• 한국표면공학회지
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• 제42권1호
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• pp.41-46
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• 2009

The fit between dental implant fixture and zirconia abutment is affected by many variables during the fabrication process by CAD/CAM program and milling working. The purpose of this study was to evaluate the surface compatibility and electrochemical behaviors of zirconia abutment for prosthodontics. Zirconia abutments were prepared and fabricated using zirconia block and milling machine. For stabilization of zirconia abutments, sintering was carried out at $1500^{\circ}F$ for 7 hrs. The specimens were cut and polished for gap observation. The gap between dental implant fixture and zirconia abutment was observed using field-emission scanning electron microscopy (FE-SEM). The hardness and corrosion resistance of zirconia abutments were observed with vickers hardness tester and potentiostat. The gap between dental implant fixture and zirconia abutment was $5{\sim}12{\mu}m$ for small gap, and $40{\sim}60{\mu}m$ for large gap. The hardness of zirconia surface was 1275.5 Hv and showed micro-machined scratch on the surface. The corrosion potentials of zirconia abutment/fixture was .290 mV and metal abutment/fixture was .280 mV, whereas $|E_{pit}-E_{corr}|$ of zirconia abutment/fixture (172 mV) was higher than that of metal abutment/fixture (150 mV). The corrosion morphology of metal abutment/fixture showed the many pit on the surface in compared with zirconia abutment/fixture.

• 콘크리트학회지
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• 제5권3호
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• pp.107-115
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• 1993

최근 건설공사의 급증으로 인한 하천골재의 고갈로 콘크리트용 대체골재로서 해사\ulcorner선사 등이 대구되고 있다. 그러나 해사는 세척하지 않고 그대로 콘크리트에 사용할 경우 콘크리트중의 철근부식 촉진에 따른 콘크리트의 균열발생 등 조기 노후화현상으로 내구성에 많은 문제점을 내포하고 있고, 산사는 국내 연구실적이 전혀 없는 상태에서 지역적으로 무분별하게 사용되고 있어 이들에 관한 제반 공학적 특성 및 활영방안 연구가 시급한 실정이다. 따라서 본 연구는 산사\ulcorner해사를 사용한 콘크리트의 압축강도 특성 및 해사의 염분함량과 콘크리트의 물-시멘트비에 따른 철근부식량과의 관계를 구명하였다.

• Corrosion Science and Technology
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• 제5권6호
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• pp.218-221
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• 2006

Influence of microstructure on the corrosion property of Mg-Al-Zn alloy was investigated using potentiodynamic polarization experiments, galvanic coupling experiments, and scanning electron microscopy in sodium chloride solutions. Pitting was the most common form of attack in chloride solution, and filiform corrosion was also occurred in AZ91D-T4 alloy. On the contrary, filiform attack in the bulk matrix was predominant corrosion form in AZ91D-T6 alloy, and the number and size of pit were decreased than those of AZ91D-T4 alloy. Galvanic coupling effect between $Mg_{17}Al_{12}$ and matrix was existed, but the propagation of galvanic corrosion was localized only near the $Mg_{17}Al_{12}$ phase in AZ91D-6T alloy. The corrosion resistance of Mg-Al matrix increased with decreasing Al content in the matrix. And, it could be regarded that Al content in the matrix is decreased by precipitation of $Mg_{17}Al_{12}$ during the aging treatment and it decreases the anodic reaction rate of the matrix and galvanic effect in AZ91D-T6 alloy. It could be considered that the composition and microstructure of surface protective layer would be varied by precipitation of $Mg_{17}Al_{12}$ and subsequent decreasing of Al content in the matrix. And it would contribute the corrosion resistance of AZ91D-T6 aging alloy.

• 한국해양공학회지
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• 제9권2호
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• pp.141-148
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• 1995

Fatigue tests were carried out by a rotary bending testing machine of cantilever type. M.E.F.(ferrite encapsulated islands of martensite) materials were made by a series of heat treatment from a low carbon steel(SM 20 C). The fatigue tests were conducted at stress levels of 302 MPa and with frequencies of 25Hz, 2.5 Hz and 0.5 Hz in 3% NaCl solution. The fatigue strength increased with frequency got higher. The microcracks and corrosion pits were generated at the boundary between the matrix and the 2nd phase. The cracks generated by the corrosion pits were coalesced with the pits around the notch and became the initial crack. The $N_i/N_f$ ratio increased as the frequency and stress level decreased. The interference phenomenon increased with stress level and frequency gots higher. The crack propagation rate was delayed as the stress level lowers and the frequency gets higher, however, the range of the stress intensity factor depended only on a stress level.

• 대한조선학회논문집
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• 제43권4호
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• pp.467-475
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• 2006

Fatigue strength of hull structural steel plate, extracted from longitudinal bulkhead of a 17-year-old ore/oil carrier for renewal, was investigated in air and in artificial seawater condition. The surface of the plate was covered with corrosion pits and they proved to be crack initiation sites by fractography using SEM. From this research, it was found that the evaluation method for fatigue strength of virgin mild steel plates in air and in artificial seawater can also be applied to the evaluation of the fatigue strength of mild steel plates those were long-term exposed to a corrosive environment and their surfaces had been rusted intensively.

• Journal of Advanced Marine Engineering and Technology
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• 제38권8호
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• pp.968-973
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• 2014

Aluminum anode of marine growth prevention system for ship is installed in seachest or sea water strainer. The Al anode is connected to a control panel that feeds a current to the anode. The dissolved ions produced by the anode are transferred in sea water, spreads through the sea water pipe system and creates a protective film in the pipelines. Thereby, corrosion in pipeline system significantly is reduced. In application on condition as a steel ship, the big accident can be caused by the corrosion. Accordingly, in this research, we evaluated influence of applied current and flow velocity on electrochemical characteristics of Al anode for marine growth prevention system (MGPS). Based on the results of the erosion-cavitation experiments, cavitation rate increased greatly until 120 min. of the experimental time and decreased a little at the point of 180 min. where pit grew and merging occurred but showed a tendency of steadily increasing consumption rates. Based on the results of the Tafel analysis, compared to static states, corrosion current densities show a rapidly increasing tendency when flow occurred.

• 한국표면공학회지
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• 제41권4호
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• pp.163-168
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• 2008

The dental orthodontic bracket requires good mechanical properties, such as elastic strength and frictional resistance, combined with a high resistance to corrosion. The objective of this study was to investigate the effects of TiN and ZrN coating on corrosion resistance of orthodontic brackets using various electrochemical methods. Brackets manufactured by Ormco Co. were used, respectively, for experiment. Ion plating was carried out for coatings of bracket using Ti and Zr coating materials with nitrogen gas. Ion plated surface of each specimen was observed with field emission scanning electron microscopy(FE-SEM), energy dispersive Xray spectroscopy(EDS) and electrochemical tester. The corrosion potential of the TiN and ZrN coated bracket was comparatively high. The current density of TiN and ZrN coated bracket was smaller than that of non-coated bracket in 0.9% NaCl solution. Pit nucleated at angle of bracket slot.

• 한국표면공학회지
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• 제50권5호
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• pp.360-365
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• 2017

In this study, ion release and biocompatibility of sintered Ni-Cr-Ti alloy for dental prosthodontics have been researched by corrosion and cell culture test. The microstructures of the alloys were observed by optical microscope, and corrosion behavior was investigated using potentiostat (Model PARSTAT 2273, EG&G, USA). Cell culture was carried out using hGf cell in DMEM (Welgene Inc., South Korea) supplemented with 10% fetal bovine serum (FBS) (Welgene Inc., South Korea) and antibiotic antimycotic solution (Welgene Inc., South Korea). After corrosion and cell culture test, surface morphologies were observed by field-emission scanning electron microscopy. For wettability behaviors, contact angles were measured by wettability test. As the content of Ti increased, the number of pit decreased and the corrosion resistance was improved from anodic polarization test, also, polarization resistance of samples containing Ti remarkably improved as compared with the alloy not containing Ti. The sintered alloy showed a low contact angle due to the pores formed on the surface. The addition of Ti element showed that the cell survival rate was better than that of the control group.

• Corrosion Science and Technology
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• 제15권5호
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• pp.217-225
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• 2016

Linear polarization resistance (LPR) testing of soils has been used extensively by a number of water utilities across Australia for many years now to determine the condition of buried ferrous water mains. The LPR test itself is a relatively simple, inexpensive test that serves as a substitute for actual exhumation and physical inspection of buried water mains to determine corrosion losses. LPR testing results (and the corresponding pit depth estimates) in combination with proprietary pipe failure algorithms can provideauseful predictive tool in determiningthe current and future conditions of an asset. Anumber of LPR tests have been developed on soil by various researchers over the years1), but few have gained widespread commercial use, partly due to the difficulty in replicating the results. This author developed an electrochemical cell that was suitable for LPR soil testing and utilized this cell to test a series of soil samples obtained through an extensive program of field exhumations. The objective of this testing was to examine the relationship between short-term electrochemical testing and long-term in-situ corrosion of buried water mains, utilizing an LPR test that could be robustly replicated. Forty-one soil samples and related corrosion data were obtained from ad hoc condition assessments of buried water mains located throughout the Hunter region of New South Wales, Australia. Each sample was subjected to the electrochemical test developed by the author, and the resulting polarization data were compared with long-term pitting data obtained from each water main. The results of this testing program enabled the author to undertake a comprehensive review of the LPR technique as it is applied to soils and to examine whether correlations can be made between LPR testing results and long-term field corrosion.

• 전기화학회지
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• 제11권3호
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• pp.184-189
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• 2008

Inhibitive effects of chromate, phosphate, sulfate, and borate on chloride pitting corrosion of Al have been investigated using cyclic voltammetry. During the anodic oxide growth, the critical concentration of chloride for pit initiation decreased in the order: chromate > phosphate > sulfate > borate, and the maximum pitting current density increases in the reverse order: chromate < phosphate < sulfate < borate. The decreasing pitting current density was observed in the successive polarization cycles, which was attributed to the aging of Al oxides and field relaxation at oxide/solution interface.