• Journal of the Korean institute of surface engineering
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• v.51 no.2
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• pp.95-103
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• 2018

Recently, many types of constructional steels have been often exposed to under severe corrosive environments due to acid rain with increasing environmental contamination. In order to inhibit their corrosion in severe corrosive environments, a painting method has been widely applied to numerous constructional steels of land as well as marine. Therefore, development of paint having a good quality of corrosion resistance is considered to be very important. In this study, four types of anti-corrosive paints (AP: Phenol epoxy, AC: Ceramic epoxy, AT: Coal tar epoxy, AH: High solid epoxy) were coated to the specimens, and then, were immerged in various salt solutions (0.1, 0.3, 3, 6, 9 and 15% NaCl solutions) for 11 days. And, the corrosion resistance of these samples by effect of osmotic pressure with salt concentration was investigated with electrochemical methods such as measurement of corrosion potential, impedance and corrosion current density. The corrosion current densities of all samples (AC, AT and AH) submerged in 3% NaCl solution exhibited the smallest values compared to other salt solutions. However, in the case of lower values of salt solutions than 3% NaCl solution, the corrosion current density increased again because it makes easier for water, dissolved oxygen and chloride ion etc. to invade toward inner side of coating film due to increasing of the osmotic pressure than 3% NaCl solution, but in the case of higher values of salt solutions than 3% NaCl solution, the coating film is easily deteriorated due to high concentration of chloride ion rather than the osmotic pressure, which resulted in increasing the corrosion current density. In particular, the AC sample indicated the best corrosion resistance in 6% NaCl solution compared to other samples. Consequently, it is considered that the corrosion mechanism of the coated steel plate is completely different from bare steel plate, and the corrosion resistance of coating film by osmotic pressure and chloride ion depend on various types of epoxy of paint in NaCl solution.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.11a
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• pp.221-223
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• 2011

In this study, in order to comprehend performance of corrosion inhibitor, the experiment study was conducted about corrosion characteristic of 3 steps(0.0, norm 1/2, norm) compared to organic corrosion inhibitor standard use of liquid and molar 3 steps(0.0, 0.3, 0.6%) of Chloride by added amount of inorganic corrosion inhibitor by the corrosion inhibitor types about 2.4kg/㎥, 4.8kg/㎥ based on Chloride ion content 1.2kg/㎥ for service life prediction of concrete structure by using Poteniostat.

• Corrosion Science and Technology
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• v.12 no.3
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• pp.149-157
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• 2013

In corrosion-sensitive areas of exsisting unpainted weathering steel bridges with closed box girder structures. there are some serious local corrosion problems because of rain water or dew water which can not be solved by exsisting maintenance methods. These problems must be controled technically because of bad. influence on the safety of bridge. This study is the first stage of developing the economic corrosion control manual for these local corrosion problems. Through the injection of tar sealant into the crevice of mock-up equipment, it was prooved that the corrosive sealant can be useful to corrosion control at crevice of corrosion sensitive area.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.8
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• pp.1286-1290
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• 2004

This paper describes the anti-corrosion system on underwater structures of ships. Metals and alloys have several positions in the series such as immunity, corrosion and passivity. The iron potential has to change from the corrosion position to the anodic protection or cathodic protection for preventing corrosion by providing corrosion protection system such as ICCP(Impressed Current Cathodic Protection). The purpose of ICCP system is to eliminate the rusting or corrosion, which occurs on metal immersed in water. The system includes a power supply unit, which consists of a transformer, a converter. a controller, etc. This paper presents the protection performance of ICCP under dynamic condition such as velocity. The variation of potential and current density with time and environment factors are also described Finally, the experimental results will be explained and analysed.

• Journal of the Microelectronics and Packaging Society
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• v.23 no.4
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• pp.79-85
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• 2016

It is imperative to find environment-friendly coatings as an alternative to the currently used hexavalent chromate conversion coatings for the purpose of improving the anti-corrosion properties of aluminum alloys. Hence, in this study, the corrosion properties of a trivalent chromate conversion coating solution are analyzed and measured. Because of the presence of multiple components in trivalent chromate conversion coating solutions, it is difficult to control plating, attributed to their mutual organic relationship. It is of significance to determine the concentrations of the components present in these coatings; hence, qualitative and quantitative analysis is required. The coating solution contained not only an environment-friendly component chromium(III), but also zirconium, fluorine, sulfur, and potassium, in the coating film. These metals are confirmed to produce a film with improved corrosion resistance to form a thin layer. The excellent corrosion resistance for the trivalent chromate solution is attributed to various inorganic and organic additives.

• Advances in concrete construction
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• v.15 no.1
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• pp.41-46
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• 2023

Sport has no age limit and can be done anywhere and in any condition with minimal equipment. The existence of sports spaces in all parts of the world is considered a citizen's right. One of the activities carried out in this field is installing sports equipment and structures in parks and encouraging citizens to use this equipment for physical health with the least cost and facilities. Installing sports structures in open spaces such as parks is a practical step for developing citizens' sports. Although using devices in parks is acceptable, it is more critical to meet scientific and technical standards. The components of these structures must have high strength and endurance against changes in environmental conditions such as humidity, temperature difference, and corrosion. Among the various causes of material degradation, corrosion has always been one of several fundamental causes of metal equipment failure. Sports structures in open spaces are not safe from corrosion. Uniform corrosion is the most common type of corrosion. This corrosion usually occurs uniformly through a chemical or electrochemical reaction across the surface exposed to the corrosive environment. Rust and corrosion of outdoor sports structures are examples of this corrosion. For this reason, in this research, with the green synthesis of silica nanoparticles and its application in outdoor sports structures, the life span of these structures can be increased for the use of physical exercises as well as their quality.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.3
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• pp.203-207
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• 1998

After etching Al-Cu alloy films using $SiCl_4/Cl_2/He/CHF_3$ plasma, a corrosion phenomenon on the metal surface has been studied with XPS (X-ray photoelectron spectroscopy) and SEM (Scanning electron microscopy). In Al-Cu alloy system, the corrosion occurs rapidly on the etched surface by residual chlorine atoms. To prevent the corrosion, the $SF_6$ plasma treatment subsequent to the etch has been carried out. A passivation layer is formed by fluorine-related compounds on etched Al-Cu alloy surface after $SF_6$ treatment, and the layer suppresses effectively the corrosion on the surface as the RF power of $SF_6$ treatment increases. The corrosion could be suppressed successfully with $SF_6$ treatment in the RF power of 150watts.

• Corrosion Science and Technology
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• v.18 no.6
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• pp.258-266
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• 2019

The objective of this study was to evaluate corrosion resistance of additive manufactured 316L stainless steel and alloy 625 powders widely used in corrosion resistance alloys of marine industry in comparison with cast alloys. Directed Energy Deposition (DED) method was used in this work for sample production. DED parameter adjustment was also studied for optimum manufacturing and for minimizing the influence of defects on corrosion property. Additive manufactured alloys showed lower corrosion resistance in seawater compared to cast alloys. The reason for the degradation of anti-corrosion property was speculated to be due to loss of microstructural integrity intrinsic to the additive manufacturing process. Application of heat treatment with various conditions after DED was attempted. The effect of heat treatments was analyzed with a microstructure study. It was found that 316L and alloy 625 produced by the DED process could recover their expected corrosion resistance when heat treated at 1200 ℃.

• International Journal of Naval Architecture and Ocean Engineering
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• v.13 no.1
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• pp.707-717
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• 2021

To the date, shipbuilding companies have applied shop primer coating which protects the steel surface from global oxidization in environment. Proper shop primer requires either anti-corrosion ability during construction or anti-porosity ability during welding, and those properties contradict to each other. This report tried to derive an optimizing parameter on these conflicting properties to select a proper shop primer. First, sufficient amounts of the natural salt spray tests were carried out to achieve a series of data for the anti-corrosion ability. Second, lots of T-joint fillet welding test were performed to evaluate the trapped porosity formed in the weld pool. According to the experimental data, we could achieve either the rust-formation rate or the porosity-formation rate, then, each rate was generalized as formulae. Then, we tried to combine these conflicting properties to decide an optimum shop primer.

• Corrosion Science and Technology
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• v.3 no.6
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• pp.240-244
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• 2004

Recently a variety of electrochemical techniques have been used for the measurement of under-film corrosion of coated steel. Each method has its own characteristic and is suitable to determine some kinds of anti-corrosive mechanisms of coating film. We developed a new under-film corrosion tester (UFCT) which adoped current interrupter technique in principle. Electrochemical parameters can be measured by UFCT. It is possible for the novel under-film corrosion tester to evaluate under-film corrosion of steel covered with high electric resistance coating film which has no defect and is not easy to evaluate it by other methods. Finally some experimental results of protective coating performance obtained by UFCT were discussed.