• 한국철도학회논문집
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• 제8권4호
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• pp.299-307
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• 2005

In general, structural integrity of rolling stock structures should last more than 25 years. During the lifetime corrosive degradation occurs. For structural design and diagnosis, quantitative relationship between corrosive degradation and variation of mechanical properties such as tensile strength and fatigue strength is needed. In this study, first of all we established the atmospheric corrosion test procedure. At regular intervals using specimens of SM490A and SS400 on the atmospheric corrosion test bed, we carried out tensile and fatigue tests. The fatigue strength decreases as the atmospheric corrosion period increases. In addition we studied the effect of post-weld heat treatment on the tensile and fatigue behaviour and performed electrochemical corrosion tests.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제3권3호
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• pp.159-167
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• 1999

This study performed experiments for measuring corrosion potential and current density variations in the polarzation curves of polyvinylchloride. The results were examined to identify particular influences affectingthe corrosion potential such as temperature, pH, enzyme, and salt. The lines representing active anodic dissolution were only slightly shifted in the potential direction by temperature, pH, enzyme and salt. The Tafel slope for the anodic dissolution was determined using the polarization effect with varying conditions. The slope of the polarization curves describing the active-to-passive transition region was noticeably shifted in the potential direction. In addition, using the variation in conditions, the best temperature and pH were determined for the corrosion rate, and resistance of corrosion. The second anodic current density peak and maximum passive current density were designated as degraded(IP/I0). The value of IP/I0 was used in measuring the extent of the degradation of the polyvinychloride. The potentiodynamic parameters of the corrosion were obtained using a Tafel plot.

• Corrosion Science and Technology
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• 제17권5호
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• pp.249-256
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• 2018

Metallic structures in the oil and gas production undergo severe degradation due to sweet and sour corrosion caused by the presence of $CO_2$ and $H_2S$ in the fluid environment. The corrosion behavior of 304 austenitic stainless was investigated in the presence of varying concentrations of $CO_2$ or $H_2S$ and $CO_2+H_2S$ to understand the effect of the parameters either individually or in combination. Potentiodynamic polarization study revealed that a small amount of $CO_2$ aided in the formation of calcareous deposit of protective layer on passive film of 304 steel, while increase in $CO_2$ concentration ruptured the layer resulting in sweet corrosion. The presence of $S^{2-}$ damaged the passive and protective layer of the steel and higher levels increased the degradation rate. Electrochemical impedance studies revealed lower polarization resistance and impedance at higher concentration of $CO_2$ or $H_2S$, supporting the outcomes of polarization study. XRD analysis revealed different types of iron carbides and iron sulphides corresponding to sweet and sour corrosion as the corrosion products, respectively. SEM analysis revealed the presence of uniform, localized and sulphide cracking in sour corrosion and general corrosion with protective carbide layer amid for sweet corrosion.

• 한국자기학회지
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• 제3권3호
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• pp.221-228
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• 1993

고밀도기록용 박막재료로서의 충족조건은 높은 보자력, 높은 포화자화, 생산성, 그리고 화학적 안정성으로써 수직자기기록매체 CoCrMo 자성박막을 RF 스퍼터링 방법으로 제조한 후, 부식 특성을 전기화학적 측정, acceleration corrosion test 및 부식후 박막의 표면분석을 통하여 조사 하였다. CoCrMo 박막의 부식특성은 스퍼터링 조건에 따라서 다르게 나타났으며, Mo의 함량이 증가 할수록 내식성은 향상되었다. 전기화학부식실험 결과 박막의 Mo 함량이 증가할수록 뚜렷한 활성- 불활성 전이를 나타내었으며 부동태전류밀도의 감소를 나타내었다. Accelerated corrosion test에 서 CoCrMo 박막의 부식은 전기화학반응에 의하여 일어났으며 Mo첨가에 따라 부식이 일어난 곳의 수는 감소하였다. AES분석결과 부식 장소에는 많은 양의 $Cl_{-}$ 이온이 존재하였고, Cr의 고갈이 부식의 원인이었다.

• Corrosion Science and Technology
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• 제3권5호
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• pp.194-197
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• 2004

The corrosion resistance of several kind of ME (Metal Evaporated) tape has been investigated both in mild sulfuric acid solution and NaCl solution by electrochemical impedance spectroscopy. It was found that the degradation of ME tapes was accelerated with increasing the concentration of sulfuric acid. There was no significant change in corrosion resistance when the concentration of NaCl was under 3.5 wt%. However, the impedance value decreased when the concentration of NaCl was up to 10 wt%. The degradation of backside of ME tapes was also investigated by AC impedance measurements. The results showed that the impedance behavior of backside plastic film changed with the concentration of sulfuric acid even at the beginning of immersion, implying the changing of the permeability for the backside of ME tapes. It was also found that the corrosion resistance of DVC (Digital Video Cassette) ME tape was better that that of Hi-8mm ME tapes in sulfuric acid solutions. Also, the backside of DVC ME tape showed better water resistance than that of Hi8 ME tapes.

• 한국구조물진단유지관리공학회 논문집
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• 제14권6호
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• pp.179-187
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• 2010

콘크리트 내부에 매설된 철근의 부식은 철근콘크리트구조물의 조기 성능저하와 붕괴의 주요원인이 되고 있다. 철근콘크리트 구조물에 발생하는 열화현상 중에서 철근부식에 의해 발생되는 염해는 그 피해가 다른 열화 현상보다 심하고 구조물의 보수 및 시공 측면에서도 막대한 경비가 요구되고 보수시기 또한 정하기 힘들다. 따라서 철근의 부식상태에 대한 조기발견은 관리자의 효율적인 보수 및 보강계획 수립을 위해 매우 중요하다. 한편 철근 부식을 평가하는 방법 중 비파괴측정이 많이 사용되고 있다. 특히 CM-II(corrosion meter) 측정기는 자연전위와 분극저항 및 콘크리트 비저항을 측정할 수 있어서 많이 사용되지만 몇 가지 단점을 가지고 있다. 이러한 단점을 극복하기 위해 매립형 미니센서가 개발되어져 왔다. 이 미니센서를 이용하여 철근 부식을 측정한 후 CM-II(corrosion meter)의 측정결과와 비교분석하여 개발된 미니센서의 타당성을 검증하였다.

• 대한기계학회논문집A
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• 제33권10호
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• pp.991-1004
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• 2009

Operating experience of the various components in the nuclear power plants has shown that a variety of degradation mechanisms can occur during operation. Therefore, the accurate lifetime evaluation and systematic management are very important for the safe as well as the economical operation of the nuclear power plants. In this paper, the characteristics of a total of 17 degradation mechanisms were reviewed and the plausible degradation mechanisms such as stress corrosion cracking, fatigue, irradiation embrittlement, and so on, were identified. Also, the lifetime evaluation technologies which have been developed for the application to the domestic nuclear power plants are described. In addition, a total of 48 aging management programs which have been established for the safe operation of the various components are explained.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(I)
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• pp.163-166
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• 2005

In this study, an unified algorithm for the degradation analysis which considers the cracks in concrete and steel corrosion is developed and implemented into finite element analysis program. Using the program, degradation analysis on reinforced concrete structures subjected to chloride attacks was carried out with time by considering the cracks and the steel corrosion and cracking due to expansion of corroded reinforcing bars. The analytical procedure proposal in this study can be used quantitative evaluation of degradation and service life prediction.

• Corrosion Science and Technology
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• 제3권3호
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• pp.87-97
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• 2004

This paper presents a new approach with meso scale structure models to express mechanical property, such as stress - strain relationships, of concrete. This approach is successful to represent both uniaxial tension and uniaxial compression stress - strain relationship, which is in macro scale. The meso scale approach is also applied to predict degraded mechanical properties of frost-damaged concrete. The degradation of mechanical properties with frost-damaged concrete was carefully observed. Strength and stiffness in both tension and compression decrease with freezing and thawing cycles (FTC), while stress-free crack opening in tension softening increases. First attempt shows that the numerical simulation can express the experimentally observed degradation by introducing changes in the meso scale structure in concrete, which are assumed based on observed damages in the concrete subjected to FTC. At the end applicability of the meso scale approach to prediction of the degradation by combined effects of salt attack and FTC is discussed. It is shown that clarification of effects of frost damage in concrete on corrosion progress and on crack development in the damaged cover concrete due to corrosion is one of the issues for which the meso scale approach is useful.

• 대한기계학회논문집A
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• 제20권4호
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• pp.1123-1132
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• 1996

It has been reported that high temperature structural components represent the phenomenon of material degradation according to a long term service under high temperature and pressure. Especially, fossile power plant components using the fossil fuel and heavy oil are affected by dewpoint corrosion of $H_2SO_4$produced during a combustion. Therefore, the service materials subjected to high temperature and pressure may occur the stress corrosion cracking. The object of this paper is to investigate SCC susceptibility according to the material degradation of the high temperature structural materials in dewpoint corrosive environment-$H_2SO_4$.The obtained results are summarized as follows : 1) In case of secondary superheater tube, the fractograph of dimple is observed at the concentration of $H_2SO_4$-5%. When the concentration of $H_2SO_4$ is above 10%, the fracture mode is shifted from a transgranular fracture to an quasi-intergranular fracture according to the increment of concentration. 2) In the relationship between [$\Delta$DBTT]$_sp$ and SCC susceptibility, it is confirmed that the greater material degradation degree is, the higher SCC susceptibility is. In addition, it can be known that SP test is useful test method to evaluate SCC susceptibility for high temperature structural components. 3) When [$\Delta$DBTT]$_sp$ is above 17$17^{\circ}C$ the SCC fracture behavior is definitely observed with SCC susceptibility of above 0.4.