• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.05a
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• pp.96-102
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• 2002

This paper was studied on the wear-corrosion behavior of ductile cast iron in the acidic environment. In the dry atmosphere and variety of pH solution, wear-corrosion characteristics and friction coefficient of GCD 60 with various sliding speed and distance were investigated. And electrochemical polarization test of GCD 60 was examined in the environment of various pH value. The main results are as following : In the dry atmosphere, boundary friction appears below nearly 5 $kg_{f}$ of contact load, and it is considered that solid friction occurs over nearly 5 $kg_{f}$ of contact load. As pH value becomes low, wear-corrosion loss in the aqueous solution increases. As the corrosion environment is acidified, corrosion potential of GCD 60 becomes noble, polarization resistance becomes low, and corrosion current density increases.

• Journal of Korea Foundry Society
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• v.36 no.4
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• pp.117-125
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• 2016

The effects of the Zn content on the microstructure and corrosion behavior in 1M NaCl solution were investigated in Mg-(0~6)%Zn casting alloys. The MgZn phase was scarcely observed in the Mg-1%Zn alloy, while the Mg-(2~6)%Zn alloy consisted of ${\alpha}$-(Mg) and MgZn phases. With an increase in the Zn content, the amount of the MgZn phase was gradually increased. Immersion and electrochemical corrosion tests indicated that the Mg-1%Zn alloy had the lowest corrosion rate among the alloys, and a further increase in the Zn content resulted in the deterioration of the corrosion resistance. Microstructural examinations of the corroded surfaces and EIS analyses of surface corrosion films revealed that the best corrosion resistance at 1%Zn was associated with the absence of MgZn phase particles in the microstructure and the contribution of Zn element to the formation of a protective film on the surface. A micro-galvanic effect by the MgZn particles led to the increased rate of corrosion at a higher Zn content.

• Journal of Ocean Engineering and Technology
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• v.14 no.4
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• pp.23-29
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• 2000

When the concrete structures were being made with sand containing chloride ion it was knows that corrosion rate of reinforced steel embedded in concrete with chloride ion was higher than that of concrete with on chloride ion. In this study, the operation of Friedel salts affecting the corrosion behavior of reinforced steel embedded in cement mortar was investigated with electrochemical view. Corrosion potential of reinforced steel embedded in cement mortar with sand containing chloride ion was shifted noble direction than that of cement mortar with no chloride ion after immersed 5 month in natural sea water and also corrosion current density decreased with shifting corrosion potential to noble direction. However Friedel salts appeared from surface to 2.5cm of inside direction of mortar specimen, which is located at 11.5$\circ$(2$\theta$) in XRD analysis and the amount of Ca(OH)2 by SEM photograph in cement mortar with chloride ion was larger than that of cement mortar with mo chloride ion. Eventually it is suggested that Friedel salts was resulted from chloride ion and it acted as the corrosion inhibitor.

• Corrosion Science and Technology
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• v.9 no.2
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• pp.98-103
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• 2010

In order to further reduce the cost without reducing the corrosion resistance, a high-manganese austenitic alloy for sink roll or stabilizer roll in continuous hot-dip coating lines was developed. A systematic study of corrosion behavior of the high-manganese austenitic alloy in pure zinc bath at $490^{\circ}C$ was carried out. The results shows that, the high-manganese austenitic alloy shows better corrosion resistance than 316L steel. The corrosion rate of the high-manganese austenitic alloy in pure zinc bath is calculated to be approximately $6.42{\times}10^{-4}g{\cdot}cm^{-2}{\cdot}h^{-1}$, while the 316L is $1.54{\times}10^{-3}g{\cdot}cm^{-2}{\cdot}h^{-1}$. The high-manganese austenitic alloy forms a three-phase intermetallic compound layer morphology containing ${\Gamma$}, ${\delta}$ and ${\zeta}$ phases, while the 316L is almost ${\zeta}$ phase. The ${\Gamma}$ and ${\delta}$ phases of the high-manganese austenitic alloy contain about 8.5 wt% Cr, the existence of Cr improve the stabilization of phases, which slow down the reaction of Fe and Zn, improve the corrosion resistance of the high-manganese austenitic alloy. So substitute the nickel with the manganese to manufacture the high-manganese austenitic alloy of low cost is feasible.

• Corrosion Science and Technology
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• v.18 no.1
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• pp.24-32
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• 2019

The effects of zinc coating and heat treatment on the corrosion resistance of aluminum alloys including A1100 and the modified A3003, used as heat exchanger tube were investigated in this study. The grain size of the heat-treated specimen is larger than that of the specimen without heat treatment, but the grain size did not significantly affect the corrosion behavior. The concentration of zinc was noted at 11.3 ~ 31.4 at.% for the as-received Zn-coated samples and reduced to 1.2 ~ 2.4 at.% after the heat treatment, as measured by the scanning electron microscopy (SEM) with an energy dispersive spectrometer (EDS) on the surface. The concentration of oxygen is 22 ~ 46 at.% for the zinc coated specimens while noted at 7.4 ~ 12.8 at.% for the specimens after the removal of the coating. The corrosion behavior depended largely on the concentrations of zinc, aluminum, and oxygen on the specimen surface, but not on the Mo content. The corrosion potential was high and the corrosion rate was low for a specimen with a low zinc content, a high aluminum content, and a high oxygen content.

• Nuclear Engineering and Technology
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• v.54 no.6
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• pp.1954-1961
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• 2022

Lead-based fast reactor (LFR) has become one of the most promising reactors for Generation IV nuclear systems. A developing trend of LFR is high efficiency, along with operation temperatures up to 800 ℃ or even higher. One of key issues in the high-efficiency LFR is corrosion of cladding materials with lead at high temperatures. In this study, corrosion behavior of some refractory metals (Nb, Nb521, and Mo-0.5La) was investigated in static lead at 1000 ℃ for 1000 h. The results showed that Nb and Nb521 exhibited an intense dissolution corrosion with obvious lead penetration after corrosion, and lead penetration extended along the grain boundaries of the specimens. Furthermore, Nb521 showed a better corrosion resistance than that of Nb as a result of the elements of W and Mo included in Nb521. Mo-0.5La showed much better corrosion resistance than that of Nb and Nb521, and no lead penetration could be observed. However, an etched morphology appeared on the surface of Mo-0.5La, indicating the occurrence of corrosion to a certain degree. The results indicate that Mo-0.5La is compatible with lead up to 1000 ℃. While Nb and Nb alloys might be not compatible with lead for high-efficiency LFR at such high temperatures.

• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.1
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• pp.54-63
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• 2023

In this paper, the effect of corrosion level and crack width on the cohesive strength-slip behavior of corroded steel rebar and concrete interface is conducted. The existing studies mainly focus on the decrease in bond strength with respect to the level of corrosion; there are, however, few studies on the decrease in cohesive strength according to the crack width of the concrete surface due to corrosion. Therefore, in this study, a series of tests for the cohesive strength, slip behavior and mass loss of the reinforcing bar is evaluated at the surface of corroded rebar and concrete. It is found that the tendency to decrease the bond strength is closely related to the crack width rather than the corrosion level. Hence, to determine the degradation performance for the bond strength-slip behavior relation, the occurrence of cracks on the concrete surface can be a suitable index.

• Corrosion Science and Technology
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• v.3 no.1
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• pp.6-13
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• 2004

The effect of inhibitors on the electrochemical behavior and the stress corrosion cracking resistance of Alloy 600(UNS N06600) was evaluated in 10% sodium hydroxide solution at $315^{\circ}C$. The specimens of a C-ring type for stress corrosion cracking test were polarized at 150 mV above the corrosion potential for 120 hours with and without inhibitors such as titanium oxide, titanium boride and cerium boride. The chemical compositions of the films formed on the crack tip in the C-ring specimens were analyzed using a scanning Auger electron spectroscopy. The cerium boride, the most effective, was observed to decrease the crack propagation rate more than a factor of three compared with that obtained in no inhibitor solution. It was found that the changes of the active-passive transition potentials and the film compositions were related to the resistance to stress corrosion cracking in high temperature caustic solution.

• Journal of Technologic Dentistry
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• v.30 no.2
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• pp.9-16
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• 2008

The surface microstructural changes, mechanical properties and corrosion resistance of Ti-Pd alloys for dental biomaterials have been investigated. Ti, Ti-Pd alloys were melted in arc furnace and the corrosion resistance of Ti-Pd alloys was evaluated by anodic polarization test. The surface microstructural changes and mechanical properties of Ti-Pd alloys were analysed by scanning electron microscope and Vickers micro-hardness tester. The vickers hardnees of pure Ti improved by addition of Pd but Ti-25Pd alloy showed decreasing compared with Ti-15Pd. And anodic polarization and potentiostatic test were conducted in 5% HCl to quantify the resistance to corrosion with the addition of Pd, There was no significant difference in corrosion resistance between pure Ti, Ti-5Pd and Ti-15Pd alloy. However, Ti-25Pd alloy showed decreasing compared with pure Ti in corrosion resistance. From these results, it was concluded that newly formulated Ti-15Pd experimental alloy have adequate hardness and high corrosion resistance, and this alloy is promising candidate for a successful dental casting alloy.

• Journal of the Korean institute of surface engineering
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• v.24 no.1
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• pp.34-34
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• 1991

Corrosion behavior of TiN coated steel was studied in terms of thickness of interlayer Ti and TiN coating TiN was are ion plated to a thickness of 1$\mu\textrm{m}$ and 2$\mu\textrm{m}$ respectively with interlayer coating of Ti of 1$\mu\textrm{m}$, 2$\mu\textrm{m}$ and 3$\mu\textrm{m}$. Corrosion resistance of TiN coated steel was evaluated by anodic palarization test in 1N H2SO4 as well as salt spray test. Porosity of each coating was also tested by using SO2 test method. Corrosion current density decreased with increasing TiN coating thickness and Ti interlayer coating markedly enhanced the corrosion resistance. Ti interlayer coating of 2$\mu\textrm{m}$ and 3$\mu\textrm{m}$ prior to 2$\mu\textrm{m}$ TiN coating decreased the corrosion current density of active range by an order of 4 and that of passive range by an order of 2. This improvement was associated with the retardation of corrosive agent penetration with increasing coating thickness and inherent corrosion resistance of Ti interlayer. Ti interlayer coating was also very effective in improvement of corrosion resistance under salt atmosphere.