltage and current of the bonding wire should be considered. In hydrochloric acid solution, 97.3 wt% Ag wire showed the highest corrosion rate, while ACA and Au showed similar corrosion rates. Additionally, in the case of sulfuric acid solution, all three types showed lower corrosion rates than those under the hydrochloric acid solution environment. The corrosion rate was higher in the order of 97.3 wt% Ag > ACA > 100 wt% Au wires.