• Title/Summary/Keyword: Corrosion Properties

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Effect of Sn Addition on Corrosion Behavior of Mg-4%Zn Casting Alloy (Mg-4%Zn 주조 합금의 부식 거동에 미치는 Sn 첨가의 영향)

  • Han, Jin-Gu;Jun, Joong-Hwan
    • Journal of Korea Foundry Society
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    • v.37 no.3
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    • pp.63-70
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    • 2017
  • In the present study, effects of an addition of Sn on the microstructure and corrosion behavior were investigated in Mg-4%Zn-(0-3)%Sn casting alloys. With an increase in the Sn content, the ${\alpha}-(Mg)$ dendritic cell size was reduced, whereas the total amount of precipitates increased due to the formation of the $Mg_2Sn$ phase. It was found in immersion and electrochemical corrosion tests that the addition of Sn has a detrimental effect on the corrosion resistance of the Mg-4%Zn alloy. Microstructural examinations of the corrosion product and the corroded surface indicated that an accelerated micro-galvanic effect by the $Mg_2Sn-phase$ particles and a less protective corrosion product on the surface were responsible for the increased corrosion rate at a higher Sn content.

Chromate-free Hybrid Coating for Corrosion Protection of Electrogalvanized Steel Sheets

  • Jo, Du-Hwan;Kwon, Moonjae;Kim, Jong-Sang
    • Corrosion Science and Technology
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    • v.11 no.1
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    • pp.15-19
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    • 2012
  • Both electrogalvanized and hot-dip galvanized steel sheets have been finally produced via organic-inorganic surface coating process on the zinc surface to enhance corrosion resistance and afford additional functional properties. Recently, POSCO has been developed a variety of chromate-free coated steels that are widely used in household, construction and automotive applications. New organic-inorganic hybrid coating solutions as chromate alternatives are comprised of surface modified silicate with silane coupling agent and inorganic corrosion inhibitors as an aqueous formulation. In this paper we have prepared new type of hybrid coatings and evaluated quality performances such as corrosion resistance, spot weldability, thermal tolerance, and paint adhesion property etc. The electrogalvanized steels with these coating solutions exhibit good anti-corrosion property compared to those of chromate coated steels. Detailed components composition of coating solutions and experimental results suggest that strong binding between organic-inorganic hybrid coating layer and zinc surface plays a key role in the advanced quality performances.

Corrosion Resistance of SD460 Reinforcing Rod by Ceramic Coating (SD460 철근의 세라믹 코팅에 의한 내식성 향상연구)

  • Park, Ki Y.;Lee, Jong K.;Hong, Seok W.
    • Corrosion Science and Technology
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    • v.8 no.4
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    • pp.157-161
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    • 2009
  • The corrosion resistance of reinforcing bar was studied to endure the marine environment during shipment. The red rust on the surface did not damage the adherence in the concrete structures, especially in highly alkaline environment, but made the consumer doubt of the quality. The passivation process by alkalization of the quenching water in the tempcore process failed to endure the long shipping period. The ceramic coating by sol-gel process improved the corrosion resistance without damaging the mechanical properties and adherence between concrete and reinfiorcing bar. Optimal concentration of the coating solution and coating temperature were tested. No additional energy was necessary for the coating process by spraying during cooling process, resulting simplified process and low cost. Salt spray test, cyclic corrosion test and atmospheric test were employed to confirm the resistance. The corrosion rates were presented by rating number and polarization resistance. The coating layer was examined by FIB, XRD and SEM etc.

Improvement of the Corrosion Resistance of PVD Hard Coating/Substrate Systems - Recent Developments -

  • Jehn, Hermann A.;Kang, Sung-Goon
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.472-483
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    • 1999
  • Hard coatings playa continuously increasing role in the field of tribology as well as for decorative applications. In both areas they are often also exposed to corrosive media. While especially hard nitride coatings show a high corrosion resistance for themselves, hard $coating_strate systems may suffer from a severe corrosion attack due to the defects in the coating structure (pores, pinholes) resulting from the PVD-typical film morphology. While a huge number of investigations cover the tribological properties, only limited studies deal with the corrosion behavjour of coating substrate systems and attempts are made to improve their corrosion resistance. The present paper shortly describes the corrosion mechanisms and repots characteristic examples of the system behaviour. Special emphasis is laid on recent investigations to improve the corrosion resistance by alloying, interlayers or multilayered coating structures.es.

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Corrosion Characteristics of Aluminum Die Casting Alloys with Different Scrap Charge Rate (스크랩 장입 비율에 따른 다이캐스팅용 알루미늄 합금의 부식 특성)

  • Kim, Jun-Ho;Lee, Seung-Hyo
    • Journal of the Korean institute of surface engineering
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    • v.53 no.6
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    • pp.322-329
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    • 2020
  • The utilization of aluminum scrap is a subject of great importance in terms of reducing energy consumption and environmental protection. However, aluminum scrap contains impurities, which can degrade the properties of aluminum alloy, especially corrosion resistance. This study examines the effect of scrap charge rate of aluminum alloys about microstructures and corrosion characteristics. According to the metallographic examinations, Mg2Si tended to become coarser and its uniformity was decreased by increasing aluminum scrap charge rate. The immersion test exhibited corrosion progressed through the eutectic areas due to micro-galvanic interactions. Electrochemical measurements revealed that excess aluminum scrap could reduce the intergranular corrosion resistance of aluminum alloys. Results showed that the scrap charge rate is important factor in the design of corrosion resistance of aluminum die casting alloys.

Experimental Study of Bond Properties Using Coated Bars (도막재료에 따른 철근의 부착성능에 관한 실험적 고찰)

  • 김영진
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.211-216
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    • 2003
  • Coated bars are protecting reinforcing bars from corrosion and enhancing durabilities of reinforced concrete structures are tested to evaluate corrosion protection properties. Tests are performed based on the relevant standards of ACI and ASTM, such as chemical resistance, salt water spray, salt crack test and chloride permeability test with the main variable of the coating thickness. Three type materials are tested by Polyethylene, epoxy and bare bar. Test results show good chemical protection property and chloride permeability. Polyethylene coated bar is good coating material than any other materials.

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The integrity assessment of the pipeline (파이프라인의 건전성 평가)

  • 이억섭;황인현
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2000.06a
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    • pp.25-30
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    • 2000
  • The object of this work is to develop an assessment system for pipeline integrity The system consists of four module applications for internal algorithm; the effect of corrosion in pipeline, crack, stress corrosion crack (SCC) and fatigue modules. Presently, the module of the external corrosion has been developed and the internal algorithm for the effect of corrosion in pipeline and the database of the system are described in this paper, The database of the system is separated to mainly four parts; geometry of pipeline, material properties, boundary conditions and general Properties. Each components of the system are designed by user-friendly concept. This system may give a guideline for maintenance and modifications for the pipeline at the industrial sight. Furthermore, a procedure to evaluate an inspection interval is also provided.

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Effect of degree of corrosion on the mechanical properties of rebar (철근부식정도가 철근의 역학적 특성에 미치는 영향)

  • Cheong, Hai-Moon;Lee, Chan-Young;Ahn, Tas-Song;Tae, Sung-Ho;Lee, Han-Seung;Kang, In-Seok
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.257-260
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    • 2006
  • This paper reports results of a study conducted to assess the effect of degree of corrosion of reinforcing steel bar on their mechanical properties. Reinforcing steel bars, 13mm in diameter, that were corroded by electrically accelerated corrosion method in concrete specimens were removed and tested in tension. Results indicated that the level of reinforcement corrosion influenced yield point, the tensile strength and elongation of steel bars.

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Corrosion Properties of Zircaloy-4 Cladding Tube having a Laser Welding Part in Elevated Temperature (Zircaloy-4 핵연료봉 레이저 용접부의 고온부식 특성 연구)

  • Kim, D.G.;Park, J.S.;Kim, S.T.;Yang, M.S.;Lee, J.W.;Kim, S.S.;Jung, Y.H.
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.256-261
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    • 2001
  • Corrosion and tensile properties of zircaloy-4 cladding tube having a laser welding part in elevated temperature are studied to present the criterion of quality evaluation in nuclear reactor and to found the scientific basis of SCC, with laser welding method using by coupling up cladding tube to end cap. In the result of tensile test($400^{\circ}C$), the fracture is not happened in the welding part but base metal and the result of corrosion test($400^{\circ}C$ 1500psi steam), corrosion rate of the molten zone and PMZ is a little higher than the other zone.

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The Effect of MgO Clinker s Properties on Corrosion of MgO-C Brick (MgO-C벽돌에 있어서 MgO Clinker의 특성이 침식에 미치는 영향)

  • ;;;Akira Watanabe;Shigeyuki Takanaka
    • Journal of the Korean Ceramic Society
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    • v.25 no.6
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    • pp.593-600
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    • 1988
  • The properties of 10 kinds of MgO clinker were investigated to know the effect of MgO clinker's porperties on corrosion of MgO-C brick. For MgO clinker, chemical composition, porosity, density, periclase grain size, and microstructure were examined, while slag corrosion resistance was examined for MgO-C brick. In MgO clinker pore size and it's distribution, periclase grain size, impurities composition and the composition of grain boundaries are more important factors to determine corrosion degree of MgO-C brick than density, potosity and MgO purity.

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