• Title/Summary/Keyword: Corrosion potential

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A STUDY ON THE CORROSION OF AMALGAMS IN CHLORIDE SOLUTION (Chloride용액에서의 아말감부식에 대한 연구)

  • Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.23 no.1
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    • pp.502-514
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    • 1998
  • The purpose of this study is to observe the corrosion characteristcs of four dental amalgams(CAULK FINE CUT, CAULK SPHERICAL, DISPERSALLOY, TYTIN) and to determine a function of chloride concentration through the anodic polarization curve obtained by using a potentiostat. After each amalgam alloy and Hg being triturated, the triturated mass was inserted into the cylinderical metal mold, and condensed by hydrolic pressure. Each specimen was removed from the metal mold. 24 hours after condensation, specimens were polished with the emery paper and stored at room temperature for 6 months. The anodic polarization curves were employed to compare the corrosion behaviours of the amalgam m KCl and KCl-NaCl solution, which had chlonde concentration of 0.4 g/l, 0.8 g/l, 1.2 gil, and 1.6 gil at $37^{\circ}C$ with 3-electrode potentiostat. After the immersion of specimen in electrolyte for 1 hour, the potential scan was begun. The potential scan range was - 1500mV ~+800mV(vs. S.C.E.) in the working electrode and the scan rate was 50mV/sec. The results were as follows, 1. The corrosion potential. the potential of anodic current peak, and transpassive potential in the solution of high chloride concentration shifted to more cathodic direction than those in the solution of low concentration, and the current density in the solution of high chloride concentration was higher than that in the solution of low concentration. 2. The corrosion potential, the potential of anodic current peak, and transpassive potential for CAULK FINE CUT amalgam were the most cathodic among the others, and the current density were the highest among the others. 3. In the solution of low chloride concentration, the corrosion potential, the potential of anodic current peak, and transpassive potential for DISPERSALLOY were the most anodic among the others, however in the solution of high chloride concentration, those for TYTIN were the most anodic among the others. 4. The anodic polarization curve for CAULK SPHERICAL was similar to that for high copper amalgams.

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Energy harvesting techniques for remote corrosion monitoring systems

  • Kim, Sehwan;Na, Ungjin
    • Smart Structures and Systems
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    • v.11 no.5
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    • pp.555-567
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    • 2013
  • An Remote Corrosion Monitoring (RCM) system consists of an anode with low potential, the metallic structures against corrosion, an electrode to provide reference potential, and a data-acquisition system to ensure the potential difference for anticorrosion. In more detail, the data-acquisition (DAQ) system monitors the potential difference between the metallic structures and a reference electrode to identify the correct potential level against the corrosion of the infrastructures. Then, the measured data are transmitted to a central office to remotely keep track of the status of the corrosion monitoring (CM) system. To date, the RCM system is designed to achieve low power consumption, so that it can be simply powered by batteries. However, due to memory effect and the limited number of recharge cycles, it can entail the maintenance fee or sometimes cause failure to protect the metallic structures. To address this issue, the low-overhead energy harvesting circuitry for the RCM systems has designed to replenish energy storage elements (ESEs) along with redeeming the leakage of supercapacitors. Our developed energy harvester can scavenge the ambient energy from the corrosion monitoring environments and store it as useful electrical energy for powering local data-acquisition systems. In particular, this paper considers the energy harvesting from potential difference due to galvanic corrosion between a metallic infrastructure and a permanent copper/copper sulfate reference electrode. In addition, supercapacitors are adopted as an ESE to compensate for or overcome the limitations of batteries. Experimental results show that our proposed harvesting schemes significantly reduce the overhead of the charging circuitry, which enable fully charging up to a 350-F supercapacitor under the low corrosion power of 3 mW (i.e., 1 V/3 mA).

Effects of Plasma-Nitriding on the Surface Characteristics of Stainless Steels Containing Nb (Nb함유 스테인리스강의 표면특성에 미치는 플라즈마질화의 영향)

    • Journal of the Korean institute of surface engineering
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    • v.37 no.2
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    • pp.119-127
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    • 2004
  • In order to develop the corrosion and wear resistance of stainless steels, effects of plasma-nitriding on the surface characteristics of stainless steels containing Nb were investigated by utilizing a potentiostat. It was found that plasma nitriding at $350^{\circ}C$, compared with $500^{\circ}C$, produced a good corrosion resistance as nitriding time increased, whereas stainless steel containing low Nb content showed that pitting potential and corrosion potential decreased.

A Study of Non-destructive Measurement on the Reinforced Concrete Structure Damaged by Reinforcing Steel Corrosion (철근콘크리트구조물의 철근부식에 대한 비파괴 측정과 부식에 따른 균열거동)

  • 김성운;정한중;김창환;임선택
    • Proceedings of the Korea Concrete Institute Conference
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    • 1991.10a
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    • pp.80-85
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    • 1991
  • This experimental study was performed to derive the relationship between the measured values(corrosion potential) and the actual amount of corrosion products(reinforcing steel weight loss rate). Also the growth of crack due to the steel corrosion was oberved. First, the reinforcing steel of R/C specimen was corroded with chloride penetration and accelerated galvanostatic corrosion method. And then, the corrosion potential of reinforcing steel was measured with nondestructive tester.

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A Study on the Estimation of Steel Corrosion in Concrete Exposed under the Environment of Seawater (해양환경하에 방치한 콘크리트중의 철근의 부식 추정에 대한 연구)

  • 문한영;김성수;류재석
    • Magazine of the Korea Concrete Institute
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    • v.6 no.2
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    • pp.129-137
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    • 1994
  • This study was performed for the purpose of obtaining the fundamental data to establish the criterion of concrete deterioration and presuming steel corrosion of concrete structures under the environment of seawater. Steel embedded concrete specimens were exposed in seawater for 1year. The soluble chloride content in concrete, corrosion potential and steel corrosion were considered. The results show that soluble chloride content in concrete was decreased with lower water-cement ratio and with mineral admixtures. Half-cell potential is reduced with steel corrosion. Corrosion area ratio is correlative with half-cell potential.

Electrochemical Study on the Effect of Post-Weld Heat Treatment Affecting to Corrosion Resistance Property of the Weldment of SCM440 Steel (SCM440강 용접부의 내식성에 미치는 용접후 열처리효과에 관한 전기화학적 연구)

  • 김성종;김진경;김종호;김기준;김영식;문경만
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.6
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    • pp.78-88
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    • 2000
  • The effect of post-weld heat treatment(PWHT) of SCM440 steel was investigated with parameters such as micro-Vickers hardness, corrosion potential, polarization behaviors, galvanic current, Al anode generating current and Al anode weight loss, etc. Each hardness of three parts(HAZ, BM, WM) by PWHT is lower than each of as-welded parts. However, hardness of WM area was the highest among those three parts in case of both PWHT and as-welded. Corrosion potential of WM part was the highest among those three parts and WM area was also acted as cathode without regard to PWHT. The magnitude of corrosion potential difference among three parts by PWHT was larger than that of three parts of as-welded, and corrosion current by galvanic cell of these three parts by PWHT was also larger compared to as-welded. Therefore, it is suggested that corrosion resistance property of SCM440 steel is decreased by PWHT than as-welded. However, both Al anode generating current and anode weight loss were also increased by PWHT compared to as-welded when SCM400 steel is cathodically protected by Al anode.

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A Study on the Mechanism of Crevice Corrosion for 430 Stainless Steel (430 스테인리스강의 틈부식 발생기구에 대한 연구)

  • 백신영;나은영
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.3
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    • pp.447-452
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    • 2003
  • Crevice corrosion is localized form of corrosion usually associated with a stagnant solution on the micro-environmental level. Such stagnant micro environments tend to occur in crevices (shielded areas) such as those formed under gaskets washers insulation material. fastener heads. surface deposits. disbonded coatings. threads. lap joints and clamps. Crevice corrosion is initiated by changes in located electrochemical reaction within the crevice such as a) depletion of inhibitor in the crevice b) depletion of oxygen in the crevice c) a shift to acid conditions in the crevice and d) build-up of aggressive ion species (e.g chloride) in the crevice. In this study. the mechanism of crevice corrosion for Type 430 stainless steel is investigated undercondition that the size of specimen is $15{\times}20\{times}3mm$, in 1N $H_2SO_4$ + 0.05N NaCl solution. and the artificial crevice gap size of 3 x 0.2 x 15 mm. Crevice corrosion is measured under applied potential -300mV(SCE) to the external surface. The obtained result of this study showed that 1) the induced time for initiation of crevice is 750 seconds. 2) potential of the crevice was about from -320mV to -399mV. which is lower than that of external surface potential of -300mV It is considered that potential drop in the crevice is one of mechanisms for the crevice corrosion

Study on the Characteristics of Corrosion for Epoxy Coated Steel Structure (에폭시도막 강구조물의 부식특성에 관한 연구)

  • Lim, U-Jo;Cheun, Jeong-Hyun;Jeong, Gi-Cheol
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.34 no.2
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    • pp.223-230
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    • 1998
  • Recently, with the rapid development in the industries such as mechanical plants, automobiles, ships and marine structures, it is enlarged by the use of the SS 41 steel. This mechanical plants and marine structures are exposed m corrosion because of Cl-under marine environments. To protect their accidents, mainly applied anti-corrosion epoxy coating and various protective its structures. In this study, corrosion control characteristics on the epoxy coating were investigated by the galvanic corrosion of impressed voltage tester under marine environments The main results obtained are as follows; 1. Corrosion current density of amine-epoxy coating becomes more increased than that of other epoxy coating and the time area rate of pin hole and pit until 5% becomes most rapid. 2. The potential of SUS 304 stainless steel(cathode) for Al-epoxy coating is nearly zero potential. 3. Corrosion current density of Amine-epoxy by shot blast becomes more decreased than that of not shot blast and cathodic potential becomes more noble. 4. As distance of anode and cathode is more decreased, corrosion current density of epoxy coating is more increased and cathodic potential becomes less noble.

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Effects of Torsional Stress on the Corrosion Characteristics in the Rotor Assembly of Marine Diesel Engine Supercharger (선박용 디젤엔진 과급기 로터 접합체의 부식특성에 미치는 비틀림응력의 영향)

  • Jo, S.K.;Kong, Y.S.;Kim, Y.D.
    • Journal of Power System Engineering
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    • v.9 no.1
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    • pp.50-56
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    • 2005
  • The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded torsional stress. The surface corrosion pattern of SCM440 area was showed global corrosion and narrow pitting, that was cause by galvanic corrosion between friction welded IN713LC and SCM440. But corrosion does not proceeded from IN713LC area. Initially, the average relative electrode potential and corrosion current were decreased suddenly, by and large, it was stabilized gradually tend to decreasing with the elapse of the immersion time. The corrosion rate was decreased by increasing the load stress, but 200 MPa specimen was showed most large value.

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Study on the Crevice Corrosion Behavior of SS 400 in Marine Environment (해양환경중에서 SS400강재의 간극부식거동에 관한 연구)

  • 임우조;정기철;안석환;윤병두
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2000.11a
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    • pp.1-6
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    • 2000
  • This paper was studied on the crevice corrosion behavior of SS 400 in marine environment. In 0%, 2%, 3.5%, 5% NaCl solution, the aspect of the crevice corrosion and polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 with crevice and non-crevice was measured according to the NaCl concentration. The main results obtained are as follows : 1) Under crevice corrosion, the corrosion potential become less noble as the concentration of NaCl solution increased. 2) The current density under open circuit potential was high drained as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, the current density was low drained. 3) The weight loss rate of SS400 was increased as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, that of SS400 was decreased.

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