• Title/Summary/Keyword: Corrosion Fatigue

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Surface Characteristics and Biocompatibility of MoS2-coated Dental Implant (MoS2 코팅된 치과용 임플란트의 표면특성과 생체적합성)

  • Min-Ki Kwon;Jun-Sik Lee;Mi Eun Kim;Han-Cheol Choe
    • Corrosion Science and Technology
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    • v.23 no.1
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    • pp.72-81
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    • 2024
  • The Ti-6Al-4V alloy is widely used as an implant material due to its higher fatigue strength and strengthto-weight ratio compared to pure titanium, excellent corrosion resistance, and bone-like properties that promote osseointegration. For rapid osseointegration, the adhesion between the titanium surface and cellular biomolecules is crucial because adhesion, morphology, function, and proliferation are influenced by surface characteristics. Polymeric peptides and similar coating technologies have limited effectiveness, prompting a demand for alternative materials. There is growing interest in 2D nanomaterials, such as MoS2, for good corrosion resistance and antibacterial, and bioactive properties. However, to coat MoS2 thin films onto titanium, typically a low-temperature hydrothermal synthesis method is required, resulting in the synthesis of films with a toxic 1T@2H crystalline structure. In this study, through high-temperature annealing, we transformed them into a non-toxic 2H structure. The implant coating technique proposed in this study has good corrosion resistance and biocompatibility, and antibacterial properties.

Characteristics of the Cyclic Hardening in Low Cycle Environmental Fatigue Test of CF8M Stainless Steel (CF8M 스테인리스 강 저주기 환경피로 실험의 주기적 변형률 경화 특성)

  • Jeong, Il-Seok;Ha, Gak-Hyun;Kim, Tae-Ryong;Jeon, Hyun-Ik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.2
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    • pp.177-185
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    • 2008
  • Low-cycle environmental fatigue tests of cast austenitic stainless steel CF8M at the condition of fatigue strain rate 0.04%/sec were conducted at the pressure and temperature, 15MPa, $315^{\circ}C$ of a operating pressurized water reactor (PWR). The used test rig was limited to install an extensometer at the gauge length of the cylindrical fatigue specimen inside a small autoclave. So the magnet type LVDT#s were used to measure the fatigue displacement at the specimen shoulders inside the high temperature and high pressure water autoclave. However, the displacement and strain measured at the specimen shoulders is different from the one at the gauge length for the geometry and the cyclic strain hardening effect. Displacement of the fatigue specimen gauge length calculated by FEM (finite element method) used to modify the measured displacement and fatigue life at the shoulders. A series of low cycle fatigue life tests in air and PWR conditions simulating the cyclic strain hardening effect verified that the FEM modified fatigue life was well agreed with the simulating test results. The process and method developed in this study for the environmental fatigue test inside the small sized autoclave would be so useful to produce reliable environmental fatigue curves of CF8M stainless steel in pressurized water reactors.

Effect of corrosion on the ultimate strength of double hull oil tankers - Part II: hull girders

  • Kim, Do Kyun;Park, Dae Kyeom;Park, Dong Hee;Kim, Han Byul;Kim, Bong Ju;Seo, Jung Kwan;Paik, Jeom Kee
    • Structural Engineering and Mechanics
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    • v.42 no.4
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    • pp.531-549
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    • 2012
  • Numerous oil tanker losses have been reported and one of the possible causes of such casualties is caused by the structural failure of aging ship hulls in rough weather. In aging ships, corrosion and fatigue cracks are the two most important factors affecting structural safety and integrity. This research is about effect on hull girder ultimate strength behavior of double hull oil tanker according to corrosion after Part I: stiffened panel. Based on corrosion data of Part I (time-dependent corrosion wastage model and CSR corrosion model), when progressing corrosion of fourtypes of double hull oil tankers (VLCC, Suezmax, Aframax, and Panamax), the ultimate strength behavior of hull girder is compared and analyzed. In case of the ultimate strength behavior of hull girder, when occurring corrosion, the result under vertical and horizontal bending moment is analyzed. The effect of time-dependent corrosion wastage on the ultimate hull girder strength as well as the area, section modulus, and moment of inertia are also studied. The result of this research will be useful data to evaluate ultimate hull girder strength of corroded double hull oil tanker.

An Effect of Steel Corrosion on Bond Stress-slip Relationship under Repeated Loading (반복하중하의 부착응력-슬립 관계에 미치는 철근 부식의 영향)

  • Kim, Chul-Min;Park, Jong-Bum;Chang, Sung-Pil;Kim, Jee-Sang
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.179-186
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    • 2010
  • The bond between steel and concrete in reinforced concrete members is essential to resist external load, but the bond mechanism in reinforced concrete beams deteriorated by steel corrosion has not been clearly known yet. Most existing researches have dealt with the bond behavior of corroded steel under monotonic loading, but scarce are researches dealing with bond behavior of corroded steel under repeated loading. This study includes the experimental investigation on the bond behavior with respect to the various degrees of steel corrosion under repeated loading. According to the test results, the bond strength of corroded steel under monotonic loading increases as the rate of steel corrosion increases unless the splitting crack occurs. The slip versus number of load cycles relation was found to be approximately linear in double logarithmic scale, not only in specimens without steel corrosion but also in specimens with steel corrosion. The test results also show that the steel corrosion does not negatively affect the bond strength of corroded steel after repeated loading unless the splitting crack occurs. But the fatigue life decreases sharply after splitting crack occurs. This research will be helpful for the realistic durability design and condition assessment of reinforced concrete structures.

Reserve capacity of fatigue damaged internally ring stiffened tubular joints

  • Thandavamoorthy, T.S.
    • Steel and Composite Structures
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    • v.4 no.2
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    • pp.149-167
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    • 2004
  • Offshore platforms have to serve in harsh environments and hence are likely to be damaged due to wave induced fatigue and environmental corrosion. Welded tubular joints in offshore platforms are most vulnerable to fatigue damage. Such damages endanger the integrity of the structure. Therefore it is all the more essential to assess the capacity of damaged structure from the point of view of its safety. Eight internally ring stiffened fatigue damaged tubular joints with nominal chord and brace diameter of 324 mm and 219 mm respectively and thickness 12 mm and 8 mm respectively were tested under axial brace compression loading to evaluate the reserve capacity of the joints. These joints had earlier been tested under fatigue loading under corrosive environments of synthetic sea water and hence they have been cracked. The extent of the damage varied from 35 to 50 per cent. One stiffened joint was also tested under axial brace tension loading. The residual strength of fatigue damaged stiffened joint tested under tension loading was observed to be less than one fourth of that tested under compression loading. It was observed in this experimental investigation that in the damaged condition, the joints possessed an in-built load-transfer mechanism. A bi-linear stress-strain model was developed in this investigation to predict the reserve capacity of the joint. This model considered the strain hardening effect. Close agreement was observed between the experimental and predicted results. The paper presents in detail the experimental investigation and the development of the analytical model to predict the reserve capacity of internally ring stiffened joints.

A Study on the Processing of Anti-Corrosive Composites for Propeller Shaft of the Ship and the Evaluation of Its Static and Fatigue Properties (선박용 프로펠러축 방식처리용 복합재료의 제조와 그 정적 및 피로특성 평가에 관한 연구)

  • 김윤해;왕지석;배창원
    • Journal of Ocean Engineering and Technology
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    • v.12 no.1
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    • pp.23-31
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    • 1998
  • Kind 1 propeller shaft in ships is the shaft which is provided with effective measures against corrosion by sea water, or the shaft which is made of approved corrosion resistance materials. The propeller shaft other than specified above is Kind 2. Thus, this study is mainly concerned with the resistance to fatigue damage in sea water against stress concentrations due to the notches. The results obtained can be summarized as follows; (1) The stress increases with curing time, however, when the curing time reaches at 96 hours the stress becomes a constant value. The elongation decreases with curing time, however, when the curing time reaches at 48 hours the elongation becomes a constant value. Thus, in case of FRP coating on propeller shaft, it is necessary to cure for 48 hours at least. (2) The relation of $\sigma$$_n$-K$_t$ is to be classified into two parts, which is a part where fracture nominal stress, $\sigma$$_n$, decreases with increasing $K_t$, and a part where $\sigma$$_n$ is nearly constant independent of $K_t$. (3) According to a linear notch mechanics, the measure of severity controlling the fracture in notched FRP body is the notch root radius, $\rho$. The notched static strength of an arbitrary specimen will be estimated from $\sigma$$_{max}$ -1/$\rho$ curve. (4) Through the observation of cross section after fatigue test, the part of interface was kept good condition irrespective of loading conditions.

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Fundamental Study on Cathodic Protection and Material Development as Erosion-Control Methods of Oceanic Centrifugal Pump(1) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구 1)

  • 이진열;임우조
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.2
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    • pp.56-66
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    • 1995
  • Recently, with theraped advancement in th oceanology such an ocean-going vessel and oceanic structures, there is a need to study the cavitation erosion-corrosion control of pump impeller, the partial element of ocean machinery, for more effective operation. Especially, the cathodic protection (impressed current method & Al-sacrificial anode method) was applied to sea water, and Cu-alloy material mixed Zn & Al was used as a control method of cavitation erosion-corrosion. In this study, used the piezoelectric vibrator with 20KHz, 24.mu.m to cavity generation apparatus, and investigated the weight loss, weight loss rate, electrode potential & current density etc. under this condition. According to test result, thos describes how to indentify an influence of the cathodic protection and Al & Zn addition in material development for the control of cavitation erosion-corrosion, and those will serve as fundamental data on the cavitation erosion-corrosion control of oceanic centrifugal pump.

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Fundamental Study on Cathodic Protection and Material Development as Erosion-Control Methods of Oceanic Centrifugal Pump(2) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구(2))

  • Lee, Jin Yeol;Im, U Jo;O, In Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.92-92
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    • 1996
  • Recently, with the rapid development in the oceanic systems such as the oceanic structures and vessel, there occurs much interest in the impingement erosion-corrosion. In this paper, Cu-metal was tested by using of erosion apparatus with water-jet type and was investigated under the behaviour of impingement erosion-corrosion according to various environmental conditions, and the properties of Cu-metal were evaluated through the measurement by weight loss, weight loss rate, protective efficiency. The results were compared with those obtained using Cu-metal applied to cathodic protection and Cu-alloys added to Zn or Al-metal. As a basis of those results, the best protective efficiencies could be taken as using cathodic protection method and Cu-alloy with Al & Zn material addings, and will be suggested as the fundamental data of the anti-impingement erosion-corrosion on Cu-metal of impeller material for oceanic centrifugal pump.

Fundamental Study on Cathodic Protection and Material Development as Erosion - Control Methods of Oceanic Centrifugal Pump(2) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구 (2))

  • 이진열;임우조;오인호
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.24-31
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    • 1996
  • Recently, with the rapid development in the oceanic systems such as the oceanic structures and vessel, there occurs much interest in the impingement erosion-corrosion. In this paper, Cu-metal was tested by using of erosion apparatus with water-jet type and was investigated under the behaviour of impingement erosion-corrosion according to various environmental conditions, and the properties of Cu-metal were evaluated through the measurement by weight loss, weight loss rate, protective efficiency. The results were compared with those obtained using Cu-metal applied to cathodic protection and Cu-alloys added to Zn or Al-metal. As a basis of those results, the best protective efficiencies could be taken as using cathodic protection method and Cu-alloy with Al & Zn material addings, and will be suggested as the fundamental data of the anti-impingement erosion-corrosion on Cu-metal of impeller material for oceanic centrifugal pump.

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Effects of ta-C Coatings on Surface Characteristics of Dental Ni-Ti Files (치과용 Ni-Ti파일의 표면특성에 미치는 ta-C코팅효과)

  • Sun-Kyun Park;Han-Cheol Choe
    • Corrosion Science and Technology
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    • v.22 no.5
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    • pp.368-376
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    • 2023
  • Dental Ni-Ti files must ensure stability and resistance to fatigue fracture. DLC and ta-C were coated to remove defects on the surface and ensure stability, and the surface characteristics were investigated. When coated with DLC, it was black, and in case of ta-C coating, it was blue-black. Scratches, which are defects caused by mechanical processing, were formed on the surface of the un-coated Ni-Ti file from the end of the file along the direction of processing, with the Pro-file appearing in the vertical direction and the K-file appearing in the file direction. Scratches were reduced on the coated surface, and the surface roughness was greatly reduced after coating compared to before coating. The un-coated Ni-Ti file had the lowest hardness, the DLC-coated file had the highest hardness, and ta-C showed relatively high hardness. The elastic modulus of the DLC coating film was high, and the ta-C elastic modulus was low. The adhesion of the DLC coating film tended to be higher than that of ta-C, and the wear loss amount of DLC coating of taC was lower. The corrosion potential of the ta-C coating increased significantly, and the corrosion current density decreased.