• Title/Summary/Keyword: Corrosion Potential 부식전위

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The Effects of pH on the Corrosion Characteristics in Dissimilar Friction Welded Zone of IN713LC-SCM440 (IN713LC-SCM440 이종재 마찰용접부의 부식특성에 미치는 pH의 영향)

  • JO SANG-KEUN;KONG YU-SIK;KIM YOUNG-DAE
    • Journal of Ocean Engineering and Technology
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    • v.19 no.2 s.63
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    • pp.53-59
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    • 2005
  • The effect of pH on the corrosion characteristics in the dissimilar friction welded zone of IN713LC-SCM440 in the loaded torsional stress was studied. The corrosion experiment was performed for 120 hours on the specimens with five steps of pH. The surface corrosion pattern of the SCM440 area showed global corrosion and narrow pitting, which was caused by galvanic corrosion between friction welded IN713LC and SCM440, but corrosion did not proceeded from the IN713LC area. The average relative electrode potential gradually tends to decrease with the elapse of the immersion time in the acidity area. The average corrosion current also gradually tend to decrease The corrosion rate showed a larger value when the average relative electrode potential was higher and the average relative current was lower. The corrosion rate showed a larger value when the average relative electrode potential was higher in the acidity area, and it showed large when the average relative electrode potential was lower in the alkalinity area.

Effects of Torsional Stress on the Corrosion Characteristics in the Rotor Assembly of Marine Diesel Engine Supercharger (선박용 디젤엔진 과급기 로터 접합체의 부식특성에 미치는 비틀림응력의 영향)

  • Jo, S.K.;Kong, Y.S.;Kim, Y.D.
    • Journal of Power System Engineering
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    • v.9 no.1
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    • pp.50-56
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    • 2005
  • The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded torsional stress. The surface corrosion pattern of SCM440 area was showed global corrosion and narrow pitting, that was cause by galvanic corrosion between friction welded IN713LC and SCM440. But corrosion does not proceeded from IN713LC area. Initially, the average relative electrode potential and corrosion current were decreased suddenly, by and large, it was stabilized gradually tend to decreasing with the elapse of the immersion time. The corrosion rate was decreased by increasing the load stress, but 200 MPa specimen was showed most large value.

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The Effect of LiBr Concentration on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids ($LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 LiBr 농도의 영향)

  • Lim Uh Joh;Jeong Ki Cheol
    • Journal of the Korean Institute of Gas
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    • v.5 no.4 s.16
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    • pp.33-39
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    • 2001
  • This paper was studied on corrosion behavior of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the various concentration of lithium bromide solution, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze is carried out. And the corrosion behavior of materials forming absorption refrigeration systems is investigated. The main results are as following: 1) As concentration of lithium bromide solution increases, polarization resistance of materials of each kinds is low. And open circuit potential becomes less noble, the corrosion current density is high drained 2) Open circuit potential of SS 400 is less noble than that of Cu and Al-Ni bronze, corrosion current density of SS5 400 is high drained than that of Cu and Al-Ni bronze. 3) Anodic polarization of Cu and Al-Ni bronze in $62\%$ LiBr solution continues the active state. that of Cu and Al-Ni bronze in the natural sea water maintains the active state and the critical current for passivation appears.

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An Electrochemical Evaluation on the Crevice Corrosion of 430 Stainless Steel with Variation of Crevice Wide by Micro Capillary Tubing Method (Micro Capillary Tube 방법을 이용한 430 스테인레스강 틈의 폭변화에 따른 틈부식의 전기화학적 평가)

  • Na, Eun-Young
    • Journal of the Korean Electrochemical Society
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    • v.6 no.4
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    • pp.250-254
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    • 2003
  • In this study, the IR drop theory was adopted to explain the initiation of crevice corrosion in the framework of IR drop in crevice electrolyte. Furthermore, the electrochemical polarization was measured to study the mechanism of crevice corrosion for type STS430 stainless steel. lest method adopts under condition that the size of specimen is $10\times20\times5mm,\;in\;1N\;H_2SO_4+0.1N\;NaCl$ solution, and the artificial crevice gap sizes are three kinds, the Micro capillary tube size is inner diameter 0.04 mm, outer diameter 0.08 mm. Crevice corrosion is measured under the applied voltage of passivation potential -200mV/SCE, resulted from anodic potentio-dynamic polarization to the external surface along the crevice. The potential difference was measured by depth profile by Micro capillary tube which inserted in the crevice. The obtained results of this study showed that 1) As artificial crevice gap size became narrow, the current density was increased, whereas no crevice corrosion was found in the crevice gap size $3\times0.5\times16mm\;in\;1N\;H_2SO_4+0.1N\;NaCl\;solution\;at\;20^{\circ}C$ 2) potential of the crevice was about from -220 to -358mV which is lower than that of external surface potential of -200mV The results so far confirmes that the potential drop(so-called IR drop) in the crevice is one of the major mechanisms the process of crevice corrosion for 430 stainless steel.

Evaluation of Steel Corrosion of Slag Concrete by Half-cell Potential Method (반전지-전위 측정방법을 활용한 슬래그 콘크리트의 철근 부식 저항성능 평가)

  • Lee, Bo-Kyeong;Kim, Gyu-Yong;Kim, Rae-Hwan;Yoon, Min-Ho;Lee, Young-Wook;Choe, Gyeong-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.3-4
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    • 2014
  • There is high probability of steel corrosion on the reinforced concrete exposed to marine environment by penetration of chloride ion. When making concrete structure with slag as admixture in marine environment, salt damage can be prevented. Therefore, this paper presents experimental results of steel corrosion resistance of slag concrete considering marine environment through half-cell potential method which is one of the nondestructive test. As a result of half-cell potential experiment, it was assumed that every specimen exposed to marine environment was not corroded, and as a result of destroying specimens, it was confirmed that there was no corrosion in specimens.

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Effect of $H_O_2$ on the Corrosion Behavior of 304L Stainless Steel ($H_O_2$ 가 304L 스텐리스강의 부식거동에 미치는 영향)

  • Song, Taek-Ho;Kim, In-Sup;Park, Sung-Ki
    • Nuclear Engineering and Technology
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    • v.27 no.4
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    • pp.453-462
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    • 1995
  • In connection with the safe storage of high level nuclear waste, effect of $H_2O$$_2$ on the corrosion behavior of 304L stainless steel was examined. Open circuit potentials and polarization curves were measured with and without $H_2O$$_2$. The experimental results show that $H_2O$$_2$ increased corrosion potential and decreased pitting potential. The passive range, therefore, decreased as $H_2O$$_2$ concentration increased, indicating that pitting resistance was decreased by the existence of $H_2O$$_2$ in the electrolyte. These effect of $H_2O$$_2$ on corrosion of 304L stainless steel are considered to be similar to those of ${\gamma}$-irradiation. To compare the effects of $H_2O$$_2$ with those of $O_2$, cathodic and anodic polarization curves ore made in three types of electrolyte such as aerated, deaerated, and stirred electrolyte. The experimental results show that the effects of $H_2O$$_2$ on the corrosion behavior were tory similar to those of $O_2$ such as increase of corrosion potential, decrease of pitting resistance, and increase of repassivation potential. In acid and alkaline media, the corrosion potential shifts by $H_2O$$_2$ were restricted by the large current density of proton reduction and by the le Chatelier's principle respectively.y.

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The Effect of Shot Peening on Corrosive Behavior of SAE 5155 in $3.5\%$ NaCl Solution ($3.5\%$ NaCl수용액에서 SAE 5155의 부식거동에 미치는 쇼트피닝의 영향)

  • An Jae-Pil;Park Keyung-Dong
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.6
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    • pp.692-700
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    • 2005
  • In this study. investigated the effect of shot peening on the corrosion of SAE 5155 steel immersed in $3.5\%$ NaCl solution and corrosion characteristics by the heat treatment during shot peening process. The immersion test was Performed on the four kinds of specimens. Corrosion Potential, polarization curve, residual stress etc. were investigated from experimental results. From these test results, the effect of shot peening on the corrosion was evaluated The important results of the experimental study on the effects of shot peened SAE 5155 on the corrosion are as follows; Shot peened specimens show the low of corrosion current as compared with un peened specimens. In the case of corrosion potential, shot Peened specimen shows more negative Potential as compared with that of parent metal Surface of specimen, which is treated with shot peening Process. is Placed as more activated state against inner parent metal. Corrosion rate is shown that shot Peened specimens have less corrode than un peened specimens. But non heat treated shot peened specimens show the biggest weight loss owing to variable compressive residual stress layer by shot ball.

On Corrosion Behaviors in Welded Zone of API 5L-X65 Steel for Natural Gas Transmission (천연가스 수송용 API 5L-X65강 용접부의 부식거동에 관한 연구)

  • JO SANG-KEUN;SONG HAN-SEOP;KONG Yu-SIK;KIM YOUNG-DAI
    • Journal of Ocean Engineering and Technology
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    • v.18 no.5
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    • pp.50-56
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    • 2004
  • This study is on the constant-current stress corrosion test, related to the load stress, in both the welded and non-welded zones of high tensile strength steel that is used for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed general corrosion and narrow pitting, and the pitting was increased with load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel, used for natural gas transmission specimens, were decreased rapidly, and the average relative electrode potential was higher and the average relative current was lower in welded zone, compared to base metal. The average relative electrode potential was decreased with load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone, compared to base metal, and the corrosion rate was decreased by increasing the load stress.

Effect of Corrosion Characteristics in Relation to Loaded Stress in the Welded Zone of A5083-H116 Aluminum Alloy (A5083-H116 알루미늄 합금재 용접부의 부하응력에 따른 부식특성의 영향)

  • Jo, S.K.;Kong, Y.S.;Kim, Y.D.
    • Journal of Power System Engineering
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    • v.8 no.3
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    • pp.44-51
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    • 2004
  • Effect of corrosion characteristics in relation to loaded stress in the welded zone of A5083-H116 aluminum alloy, in the seawater was studied. The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded stress. The corrosion crack, corrosion rate, electrode potential, current, and corrosion pattern, etc. were examined for the specimens with the elapse of the immersion time. The main result derived from this study is the crack growth length is increased with the increasing loaded stress. The electrode potential and the corrosion current are decreased rapidly in the early stage of the corrosion, and then decreased gradually and stabilized eventually with the elapse of the immersion time. The test condition of the longer crack growth tends to show the higher corrosion rate. Corrosion pattern of the welded zone indicates that the depth and width of the pitting become increasing with the increasing loaded stress.

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