• 제목/요약/키워드: Corrosion Environment

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Prediction of Deterioration Process for Concrete Considering Combined Deterioration of Carbonation and Chlorides Ion (중성화와 염해를 고려한 콘크리트의 복합열화 예측)

  • Lee, Chang-Soo;Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.15 no.6
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    • pp.902-912
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    • 2003
  • The most common deteriorating processes of concrete structures are carbonation and chloride ion ingress. Many concrete structures have been suffered from chloride ions diffusion or carbonation induced reinforcement corrosion damage and many studies have been done on it. However, those studies were confined mostly to the single deterioration of carbonation or chloride attack only, although actual environment is rather of combined conditions. In case of many in-situ concrete structures, deterioration happened more for the case of combined attack than the single case of carbonation or chloride attack. In this paper, chloride profiles of carbonated concrete is predicted by considering two layer composite model, which is based on Fick's 2nd law. From the experimental result on combined deterioration of chloride and carbonation, it was examined that high chloride concentration was built up to 3∼5 mm over depth from carbonation depth. The analytical modeling of chloride diffusion was suggested to depict the relative influence of the carbonation depth. The diffusion coefficients of carbonation concrete and uncarbonated concrete with elapsed time were considered in this modeling.

Friction and Wear of Inconel 690 for Steam Generator Tube in Fretting (증기발생기 세관용 Inconel 690 의 프레팅 마찰 및 마멸특성)

  • Lee, Young-Ze;Lim, Min-Kyu;Oh, Se-Doo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.3
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    • pp.432-439
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    • 2003
  • Inconel 690 for nuclear steam generator tube has more Chromium than the conventionally used Inconel 600 in order to increase the corrosion resistance. To evaluate the tribological characteristics of Inconel 690 under fretting condition the fretting tests were carried out in air and elevated temperature water. Fretting tests of the cross-cylinder type were done under various vibrating amplitudes and applied normal loads in order to measure the friction forces and wear volumes. From the results of fretting wear tests. the wear of Inconel 690 can be predictable using the work rate model. The amounts of friction forces were proportional to relative movement between two fretting surfaces. The friction coefficients were decreased as increasing the normal loads and deceasing the vibrating amplitudes. Depending on fretting environment, distinctively different wear mechanisms and often drastically different wear rates can occur It was found that the fretting wearfactors in air and water at 2$0^{\circ}C$, 5$0^{\circ}C$, and 8$0^{\circ}C$ were 7.38 $\times$ $10^{-13}$$Pa^{-1}$, 2.12 $\times$$10^{-13}$$Pa^{-1}$, 3.34$\times$$10^{-13}$$Pa^{-1}$and 5.21$\times$$10^{-13}$$Pa^{-1}$, respectively flexibility to model response data with multiple local extreme. In this study, metamodeling techniques are adopted to carry out the shape optimization of a funnel of Cathode Ray Tube, which finds the shape minimizing the local maximum principal stress. Optimum designs using two metamodels are compared and proper metamodel is recommended based on this research.

Development of Thermoplastic Carbon Composite Bipolar Plates for High-temperature PEM Fuel Cells (고온 양성자 교환막 연료전지용 열가소성 탄소 복합재료 분리판 개발)

  • Lim, Jun Woo;Kim, Minkook;Lee, Dai Gil
    • Composites Research
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    • v.29 no.5
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    • pp.243-248
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    • 2016
  • Although thermoset carbon fiber composite bipolar plates not only have high mechanical properties but also high corrosion resistance in acid environment, high manufacturing cost and low bulk electrical conductivity are the biggest obstacle to overcome. In this research, thermoplastic polymer is employed for the matrix of carbon composite bipolar plate to increase both the manufacturing productivity and bulk electric conductivity of the bipolar plate. In order to increase the electrical conductivity and strength, plain type carbon fabric rather than chopped or unidirectional fibers is used. Also nano particles are embedded in the thermoplastic matrix to increase the bulk resistance of the bipolar plate. The area specific resistance and the mechanical strength of the developed bipolar plate are measured with respect to the environmental temperature and stack compaction pressure.

Structural health monitoring of a newly built high-piled wharf in a harbor with fiber Bragg grating sensor technology: design and deployment

  • Liu, Hong-biao;Zhang, Qiang;Zhang, Bao-hua
    • Smart Structures and Systems
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    • v.20 no.2
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    • pp.163-173
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    • 2017
  • Structural health monitoring (SHM) of civil infrastructure using fiber Bragg grating sensor networks (FBGSNs) has received significant public attention in recent years. However, there is currently little research on the health-monitoring technology of high-piled wharfs in coastal ports using the fiber Bragg grating (FBG) sensor technique. The benefits of FBG sensors are their small size, light weight, lack of conductivity, resistance corrosion, multiplexing ability and immunity to electromagnetic interference. Based on the properties of high-piled wharfs in coastal ports and servicing seawater environment and the benefits of FBG sensors, the SHM system for a high-piled wharf in the Tianjin Port of China is devised and deployed partly using the FBG sensor technique. In addition, the health-monitoring parameters are proposed. The system can monitor the structural mechanical properties and durability, which provides a state-of-the-art mean to monitor the health conditions of the wharf and display the monitored data with the BIM technique. In total, 289 FBG stain sensors, 87 FBG temperature sensors, 20 FBG obliquity sensors, 16 FBG pressure sensors, 8 FBG acceleration sensors and 4 anode ladders are installed in the components of the back platform and front platform. After the installation of some components in the wharf construction site, the good signal that each sensor measures demonstrates the suitability of the sensor setup methods, and it is proper for the full-scale, continuous, autonomous SHM deployment for the high-piled wharf in the costal port. The South 27# Wharf SHM system constitutes the largest deployment of FBG sensors for wharf structures in costal ports to date. This deployment demonstrates the strong potential of FBGSNs to monitor the health of large-scale coastal wharf structures. This study can provide a reference to the long-term health-monitoring system deployment for high-piled wharf structures in coastal ports.

Influence of porosity and cement grade on concrete mechanical properties

  • Huang, Jiandong;Alyousef, Rayed;Suhatril, Meldi;Baharom, Shahrizan;Alabduljabbar, Hisham;Alaskar, Abdulaziz;Assilzadeh, Hamid
    • Advances in concrete construction
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    • v.10 no.5
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    • pp.393-402
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    • 2020
  • The given research focuses on examining the effect of relatively humidity (RH) and curing temperature on the hydrates as well as the porosity of calcium sulfoaluminate (CSA) cement pastes. Numerous tests, which consist of mercury intrusion porosimetry (MIP), thermosgravi metric (TG) and X-ray diffraction (XRD) were conducted. Various characterization techniques which include, scanning electron microscopy, Fourier transform microscopy along with X-ray diffraction evaluations were conducted on the samples to examine phase formation and crystallinity, morphology and microstructure along with bond formations and functional groups, respectively. During long-term study, the performance of concrete which consisted of limestone and flash-calcined was close to those from standard Portland cement concrete. Traditional classifications and methods of corrosion were widely used for the assessment of steel in concrete which may get employed to concrete which contains LC3 to recalibrate the range of polarization resistance for passitivity condition. For example, there is up to 79.5% and 146% respective flexural and compressive strengths. Moreover, they developed more advance electrical and thermo-mechanical performance with a substantial reduction in absorption of water of close to 400%. These advantages allow this research crucial to evaluate how these methods can be applied. Additionally, the research evaluates developed and more advanced cement preservation and repair techniques. The conclusion suggests concerted efforts by various stakeholders such as policy makers to enable low-carbon rates.

Study on Plugging Criteria for Thru-wall Axial Crack in Roll Transition Zone of Steam Generator Tube (증기발생기 전열관 확관천이부위 축방향 관통균열의 관막음 기준에 관한 연구)

  • Park, Myeong-Gyu;Kim, Yeong-Jong;Jeon, Jang-Hwan;Kim, Jong-Min;Park, Jun-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.9
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    • pp.2894-2900
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    • 1996
  • The stream generator tubes represent an integral part of a major barrier against the fission product release to the environment. So, the rupture of these tubes could permit flow of reactor coolant into the secondary system and injure the safety of reactor coolant system. Therefore, if the crack was detected during In-Service Inspection of tubes the cracked tube should be evaluated by the pulgging criteria and plugged or not. In this study, the fracture mechanics evaluation is carried out on the thru-wall axial crack due to Primary Water Stress Corrosion Cracking in the roll transition aone of steam generator tube to help the assurence the integrity of tubes and estabilish the plugging criteria. Due to the Inconel which is used as tube material is more ductile than others, the plastic instability repture theory was used to calculate the critical and allowable crack length. Based on Leak Before Break concept the leak rate for the critical crack length and the allowable leak rate are compared and the safety of tubes was given.

A study on fatigue properties of GFRP in synthetic sea water (인공해수중 GFRP의 피로특성에 관한 연구)

  • 김연직;임재규
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.6
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    • pp.1351-1360
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    • 1993
  • The fatigue behavior of GFRP composites is affected by environmental parameters. Therefore, we have to study on effect of sea water on fatigue behavior of GFRP composites as to maintain the safety and confidence in design of ocean structure of GFRP. In this paper, we investigated the fatigue properties of chopped strand glass mat/polyester composite in synthetic sea water. (pH 8.2) In case of the glass fiber (CSM type) reinforced polyester composite materials, the fatigue crack in the both dry and wet specimens tested in air or synthetic sea water occurred at the initial of cycle. Thereafter, it was divided with two regions that one decreased with the crack extension and the other increased with the crack extension. The transition point occurred during the crack propagation shifted to high ${\Delta}K$ value as load increase but its point is not changed regardless of immersion or test environment under a constant load. The synthetic sea water degrades the bond strength between fiber and matrix, thereby the tendency of rapid deceleration and acceleration of the crack growth was appeared.

AN EVALUATION OF DYNAMIC FATIGUE CHARACTERISTICS OF DENTAL CERAMICS FOR ALL-CERAMIC CROWN (All-ceramic Crown 용 도재의 동적 피로특성 평가)

  • Yu, Hyoung-Woo;Bae, Tae-Sung;Song, Kwang-Yeob;Park, Charn-Woon
    • The Journal of Korean Academy of Prosthodontics
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    • v.35 no.4
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    • pp.781-792
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    • 1997
  • This study was peformed to evaluate the dynamic fatigue characteristics of the dental ceramics for all-ceramic crown. A feldspathic porcelain of VMK68. glass ceramic of IPS-Empress, and glass infiltrated alumina ceramic of In-Ceram were used. Disc specimens were prepared to the final dimensions of 12 mm in diameter and 1 mm in thickness. The biaxial flexure test was conducted using a ball-on-three-ball method. 240 specimens were tested in $37^{\circ}C$ water by testing 20 samples at each of four loading rates:0.05, 0.2, 1, and 5mm/min. 60 specimens were tested in a moisture-free environment by testing 20 samples at 5mm/min. The inert strength of VMK68 was 80.25MPa, and the fatigue parameters were n=29.1, ${\sigma}_{fo}=52.90MPa$. The inert strength of IPS-Empress was 104.76MPa, and the fatigue parameters were n=32.46, ${\sigma}_{fo}=67.52MPa$. The inert strength of In-Ceram was 429.33MPa, and the fatigue parameters were n=31.46, ${\sigma}_{fo}=258.36MPa$. 10-year failure stresses of VMK68, IPS-Empress, and In-Ceram were 20.3MPa, 24.8MPa, and 93.6MPa, respectively. Failure strength and fatigue life showed the highest value in In-Ceram, and then, IPS-Empress and VMK68.

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A study on press plasticity of A3003-O aluminum material (A3003-O 알루미늄 소재의 프레스 성형성에 대한 연구)

  • Kim, Hyeok-Jin;Han, Seong-Ryeol;Kim, Kyung-A
    • Design & Manufacturing
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    • v.13 no.4
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    • pp.23-27
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    • 2019
  • People's interest in the environmental problems of the Earth is growing as they come to the modern world, and research is being actively conducted on how to protect the environment. As a result, the automobile industry, one of the causes of environmental pollution, is also affected. Therefore, research is being conducted to improve the fuel economy and light weight of cars, development of pollution-free cars such as electric cars, and aluminium materials that are lighter than ordinary steel sheets and easier to recycle are gaining attention. In this experiment, the material was formed to form a form of aluminium and the material reduction rate of the side wall of the foam was tested according to the amount of side wall. The material used in the experiment was A3003-O, which is less plastic than normal steel plates, but has excellent corrosion resistance, plasticity and weldability compared to aluminium materials, but has poor tensile strength. For tensile testing, a certain array of Forming Shapes was molded and the height of the Forming was set to 5mm, and the height of the Forming was 4.7mm, indicating that the difference between the first 5mm Forming and the height was not large. In addition, the material reduction rate was tested by giving 15, 0, and -0.15 teas, respectively, and was found to be valuable as a product only for -0.15.

Safety Evaluation of Molten Steel Carrier by Using Instrument Indentation Technique (계장화압입시험법을 이용한 용강운반용 구조물의 안전성 평가)

  • Lee, Jeong-Ki;Kim, Yi-Gon;Yoo, Dae-Wha;Kim, Kwang-Ho;Lee, Kyeong-Ro;Kim, Chung-Youb
    • Journal of the Korean Society for Nondestructive Testing
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    • v.34 no.1
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    • pp.53-59
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    • 2014
  • Because a molten steel carrier is used in high-temperature and corrosive environments, erosion and corrosion decrease the thickness of the structure and expand the vent hole for emitting gas generated from refractory bricks. This increases the stress throughout the structure and introduces a significant stress concentration around the vent hole. In addition, the high-temperature environment degrades mechanical properties such as the yield and tensile strengths. These problems seriously affect the safety of the structure. In this study, the safety of a 10-year-old structure was evaluated by analyzing the stress distribution and measuring the mechanical properties of the structure. The mechanical properties were directly measured on the structure surface using the instrument indentation technique.