• Title/Summary/Keyword: Corrosion behavior

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Comparison of Welding Characteristics on Heat input Changing of Laser Dissimilar Metals Welding (레이저 이종용접에서의 입열량 변화에 대한 용접특성 비교)

  • Shin H.J.;Yoo Y.T.;Shin B.H.;Ahn D.G.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.997-1003
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    • 2005
  • Laser welding of dissimilar metals has been widely used to improve a wear resistance and a corrosion resistance of the industrial parts. The objective of this research works is to investigate the influence of the process parameters, such as the welding for SM45C and STS304 with CW Nd:YAG lasers. The bead-on-plate welding tests are carried out for several combinations of the experimental conditions. In order to quantitatively examine the characteristics of the dissimilar welding, the welding qualify of the cut section, stain-stress behavior and the hardness of the welded part are investigated. From the results of the investigation, it has been shown that the optimal welding condition without defects in the vicinity of the welded area and with a good welding quality is 1600W of the laser power, 0.85m/min of welding speed and 4m/min of pressure for shielding gas.

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Fatigue Crack Propagation Characteristics of Duplex-Stainless Steel Weldment (III) (2상계 스테인리스강 용접부의 피로크랙전파 특성 (III))

  • 이택순;권종완
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.901-910
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    • 1989
  • Corrosion fatigue crack propagation behavior of duplex stainless steel weldments in substitute ocean water was investigated to evalulate effects of micro-structural change and residual stresses. Fatigue crack propagation rate was found influenced markedly .alpha./.gamma. phase ratio but little by residual stresses. Fatigue crack propagation rate is higher in the corrosive environment than in room atmosphere. The crack propagation rate estimated by the measurement of striation spacing was higher than that, obtained by crack length measurement in low .DELTK.K region. At hight .DELTK.K region, however, both crack propagation rates were found to be identical.

A Study on Formation and Evaluation of he Thin Films for Improvement of Tribology Properties (Tribology특성 향상을 위한 Ag 박막의 형성과 평가에 관한 연구)

  • 이경황;이상기;송복한;정병진;박창남;문경만;이명훈
    • Journal of the Korean institute of surface engineering
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    • v.33 no.5
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    • pp.319-328
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    • 2000
  • Silver is known to have such characteristics as low shear strength, good transfer-film forming tendency, and good corrosion resistance. Silver thin films have been prepared by ion plating of physical vapour deposition (PVD) using both argon gas pressure and bias voltage of processing condition. After the silver films were prepared, the properties in them were examined by gas pressure and bias voltage of substrate. Their morphology and crystal orientation were investigated by scanning electron microscopy (SEM) and X-ray diffractor. The properties of film were, also, studied to relate with morphology, X-ray diffraction pattern, and friction coefficient at vacuum ambient. The friction coefficient was stabilized remarkably on deposited films with increasing argon pressure for deposition. Also, the effect of increasing of the bias voltage for deposition resulted in lower friction coefficient and stability in $1.7$\times$10^{-4}$ torr. On the contrary, behavior of friction coefficient was stabilized on deposited films with decreasing the bias voltage in $1.7$\times$10^{-5}$ torr for deposition.

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Effects of phosphating bath compositions on the formation and structure of zinc phosphate conversion coatings on magnesium alloy AZ31

  • Phuong, Nguyen Van;Lee, Kyuhwan;Chang, Doyon;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.322-323
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    • 2012
  • This study discussed the formation of phosphate conversion coatings on AZ31 Mg alloy (AZ31) from the zinc phosphating bath with various concentrations of sodium fluoride (NaF). The effects of NaF on the formation, structure, composition and electrochemical behavior of the phosphate coatings were examined using scanning electron microscopy (SEM), X-ray diffraction (XRD) weight balances, open circuit potential (OCP) transients, potentiodynamic polarization curves and immersion test. The coatings were composed of two layers: an outer $Zn_2(PO_4)_3.4H_2O$ (hopeite) crystal layer and an inner amorphous of $MgZn_2(PO_4)_2$. NaF concentration is emphasized to be highly effective in the formation of the hopeite crystal and etching and coating rates. Potentiodynamic polarization and immersion test showed that the coatings formed in the zinc phosphating bath with addition of NaF have much higher corrosion resistance than bare AZ31.

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Effect of Weld Improvement on the Corroded Fatigue Life of Welded Structures (용접구조물의 부식피로수명에 미치는 용접부 개선처리 효과)

  • Im, Sung-Woo;Chang, In-Hwa;Kim, Sang-Shik;Song, Ha-Cheol
    • Journal of Ocean Engineering and Technology
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    • v.22 no.2
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    • pp.50-57
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    • 2008
  • The effect of weld improvement on the corroded fatigue life of welded structures was investigated. Toe grinding, TIG dressing and weld profiling were used as the geometric improvement methods. Fatigue tests under the corroded condition in artificial seawater were carried out to investigate the corrosion fatigue behavior of API 2W Gr.50T steel plate produced by POSCO. The test results in weld improved conditions were compared with those in as-welded condition. The test results were also compared with the design curves in UK DEn Class F. Corroded fatigue life of weld improved specimens was longer than that of as-welded specimen. Especially, the corroded fatigue life exceeded the mean SN curve in air of UK DEn Class F.

Electrochemical Characteristics of HA Film on the Ti Alloy Using Pulsed Laser Deposition

  • Jeong, Yong-Hoon;Shin, Seung-Pyo;Chung, Chae-Heon;Kim, Sang-Sub;Choe, Han-Cheol
    • Korean Journal of Metals and Materials
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    • v.50 no.5
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    • pp.395-400
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    • 2012
  • In this study, we have investigated the surface morphology of hydroxyapatite (HA) coated Ti alloy surface using pulsed laser plating. The HA (tooth ash) films were grown by pulsed KrF excimer laser, film surfaces were analyzed for topology, chemical composition, crystal structure and electrochemical behavior. The Ti-6Al-4V alloy showed ${\alpha}$ and ${\beta}$ phase, Cp-Ti showed ${\alpha}$ phase and the HA coated surface showed HA and Ti alloy peaks. The HA coating layer was formed with $1-2{\mu}m$ droplets and grain-like particles, particles which were smaller than the HA target particle, and the composition of the HA coatings were composed of Ca and P. From the electrochemical test, the pitting potential (1580 mV) of HA coated Ti-6Al-4V alloy was higher than those of Cp-Ti (1060 mV) and HA coated Cp-Ti (1350 mV). The HA coated samples showed a lower current density than non-HA coated samples, whereas, the polarization resistance of HA coated samples showed a high value compared to non-HA coated samples.

Analysis of RC beam with unbonded or exposed tensile steel reinforcements and defective stirrup anchorages for shear strength

  • Wang, Xiao-Hui;Liu, Xi-La
    • Computers and Concrete
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    • v.10 no.1
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    • pp.59-78
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    • 2012
  • Although the effect of corrosion of reinforcing bar on the shear behavior of the reinforced concrete (RC) beam had been simulated by tests of the beam with unbonded, half-exposed or whole-exposed tensile steel reinforcements as well as defective stirrup anchorages, theoretical methods to accurately predict remaining capacity of this kind of RC beams, especially shear capacity, are still lacking. Considering the possible position of the critical inclined crack, the actual pattern of strains in the concrete body within the partial length and the proposed compatibility condition of deformations of the RC beam, shear strength of the RC beam with unbonded or exposed tensile steel reinforcements and/or defective stirrup anchorages is predicted. Comparison between the model's predictions with the experimental results published in the literature shows the practicability of the proposed model. Influence of the length of unbonded or exposed tensile steel reinforcements and the percentage of stirrups lacked end anchorages on the shear strength of the RC beam is discussed. It is concluded that, the shear strength of the RC beam with unbonded or exposed tensile steel reinforcements and/or defective stirrup anchorages is greatly influenced by the length of unbonded or exposed tensile steel reinforcements and the percentage of stirrups lacked end anchorages, this influence can be adverse, insignificant or even favourable, dependent on the given parameters of the corresponding normal bonded RC beam.

Fabrication and Characterization of Ytterbium Silicates for Environmental Barrier Coating Applications (환경차폐코팅용 이터븀 실리케이트의 제조와 물성평가)

  • Choi, Jae-Hyeong;Kim, Seongwon
    • Journal of the Korean institute of surface engineering
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    • v.54 no.6
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    • pp.331-339
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    • 2021
  • Environmental barrier coatings(EBCs) are applied to the SiC/SiC ceramic matrix composites(CMCs) in order to protect CMCs from being corroded with water vapor by combustion gas in gas turbine engines. Ytterbium silicates, such as ytterbium monosilicate and ytterbium disilicate, are ones of the candidate materials for EBCs due to their excellent resistance to water vapor corrosion as well as thermal-expansion match with SiC. In this study, ytterbium silicates are fabricated with 2-step solid-state synthesis targeting ytterbium disilicate. After synthesizing ytterbium monosilicate, the mixtures of ytterbium monosilicate and SiO2 are heat-treated and densified by using pressureless sintering or hot pressing with a variety of heating conditions. The phase formation, thermal expansion, and oxidation behavior are examined with fabricated specimens. The final densified bodies are found to be composites between ytterbium monosilicate and ytterbium disilicate with different ratios, which results in 4.43 to 6.72×10-6/K range of coefficients of thermal expansion. The probability of these ytterbium silicates for EBC applications is also discussed.

Performance evaluation of in-service open web girder steel railway bridge through full scale experimental investigations

  • Sundaram, B. Arun;Kesavan, K.;Parivallal, S.
    • Structural Monitoring and Maintenance
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    • v.6 no.3
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    • pp.255-268
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    • 2019
  • Civil infrastructures, such as bridges and tunnels are most important assets and their failure during service will have significant economic and social impact in any country. Behavior of a bridge can be evaluated only through actual monitoring/measurements of bridge members under the loads of interest. Theoretical analysis alone is not a good predictor of the ability of a bridge. In some cases, theoretical analyses can give less effect than actual since theoretical analyses do not consider the actual condition of the bridge, support conditions, level of corrosion and damage in members and connections etc. Hence actual measurements of bridge response should be considered in making decisions on structural integrity, especially in cases of high value bridges (large spans and major crossings). This paper describes in detail the experimental investigations carried out on an open web type steel railway bridge. Strain gages and displacement transducers were installed at critical locations and responses were measured during passage of locomotives. Stresses were evaluated and extrapolated to maximum design loading. The responses measured from the bridge were within the permissible limits. The methodology adopted shall be used for assessing the structural integrity of the bridge for the design loads.

Bond strength prediction of spliced GFRP bars in concrete beams using soft computing methods

  • Shahri, Saeed Farahi;Mousavi, Seyed Roohollah
    • Computers and Concrete
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    • v.27 no.4
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    • pp.305-317
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    • 2021
  • The bond between the concrete and bar is a main factor affecting the performance of the reinforced concrete (RC) members, and since the steel corrosion reduces the bond strength, studying the bond behavior of concrete and GFRP bars is quite necessary. In this research, a database including 112 concrete beam test specimens reinforced with spliced GFRP bars in the splitting failure mode has been collected and used to estimate the concrete-GFRP bar bond strength. This paper aims to accurately estimate the bond strength of spliced GFRP bars in concrete beams by applying three soft computing models including multivariate adaptive regression spline (MARS), Kriging, and M5 model tree. Since the selection of regularization parameters greatly affects the fitting of MARS, Kriging, and M5 models, the regularization parameters have been so optimized as to maximize the training data convergence coefficient. Three hybrid model coupling soft computing methods and genetic algorithm is proposed to automatically perform the trial and error process for finding appropriate modeling regularization parameters. Results have shown that proposed models have significantly increased the prediction accuracy compared to previous models. The proposed MARS, Kriging, and M5 models have improved the convergence coefficient by about 65, 63 and 49%, respectively, compared to the best previous model.