• Corrosion Science and Technology
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• 제22권2호
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• pp.123-130
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• 2023

This study aimed to evaluate corrosion resistance of steel coated with GI and Zn-Al-Mg alloy using cyclic corrosion test (CCT) with electrochemical polarization and impedance measurements. Results showed that the Zn-Al-Mg alloy coated steel had a much higher corrosion rate than GI coated steel in early stages of corrosion. With prolonged immersion, however, the corrosion rate of the Zn-Al-Mg alloy coated steel greatly decreased, mainly owing to a significant decrease in the cathodic reduction reaction and an increase in polarization resistance at the surface. This was closely associated with the formation of protective corrosion products including Zn₅(OH)₈Cl₂·H₂O and Zn₆Al₂(OH)₁₆CO₃. Moreover, when the steel substrate was locally exposed due to mechanical damage, the kinetics of anodic dissolution from the coating layer and the formation of protective corrosion products on the surface of the Zn-Al-Mg alloy coated steel became much faster compared to the case of GI coated steel. This could provide a longer-lasting corrosion inhibition function for Zn-Al-Mg alloy coated steel used in plant farms.

• Steel and Composite Structures
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• 제37권3호
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• pp.353-369
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• 2020

Eight cold-formed thin-walled steel beams were performed to investigate the effect of corrosion damage on the flexural behavior of steel beams. The relationships between failure modes or load-displacement curves and corrosion degree of steel beams were investigated. A series of parametric analysis with more than forty finite element models were also performed with different corrosion degrees, types and locations. The results showed that the reduction of cross-section thickness as well as corrosion pits on the surface would lead to a decline in the stiffness and flexural capacity of steel beams, and gradually intensified with the corrosion degree. The yield load, ultimate load and critical buckling load of the corroded specimen IV-B46-4 decreased by 22.2%, 26% and 45%, respectively. The failure modes of steel beams changed from strength failure to stability failure or brittle fracture with the corrosion degree increasing. In addition, thickness damage and corrosion pits at different locations caused the degradation of flexural capacity, the worst of which was the thickness damage of compression zone. Finally, the method for calculating flexural capacity of corroded cold-formed thin-walled steel beams was also proposed based on experimental investigation and numerical analysis results.

• Tribology and Lubricants
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• 제30권6호
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• pp.356-363
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• 2014

Marine diesel engines operate in environments in which damage easily occurs from corrosion. Recently, damage to cylinder liners has increased from corrosion wear caused by increased engine power. This damage can cause serious problems in the economy. Thus, many researchers have treated and studied damaged cylinder liners. However, a method is necessary for real-time monitoring of damage to cylinder liners during operation of the engine, before serious damage can occur. This study carries out reciprocating friction and wear tests on a cast iron specimen under various corrosion atmospheres and verifies the variations of friction coefficient and friction surface. Additionally, the friction coefficient and friction status are predicted by using a neural network that learns the vibration and frequency spectrum data from an acceleration sensor. According to our conclusions, amplitude is distributed highly at high frequencies, and values of standard deviation and kurtosis are high when damage to the friction surface is serious. The accuracy rate of the friction coefficient predicted by the neural network is over 80% of the real measured value without NaCl, and application of the neural network is very effective for diagnosing the friction condition and damage to the cylinder liner.

• Corrosion Science and Technology
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• 제10권6호
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• pp.218-224
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• 2011

The fresh water and sea water in present ships is used as cooling water for marine engine. Therefore, corrosion damage in seawater system is frequently occurred. In particular, in the impeller of pump, the performance and material span due to the corrosion and cavitation erosion has adverse effects. Most of the pump impellers in vessels are used Cu-Al alloy. Cu-Al alloy which having the excellent mechanical properties and corrosion resistance is widely used in marine environments. However, despite the excellent characteristics, the periodic replacement parts due to the cavitation damage in seawater is vulnerable to economic viewpoint. In this study, Cu-Al alloy used with impeller for centrifugal pump were conducted various experiments to evaluate its characteristics in seawater and fresh water solutions. As an electrochemical result, the dynamic conditions that exposed to the cavitation environment presented high corrosion current density with collapse of the cavity compared with the static conditions. Cavitation test results, the weightloss and weightloss rate in fresh water are observed more than those of seawater.

• 비파괴검사학회지
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• 제33권5호
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• pp.409-414
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• 2013

음향방출법을 이용하여 304 스테인레스 강의 부식 손상 과정을 평가하였다. 스테인레스 강의 가속부식시험을 수행하면서 음향방출신호를 수집할 수 있는 측정 시스템을 구성하였다. 양극분극시험에서 공식부식(pitting corrosion)이 발생하는 시점 이후부터 음향방출(AE)신호가 검출되기 시작함을 확인하였다. 부식 실험 후 시편 표면을 광학현미경으로 관찰하여 다수의 공식부식이 발생하였음을 검증하였다. 부식 시간의 증가에 따른 AE 누적카운트 증가율과 AE 신호 진폭의 변화는 3단계로 구분되는 특징을 보였다. 이러한 AE 신호 발생 특징을 스테인레스 강의 부식 발생 과정의 단계별 변화와 관련하여 고찰하였다. AE 신호를 이용하여 금속 소재의 부식 손상 정도 및 부식 과정의 평가 가능성을 제시하였다.

• Corrosion Science and Technology
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• 제4권5호
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• pp.178-190
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• 2005

In order to develop a new corrosion sensor for detecting and monitoring the external and internal corrosion damage of buried pipeline, the electrochemical property of sensors and the correlation of its output to corrosion rate of steel pipe, were evaluated by electrochemical methods in two soils of varying resistivity (5,000 ohm-cm, 10,000 ohm-cm) and synthetic tap water environments. In this paper, two types of galvanic probes were manufactured: copper-pipeline steel (Cu-CS) and stainless steel-pipeline steel (SS-CS). The corrosion behavior in synthetic groundwater and synthetic tap water for the different electrodes was investigated by potentiodynamic test. The comparison of the sensor output and corrosion rates revealed that a linear relationship was found between the probe current and the corrosion rates. In the soil resistivity of $5,000{\Omega}-cm$ and tap water environments, only the Cu-CS probe had a good linear quantitative relationship between the sensor output current and the corrosion rate of pipeline steel. In the case of $10,000{\Omega}-cm$, although the SS-CS probe showed a better linear correlation than that of Cu-CS probe, the Cu-CS probe is more suitable than SS-CS probe due to the high current output.

• Computers and Concrete
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• 제15권3호
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• pp.411-436
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• 2015

In this work, a comprehensive approach to model the structural behaviour of Reinforced Concrete (RC) beams subjected to reinforcement corrosion is proposed. The coupled environmental - mechanical damage model developed by some of the authors is enhanced for considering the main effects of corrosion on concrete, on composite interaction between reinforcement bars and concrete and on steel reinforcement. This approach is adopted for reproducing a set of experimental tests on RC beams with different corrosion degrees. After the simulation of the sound beams, the main parameters involved in the relationships characterizing the effects of corrosion are calibrated and tested, referring to one degraded beam. Then, in order to validate the proposed approach and to assess its ability to predict the structural response of deteriorated elements, several corroded beams are analyzed. The numerical results show a good agreement with the experimental ones: in particular, the proposed model properly predicts the structural response in terms of both failure mode and load-deflection curves, with increasing corrosion level.

• 비파괴검사학회지
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• 제23권4호
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• pp.364-371
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• 2003

In this paper, a review of the current status, on the use of long range cylindrically guided wave modes, and their interaction with cracks and corrosion damage in pipe-like structures will be discussed. Applications of cylindrically guided ultrasonic wave modes have been developed for inspection of corrosion damage in pipelines at chemical plants, flow-accelerated corrosion damage (wall thinning) in feedwater piping, and circumferential stress corrosion cracks in PWR steam generator tubes. It has been demonstrated that this inspection technique can be employed on a variety of piping geometries (diameters from 1 in. to 3 ft, and wall thickness from 0.1 to 6 in.) and a propagation distance of 100 meters or more is sometimes feasible. This technique can also be used in the inspection of inaccessible or buried regions of pipes and tubes.

• 해양환경안전학회지
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• 제27권1호
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• pp.187-192
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• 2021

본 연구는 절탄기 튜브의 저온부식 손상을 방지하기 위해 Inconel 625 용사재료를 활용하여 아크 열용사 코팅기술 적용 후 실링처리를 실시하였다. 용사코팅(TSC) 층의 내식성 분석을 위해 0.5 wt% 황산 수용액에서 다양한 전기화학적 실험을 진행하였다. 양극분극 실험 후에는 주사전자현미경과 EDS 성분분석을 통해 부식 손상 정도를 파악하였다. 자연전위 계측 시 TSC+실링처리(TSC+Sealing)의 안정적인 전위 형성을 통해 실링처리 효과를 확인하였다. 양극분극 실험 결과 TSC와 TSC+Sealing에서 부동태 영역이 확인되었으며, 부식 손상 역시 관찰되지 않아 내식성이 개선되었다. 더불어 타펠분석에 의해 산출된 부식전위와 부식전류밀도 분석 결과 TSC+Sealing의 내식성이 가장 우수하게 나타났다.

• International Journal of Naval Architecture and Ocean Engineering
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• 제12권1호
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• pp.645-656
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• 2020

In this study (Part II), the empirical formulation of corrosion model of a ship's ballast tank was developed to predict nonlinear time-dependent corrosion wastage based on the advanced data processing technique proposed by Part I. The detail on how to propose generalised mathematical formulation of corrosion model was precisely documented in the previous paper (Part I). The statistical scatter of corrosion data at any exposure time was investigated by the refined method and formulated based on a 2-parameter Weibull distribution which selected the best fit PDF. Throughout the nine (9) steps, empirical formulation of the ship's seawater ballast tank was successfully proposed and four (4) key step results were also obtained. The proposed method in Part I was verified and confirmed by this application of seawater ballast tank, thus making it possible to predict accurate behaviours of nonlinear timedependent corrosion. Developed procedures and obtained corrosion damage model for ship's seawater ballast tank can be used for development of engineering software.