• Corrosion Science and Technology
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• 제8권5호
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• pp.197-202
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• 2009

The high toxicity of wax, oil, varnish and volatile corrosion inhibitor(VCI) corrosion inhibitors lead to an increasing interest in using non-toxic alternatives such as anti-corrosive film. This study aims to investigate the possibility to use acryl based anti-corrosive film as a substitution of toxic corrosion inhibitors. Acryl emulsions were polymerized by several acryl monomers(acrylonitrile(AN), n-butyl acrylate(nBA), methylmethacrylate(MMA) and glycycyl methacrylate(GMA)), non-toxic corrosion inhibitor, crosslinking agents(diethylene glycol dimethacrylate(DEGDA)) and various additives in order to apply substrate of anti-corrosive film. Acryl emulsion for anti-corrosive film(AeACF) as a substrate of corrosion inhibitor film has excellent removal characteristic at above $25^{\circ}C$. The crosslinked by DEGDA in a range of above 4 wt% content anti-corrosive film can easily remove from the metal surface by using hands because it kept a balance of cohesion and adhesion strength. Anti - corrosive performance of AeACF is better than anti-corrosive oil by corrosion rate test, which was measured $54.3mg/dm^2$ day(MDD) and $142.9mg/dm^2$ day, respectively. Anti-corrosive film consisting of acryl monomers and inorganic anti-corrosive ingredients did not emit any toxic pollutants by gas chromatography. Thus it is estimated that acryl based anti-corrosion film can substitute toxic corrosion inhibitors.

• 한국산학기술학회논문지
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• 제13권2호
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• pp.784-789
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• 2012

본 논문에서는 방식 대상물 주변에 설치되어 있는 다수의 양극과 기준전극을 감시하고, 상황에 맞게 고정전위 및 분극 방법을 자동으로 적용할 수 있는 시스템을 개발하였다. 특히, 개발된 시스템은 방식 대상물의 전 부분이 균일하게 방식이 이루어지도록 자동 조정하는 기능을 가진 원격 전기방식 자동제어 장치, 부식전위를 검출하는 기능을 수행하는 부식감시 장치 그리고 이들 장치의 부식 및 방식 관련 데이터에 대해 실시간 감시 및 제어와 예측 기능을 수행하는 웹기반 운영프로그램으로 구성하였으며, 이 시스템을 이용하여 산화현상에 의한 부식을 방지함으로써 방식 대상물의 수명을 최대화할 수 있다.

• Journal of Advanced Marine Engineering and Technology
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• 제33권3호
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• pp.387-394
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• 2009

It has been observed that coated steel structures are rapidly deteriorated than designed lifetime due to acid rain caused by air pollution etc.. Therefore improvement of corrosion resistance of anti-corrosive paint is very important in terms of safety and economic point of view. In this study corrosion resistance for five kinds of anti-corrosive paints including acryl, fluorine and epoxy resin series were investigated with electrochemical methods such as corrosion potential, polarization curves, impedance and cyclic voltammogram measurements etc.. There were somewhat good relationships between values measured by electrochemical methods such as corrosion current density obtained by cathodic and anodic polarization curves, value of impedance estimated with AC impedance, and polarization resistance on the cyclic voltammogram, for example, corrosion current density was decreased with increasing of values of impedance and polarization resistance on the cyclic voltammogram. However their relationships between corrosion current density and corrosion potential were not well coincided each other. Consequently it is considered that although a corrosion potential of F101 of fuoric resin series shifted to negative direction than other anti-corrosive paints, its corrosion resistance, indicating on the cathodic and anodic polarization curves, AC impedance curves and cyclic voltammogram, was the most superior to other paints, whereas A100 containing arcylic resin showed a relatively poor corrosion resistance compared to other paints.

• Tribology and Lubricants
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• 제16권3호
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• pp.173-181
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• 2000

Friction, wear and corrosion characteristics of various MoS$_2$ bonded film lubricants were investigated to apply them to automotive wheel joints. MoS$_2$ bonded film lubricants were formulated by combinations of several additives and binders, and they were coated onto the pre-treated surfaces of specimens. Friction and wear characteristics were evaluated with Falex pin & vee-block test and LFW-1 block-on-ring test. For the corrosion resistant characteristics of the films, salt solution spray corrosion tests were performed. Results showed that MoS$_2$ bonded films containing both inorganic and organic corrosion-resistant additives yielded a synergy effect on anti-corrosion resistance. Also, binders having the better water-proof and thermal stability showed the lower friction and higher corrosion resistance.

• Corrosion Science and Technology
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• 제2권4호
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• pp.194-196
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• 2003

In this paper, a newest kind of anti-atmospheric corrosion method is introduced. This method does not adopt organic coating, plastic layer or metal plating, instead it adopts a kind of aqueous emulsion containing numerous tine solid compounds that are absorbed onto the component surface, which play the role of anti-electrochemical corrosion.

• Corrosion Science and Technology
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• 제10권1호
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• pp.24-29
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• 2011

The greatest purpose of chromate treatment is to improve anti-corrosion by stabilizing a metal surface. Because metal surface forms a compound by absorbing oxygen or water in the air by being generally unstable, it is necessary to improve anti-corrosion of the metal by forming the metal surface with a stable film. When considering the economical efficiency and requirements together because the film of the metal surface treated with chromate has good anti-corrosion and the stability also in the air by being compact and strong, Chromate treatment has been used most up to the electronics industry from the auto industry. However, these days, because hexavalent chromium is both a toxic agent to be able to cause cancers and deadly poisonous environmental pollutant, the strong legal controls on its use is being imposed all over the world. Because of this reason, a new anti-corrosion method is being required. Also, by users' various demands, the passivations that have recently been developed require various characteristics such as conductivity, chemical resistance, alkali cleaning resistance as well as anti-corrosion. We could confirm the results such as excellent anti-corrosion compared to chromate, conductivity, chemical resistance and detergent resistance as the result of analysis of various characteristics of the galvannealed sheet steels coated with Cr-Free solution developed in this research.

• 동력기계공학회지
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• 제17권4호
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• pp.79-85
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• 2013

This study aims at investigating the effect of a fusing treatments on anti-corrosion characteristics of Ni-based self-flux alloy coating. Ni-based coatings were fabricated by flame spray process on steel substrates, and fusing treatments were performed using a vacuum furnace at $800^{\circ}C$ $900^{\circ}C$, $1000^{\circ}C$ and $1100^{\circ}C$. After fusing treatments, corrosion tests were carried out using potentiostat/galvanostat at solution with pH 2 and pH 6. Corrosion potential(Ecorr) and corrosion current density(Icorr) could be analyzed from polarization curve. Fusing-treated coating at $1100^{\circ}C$ showed more favorable anti-corrosion characteristics than as-sprayed coating. Anticorrosive effect of fusing-treated coating at solution with pH 2 was relatively greater than at solution with pH 6. Fusing-treated coating at $1100^{\circ}C$ showed the most excellent anti-corrosion characteristics.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 봄 학술발표회 논문집
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• pp.261-264
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• 1997

Recently, large scale concrete structures exposed to severe environment are increasingly built in various locations. The corrosion may severely affect the durability and service life of such a concrete structure. It is therefore, necessary to develop a method to enhance the corrosion resistance of a concrete. And the purpose of this study is to evaluate the characteristics of anti-corrosion polymer cement coated rebar. The corrosion resistance of a concrete with anti-corrosion coating can be identified through accelerated corrosion test. And the bond strength test of a concrete using anti-corrosion coating was also carried out.

• Corrosion Science and Technology
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• 제15권6호
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• pp.290-296
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• 2016

This study was conducted in order to examine the effect of burn damage and the resultant anti-corrosion performance. The breakdown and defect of the paint film caused by burn damage are considered to affect not only the macroscopic appearance but also the adhesive force and the anti-corrosion performance of the paint film. The material of the paint film was epoxy paint that is used most widely for heavy-duty coating, and in order to induce burn damage, heat treatment with a torch was applied to the other side of the paint film. Surface and chemical structure changes according to aging were analyzed using FE-SEM and infrared absorption spectroscopy, and variation in the anti-corrosion performance was analyzed through the AC impedance test.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2016년도 추계 학술논문 발표대회
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• pp.134-135
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• 2016

To evaluate anti-corrosion performance of rebar in concrete according to the amount of chloride and inhibitor, electrochemical impedance spectroscopy(EIS) method was conducted in this study. For the anti-corrosion performance evaluation according to time, Impedance of rebar in concrete was measured before and after 5 cycle of corrosion acceleration. As a results, The impedance of rebar in concrete added chloride decreased than before corrosion acceleration. However impedance of other specimens was maintained or increased than before corrosion acceleration.