• 제목/요약/키워드: Corrosion Degradation

검색결과 387건 처리시간 0.032초

무도장 내후성강의 장기 내식성 및 그 현장즉시측정법 (Long-term corrosion-resistance of an uncoated weathering steel and its on-line and in-situ measurements)

  • 박정렬;김규영
    • 한국강구조학회 논문집
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    • 제16권4호통권71호
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    • pp.415-423
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    • 2004
  • 옥외 강구조물의 중요 소재인 무도장 내후성강의 장기 내식성을 평가하기 위해 우선 9년 이상 산업대기와 전원대기에 폭로된 본 강판 및 비교재 일반강판 시편의 천향면에 대해 중성의 인공우수에 침적시켜 전기화학적 부식전위, 임피던스 및 동전위 양분극 곡선으로 측정 및 그 결과를 고찰하였다. 산업대기 및 전원대기에 천향면으로 폭로된 내후성강 표면에는 부동태적인 안정화 녹층이 발달하였으며, 산업대기 폭로 표면의 인공우수에서의 부식속도는 $3{{\mu}m}/y$로 측정되어 우수한 내후내식 녹층으로 덮혀 있었다. 지속적으로 인공우수에 침적시키면 모든 시편 녹층은 점진적으로 열화되어 모재 철분의 양극산화용해 율속의 부식으로 진전됨을 나타내었다. 내후성 합금성분은 이런 부식의 진전을 지연시키고 있었다. 장기 내식성을 잘 평가하기 위해서는 9년보다 훨씬 장기간 대기폭로된 강재표면과 해당 대기 응축수 모사 수용액을 이용한 전기화학적 측정이 필요하다. 특히 본 측정방법들은 강재 표면의 원하는 부위와 폭로시간대에 거의 비파괴적으로 부식상황과 녹층의 상태와 정량적인 부식속도를 직접 바로 측정할 수 있게 하므로 강재를 사용한 교량, 탑, 건축물 등의 강구조물의 표면에 전기화학적 cell을 구성하고 이동측정기를 사용하면 강구조물의 내후 내식성을 현장즉시 측정 및 평가를 효과적으로 가능하게 할 수 있다.

Affecting of Corrosion Potential and Current Density on Variation Polarization Curves with Polyvinylchloride (I)

  • Choi, Chil-Nam;Yang, Hyo-Kyung;Jung, Oh-Jin
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제2권2호
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    • pp.91-98
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    • 1998
  • In this study, we carried out the experiments for measuring the variations of corrosion potential and current density for polarization curves with polyvinylchloride. The results exhibited especially the influence affecting the corrosion potential and various conditions (temperature, day, pH, bacteria, and added salt). The second anodic current density peak and the minimum passive current density are designated $I_P/I_0,$ respectively. The value of $I_P/I_O$ is used as a measurement for the extent of degradation of the polyvinylchloride. The potentiodpnamics parameters of the corrosion were obtained using Tafel equation.

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환경열화에 의한 철도차량 구조용강의 부식 특성 (Corrosion Characterestic of Rolling Stock Structural Steel by Environmental Degradation)

  • 김용기;장세기;오창록;구병춘
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2004년도 추계학술대회 논문집
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    • pp.680-685
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    • 2004
  • The effects of acid rain and salt content on corrosion behavior were investigated with rolling stock structural steels be caused by environmental. Since these materials are exposed to the corrosive environments like polluted air, acid rain and sea water, it is important to investigate corrosion behaviour in various corrosive environments. The aqueous corrosion of the characteristic materials in aerated acid rain and neutral solution were studied by using immersion tests, electrochemical measurements and analytical techniques. In order to examine corrosion characteristic, structural steels were electrochemically evaluated with respect to the dissolved oxygen content, pH, chloride ion concentration.

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A Numerical Study on Flow-Accelerated Corrosion in Two Adjacent Elbows

  • Yun, Hun;Hwang, Kyeongmo;Moon, Seung-Jae
    • Corrosion Science and Technology
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    • 제15권1호
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    • pp.6-12
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    • 2016
  • Flow-Accelerated Corrosion (FAC) is a well-known degradation mechanism that attacks the secondary piping in nuclear power plants. Since the Surry Unit 2 event in 1986, most nuclear power plants have implemented management programs to deal with damages in carbon and low-alloy steel piping. Despite the utmost efforts, damage induced by FAC still occurs in power plants around the world. In order to predict FAC wear, some computer programs were developed such as CHECWORKS, CICERO, and COMSY. Various data need to be input to these programs; the chemical composition of secondary piping, flow operating conditions and piping geometries. CHECWORKS, developed by the Electric Power Research Institute (EPRI), uses a geometry code to calculate geometry effects. Such a relatively simple geometry code is limited in acquiring the accuracy of FAC prediction. Recently, EPRI revisited the geometry code with the intention of updating it. In this study, numerical simulations were performed for two adjacent $90^{\circ}$ elbows and the results were analysed in terms of the proximity effect between the two adjacent elbows.

Risk-based optimum repair planning of corroded reinforced concrete structures

  • Nepal, Jaya;Chen, Hua-Peng
    • Structural Monitoring and Maintenance
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    • 제2권2호
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    • pp.133-143
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    • 2015
  • Civil engineering infrastructure is aging and requires cost-effective maintenance strategies to enable infrastructure systems operate reliably and sustainably. This paper presents an approach for determining risk-cost balanced repair strategy of corrosion damaged reinforced concrete structures with consideration of uncertainty in structural resistance deterioration. On the basis of analytical models of cover concrete cracking evolution and bond strength degradation due to reinforcement corrosion, the effect of reinforcement corrosion on residual load carrying capacity of corroded reinforced concrete structures is investigated. A stochastic deterioration model based on gamma process is adopted to evaluate the probability of failure of structural bearing capacity over the lifetime. Optimal repair planning and maintenance strategies during the service life are determined by balancing the cost for maintenance and the risk of structural failure. The method proposed in this study is then demonstrated by numerical investigations for a concrete structure subjected to reinforcement corrosion. The obtained results show that the proposed method can provide a risk cost optimised repair schedule during the service life of corroded concrete structures.

환경열화에 의한 가선재의 피로거동 (Fatigue Behavior of Catenary Wires by Environments Degradation)

  • 김용기;장세기
    • 한국철도학회논문집
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    • 제7권1호
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    • pp.14-19
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    • 2004
  • The effect of surface damage on fatigue properties of catenary wires were investigated to estimate their service lift. As surface defects of the wires caused by surface corrosion increase, surface roughness gets worse, and as roughness increases, it is easy for moisture coming from rain and dew to be condensed around uneven parts of the surface. The condensed moisture causes a locally severe corrosion which leads to damage of the wires. Corrosion of catenaty wires can make their actual lifetime shorter than that originally designed. The amount of decrease was more prominent as environmental conditions became more corrosive. They are also vibrated with some amplitude everytime pantographs touch contact line. The frequent cyclic load on the wire may result in a fatigue fracture. Surface damage by corrosion can make formation of crack initiation at fatigue. In the present study, the fatigue life of the used wire was measured 35 to 50% compared with that of new one in average.

Evaluation of Bond Properties of Reinforced Concrete with Corroded Reinforcement by Uniaxial Tension Testing

  • Kim, Hyung-Rae;Choi, Won-Chang;Yoon, Sang-Chun;Noguchi, Takafumi
    • International Journal of Concrete Structures and Materials
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    • 제10권sup3호
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    • pp.43-52
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    • 2016
  • The degradation of the load-bearing capacity of reinforced concrete beams due to corrosion has a profoundly negative impact on the structural safety and integrity of a structure. The literature is limited with regard to models of bond characteristics that relate to the reinforcement corrosion percentage. In this study, uniaxial tensile tests were conducted on specimens with irregular corrosion of their reinforced concrete. The development of cracks in the corroded area was found to be dependent on the level of corrosion, and transverse cracks developed due to tensile loading. Based on this crack development, the average stress versus deformation in the rebar and concrete could be determined experimentally and numerically. The results, determined via finite element analysis, were calibrated using the experimental results. In addition, bond elements for reinforced concrete with corrosion are proposed in this paper along with a relationship between the shear stiffness and corrosion level of rebar.

부식속도에 대한 참조 표준 작성을 위한 수환경에 따른 각종 금속의 부식특성 평가 - I. 안동지역 (Evaluation of Corrosion Properties of Several Metals in Waters for Reference Standard on Corrosion Rate - I. Andong Area)

  • 심규태;권용혁;김영식
    • Corrosion Science and Technology
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    • 제8권6호
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    • pp.238-242
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    • 2009
  • Corrosion of metallic materials occurs by the reaction with corrosive environment. In general, corrosive environments are classified as atmospheric, marine, soil etc. and regardless of any corrosive environments, reduction of thickness and cracking and degradation are induced by corrosion. Among several corrosive environments, knowing the atmospheric corrosiveness of a region, city, or country is considered of ultimate importance for major industrialists and investors who require knowledge of the corrosive impact of the atmosphere on everyday materials such as carbon steel, weathering steel, zinc, copper, and aluminium. This is why the atmospheric corrosiveness map is needed. This paper dealt with corrosion properties between several waters in the region and carbon steel, weathering steel, galvanized steel, pure copper, and pure aluminium at the representative rural area of Korea - Andong.

304L 스테인리스강의 열처리에 따른 입계부식민감도 연구 (Sensitivity to Intergranular Corrosion According to Heat Treatment of 304L Stainless Steel)

  • 장형민;김동진;김홍표
    • Corrosion Science and Technology
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    • 제19권1호
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    • pp.37-42
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    • 2020
  • Even though 304 low-carbon (304L) stainless steel was developed to enhance the resistance to intergranular corrosion and stress corrosion cracking, it is occasionally subject to degradation in harsh environments. The degree of sensitization (DOS) of 304L stainless steel was studied as a function of sensitization using a double-loop electrochemical potentiokinetic reactivation (DL-EPR) method. Sensitizing heat treatment was performed in an Ar atmosphere at 500℃, 600℃, and 700℃, with heat treatment times varying from 0 to 96 h. DOS was measured by the ratio of the peak current density value of the forward scan to that of the reverse scan. After the EPR experiment, the specimen surface was observed by scanning electron microscopy and energy dispersive spectroscopy. The DOS of the specimens heat-treated at 600℃ increased with heat treatment times up to 48 h and then decreased due to a self healing effect. The DOS was higher in specimens heat-treated at 600℃ than those at 500℃ or 700℃. Corrosion of the sensitized specimens occurred mainly at the δ-γ phase boundary. The corrosion morphology at the δ-γ phase boundary changed with sensitizing heat-treatment conditions due to differences in chromium activity in γ austenite and δ ferrite.

Improving the concrete quality and controlling corrosion of rebar embedded in concrete via the synthesis of titanium oxide and silica nanoparticles

  • Jundong Wu;Yan Cui
    • Advances in concrete construction
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    • 제15권1호
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    • pp.1-10
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    • 2023
  • Concrete is one of the most widely used structure materials. Concrete is like the motor of the construction industry. The remarkable feature of this Concrete is its cheapness and low energy consumption. Concrete alone does not show resistance against any force but only against compressive forces. Therefore, steel rebar product is used as a reinforcement and increase the strength of Concrete. It can be done by putting rebar in Concrete in different ways. Rebar rusting is one of the crucial symptoms that cause swift destruction in reinforced structures-factors such as moisture in concrete increase the steel corrosion rate. In most cases, it is difficult to compensate for the damage caused by the corrosion of base metals, so preventing corrosion will be much more cost-effective. Coatings made with nanotechnology can protect Concrete against external degradation factors to prevent water and humidity from penetrating the Concrete and prevent rusting and corrosion of the rebar inside. It prevents water penetration and contamination into the Concrete and increases the Concrete's quality and structural efficiency. In this research, silica and titanium dioxide nanoparticle coatings have been used due to their suitable electrical and thermal properties, resistance to oxidation, corrosion, and wear to prevent the corrosion of rebars in Concrete. The results of this method show that these nanoparticles significantly improve the corrosion resistance of rebars.