• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.178-184
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• 2010

The aim of this work is the fabrication of polyelectrolyte microcapsules composed of biocompatible polymers such as chitosan, heparin and alginate, to encapsulate the fluorescein isothiocyanate(FITC)-albumin, and to investigate the protein release behavior therefrom. Polyelectrolyte capsules with 4-layer structures could be prepared with biocompatible materials by oppositely charged adsorption using melamin-foramide as a template. Transmission electron microscope(TEM), scanning electron microscope(SEM) and optical microscope confirmed hollow capsule structures. Protein release before and after encapsulation was monitored with a UV-Vis spectrometer. Microcapsules have different behaviors depending on the kind of polyelectrolyte polymers, chitosan-heparin capsules or chitosan-alginate capsules. In conclusion, the polyelectrolyte multilayer shells can be switched between an open and closed state by means of tuning the pH value.

• Bulletin of the Korean Chemical Society
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• v.33 no.2
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• pp.393-397
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• 2012

We report a new route to synthesize high quality zinc blende CdS and ZnS nanocrystals in noncoordinating solvent 1-octadecene, using dodecanethiol (DDT) molecules as both the sulfur source and surface capping ligands. Different reaction temperatures and Cd(Zn)/DDT molar ratios were tested to optimize the synthesis conditions. Absorption photoluminescence (PL) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) pattern, and transmission electron microscopy (TEM) were used to characterize assynthesized nanocrystals. The narrow half width at the half-maximum on the long wavelength side of the firstexcitonic absorption peak and TEM images demonstrated nearly monodisperse size distributions of asprepared CdS, ZnS, and CdS/ZnS core/shell nanocrystals. Only trap emissions of the nanocrystals were detected when the amount of DDT was excessive, this came from the strong quenching effect of thiol groups on the nanocrystal surfaces. After overcoating with ZnS shells, band-gap emissions of CdS nanocrystals were partially recovered.

• Steel and Composite Structures
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• v.18 no.4
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• pp.1001-1021
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• 2015

Ultra-lightweight cement composite (ULCC) with a compressive strength of 60 MPa and density of $1,450kg/m^3$ has been developed and used in the steel-concrete-steel (SCS) sandwich structures. This paper investigates the structural performances of SCS sandwich composite beams with ULCC as filled material. Overlapped headed shear studs were used to provide shear and tensile bond between the face plate and the lightweight core. Three-dimensional nonlinear finite element (FE) model was developed for the ultimate strength analysis of such SCS sandwich composite beams. The accuracy of the FE analysis was established by comparing the predicted results with the quasi-static tests on the SCS sandwich beams. The FE model was also applied to the nonlinear analysis on curved SCS sandwich beam and shells and the SCS sandwich beams with J-hook connectors and different concrete core including ULCC, lightweight concrete (LWC) and normal weight concrete (NWC). Validations were also carried out to check the accuracy of the FE analysis on the SCS sandwich beams with J-hook connectors and curved SCS sandwich structure. Finally, recommended FE analysis procedures were given.

• The Journal of the Acoustical Society of Korea
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• v.25 no.2E
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• pp.49-55
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• 2006

Compressional wave velocity (Vp), shear wave velocity (Vs), elastic and physical properties, and electrical resistivity for two core sediments obtained from Southeastern Yellow Sea Mud (SEYSM) were measured and computed. The sediments consist of homogeneous mud (mostly silt and clay) with shells and shell fragments. As a result, the mean grain size is uniform ($7.5-8.5{\Phi}$ throughout the core sediments. However, physical properties such as wet bulk density and porosity show slightly increasing and decreasing patterns with depth, compared to the mean grain size. The compressional (about 1475 m/s in average) and shear wave (about 60 m/s in average) velocities with depth accurately reflect the pattern of wet bulk density and porosity. Electrical resistivity is more closely correlated with compressional wave velocity than physical properties. The computed Vp/Vs and Poisson's ratios are relatively higher (more than 10) and lower (approximately 0.002) than Hamilton's (1979) data, respectively, suggesting the typical characteristics of soft and fully water-saturated marine sediments. Thus, the Vp/Vs ratio in soft and unconsolidated sediments is not likely sufficient to examine lithology and sediment properties. Relationships between the elastic constant and physical properties are correlated well. The elastic constants (Poisson's ratio, bulk modulus, shear modulus) given in this paper can be used to characterize soft marine sediments saturated with seawater.

• Structural Engineering and Mechanics
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• v.70 no.3
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• pp.351-365
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• 2019

In this paper, free vibration of Cooper-Naghdi micro sandwich cylindrical shell with saturated porous core and reinforced carbon nanotube (CNT) piezoelectric composite face sheets is investigated by using first order shear deformation theory (FSDT) and modified couple stress theory (MCST). The sandwich shell is subjected to magneto-thermo-mechanical loadings with temperature dependent material properties. Energy method and Hamilton's principle are used for deriving of the motion equations. The equations are solved by Navier's method. The results are compared with the obtained results by the other literatures. The effects of various parameters such as saturated porous distribution, geometry parameters, volume fraction and temperature change on the natural frequency of the micro-sandwich cylindrical shell are addressed. The obtained results reveal that the natural frequency of the micro sandwich cylindrical shell increases with increasing of the radius to thickness ratio, Skempton coefficient, the porosity of the core, and decreasing of the length to radius ratio and temperature change.

• Journal of Powder Materials
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• v.11 no.4
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• pp.328-332
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• 2004

Fe nanopowders were successfully synthesized by plasma arc discharge (PAD) process using Fe rod. The influence of chamber pressure on the microstructure was investigated by means of X-ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FE-SEM), Transmission Electron Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). The prepared particles had nearly spherical shapes and consisted of metallic cores (a-Fe) and oxide shells (Fe$_{3}$O$_{4}$), The powder size increased with increasing chamber pressure due to the higher dissolution and ejection rate of H$_2$ and gas density in the molten metal.

• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3583-3589
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• 2014

This study evaluated a simple and useful route to the synthesis of mesoporous $TiO_2$ microcapsules with a hollow macro-core structure. A hydrophilic precursor sol containing the surfactants in the hydrophobic solvents was deposited on PMMA polymer surfaces modified by non-thermal plasma to produce mesoporous shells after calcination. The surface of the PMMA polymer spheres was coated with $NH_4F$ and CTAB to control the interfacial properties and promote the subsequent deposition of inorganic sols. These hollow type mesoporous $TiO_2$ microcapsules could be applied as an efficient substrate for the immobilization of DNA oligonucleotides.

• Journal of the Korean Society for Railway
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• v.6 no.3
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• pp.194-202
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• 2003

To make railway carbody light in weight has advantages at some aspects of both manufacturing and maintenance. Recently, railway carbodys of steel structure have been lightened their weight by using aluminum extrusion plate. for the additional lightening of railway carbody, an optimal design which maintains proper strength and minimizes weight must be achieved. Optimization which is used with finite element analysis for aluminum extrusion plate has the disadvantage of consuming much time. In this paper, the method of equivalent material property which is available to FEA code is established using the method of equivalent stiffness. This method for plate is expanded into the method for railway carbody structure with plates and shells. An objective function is established for maximum stiffness of unit aluminum extrusion plate using established method of equivalent material property. We performed an multi-objective optimization using the penalty function method. As a result, recommendable shapes and sizes of unit extrusion plate for under-frame of high speed train is presented.

• Journal of Ceramic Processing Research
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• v.13 no.spc1
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• pp.59-63
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• 2012

Ga2O3-core/CdO-shell nanowires were synthesized by a two step process comprising thermal evaporation of GaN powders and sputter-deposition of CdO. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) analyses revealed that the cores and the shells of the annealed coaxial nanowires were single crystal of monoclinic Ga2O3 and FCC CdO, respectively. As-synthesized Ga2O3 nanowires showed a broad emission band at approximately 460 nm in the blue region. The blue emission intensity of the Ga2O3 nanowires was slightly decreased by CdO coating, but it was significantly increased by subsequent thermal annealing in a reducing atmosphere. The major emission peak was also shifted from ~500 nm by annealing in a reducing atmosphere, which is attributed to the increases in the Cd interstitial and O vacancy concentrations in the cores.

• Journal of the Korea Furniture Society
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• v.26 no.2
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• pp.138-144
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• 2015

Among several thermal wood modification methods German oil heating technology was applied for color changing larch and paulowniawood specimens. They were heat treated at $200^{\circ}C$ for 3 hours in an autoclave filled with linseed oil. The CIE $L^*a^*b^*$ color indexes of the shells and cores of the oil heated specimens were measured. The color difference indexes between the oil heated and the control specimens of larch and paulowniawood were in the range of 6 and 12, which implies considerably different. The color difference indexes between the core layers of the larch and paulowniawood specimens were 4.3 and 1.7, respectively. It could be concluded that the specimens of the two species were color changed uniformly by oil heating.