• Journal of the Korean Ceramic Society
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• v.28 no.10
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• pp.793-802
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• 1991

The multicrystalline machinable ceramics was fabricated by melting method using domestic pyrophyllite. After determination of optimum crystallization temperature and time from results of DTA, XRD and SEM, base glasses were heat treated by 2-step schedule. Main crystalline phases identified by XRD, EDX were Na-fluorophlogopite, ${\beta}$-spoduemen and ${\alpha}$-cordierite, and the crystallization condition of these crystals was varied with chemical composition, thermal history and nucleation agents. The thermal, chemical properties of prepared samples were excellent.

• Journal of the Korean Ceramic Society
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• v.26 no.3
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• pp.347-360
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• 1989

Spinel, mullite, forsterite and cordierite composition powders were synthesized from Mg(NO3)2.6H2O, Al(NO3)3.9H2O and SiCl4-ethanol solution by spray pyrolysis method and the sinterability of these powders were investigated. The bulk density of spinel and mullite specimens sintered at 1,$700^{\circ}C$ for 1hr was 3.56g/㎤(99.5% relative density) and 3.16g/㎤(99.7% relative density), respectively. (Green compacts were made from powders prepared at 1,00$0^{\circ}C$). The bulk density of forsterite and cordierite specimens sintered at 1,480 and 1,40$0^{\circ}C$ for 2hrs were 3.217 and 2.155g/㎤, respectively. (Green compacts were made from powders prepared at 1,00$0^{\circ}C$). The constituent compositions of spinel and mullite specimens sintered at 1,$700^{\circ}C$ for 1hr were 27.5wt% MgO and 70.5wt% Al2O3, respectively. Vickers microhardness and fracture toughness of spinel sintered at the above condition were 13.7GPa and 2.6MN.m3/2, respectively, and room temperature bending strength, 425MPa, was nearly maintained even at the elevated temperature. In the case ofmullite specimens, those values were 13.5GPa, 2.2MN/m3/2 and 430MPa, respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.11a
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• pp.185-186
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• 2005

저온소결 Glass/Ceramic계 기판재료 조성으로 $Al_2O_3$, $SiO_2$, Cordierite, $Al_2O_3{\cdot}3SiO_2$의 4가지 filler에 zinc-borosilicate(ZBS) glass를 첨가하여 기판재료로의 사용가능성을 조사하였다. 4가지 filer에 ZBS glass를 30$\sim$50vol%첨가하여 $700\sim950^{\circ}C$에서 2시간 소결한 결과 40, 50vol%첨가 했을 때 900$^{\circ}C$에서 치밀한 소결체를 얻을 수 있었다. LSI칩 신호라인의 빠른 신호전달에 직접적인 영향을 주는 유전율은 기존의 $Al_2O_3$기관($\fallingdotseq$9.7)보다 저유전율 ($900^{\circ}C$에서 $Al_2O_3$-50vol%ZBS 5.7, $SiO_2$-50vol%ZBS 5.9, Cordierite-40vo1%ZBS 5.9, $Al_2O_3${\cdot}3SiO_2$-50vol%ZBS 4.9)을 나타내어 저온소결 기판재료로 사용이 가능함을 확인하였다.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.3
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• pp.223-233
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• 2011

A ceramic monolithic catalyst is a honeycomb structure that consists of two layers. The honeycomb structure is regarded as a continuum in structure and heat-flow analysis. The equivalent mechanical properties of the honeycomb structure were determined by performing finite element analysis (FEA) for a test specimen. Bending strength experiments and FEA of the test specimen used in ASTM C1674-08 standard test were performed individually. The bonding coefficient between the cordierite ceramic layer and the washcoat layer was almost zero. The FEA test specimen was modeled on the basis of the bonding coefficient. The elastic modulus, Poisson's ratio, and the thermal properties of the ceramic monolithic substrate were determined by performing the FEA of the test specimen.

• Journal of the Korean Ceramic Society
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• v.35 no.7
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• pp.706-714
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• 1998

The MgO-{{{{ { {Al }_{2 }O }_{3 } }}-{{{{ { {SiO }_{2 } }_{ } }}system containing alumina powder was fabricated sintered at various temperature and analyzed in order to study the sintering mechanism and crystallization characteristics. The specimen composed of glass powder with average particle size of 8.27 $\mu\textrm{m}$ and 0-40 vol% alumina powder were sint-ered for 3 hrs at the temperature between 850$^{\circ}C$ and 1350$^{\circ}C$ The sintering mechanism consists of the redis-tribution of particles occuring at 750$^{\circ}C$ and the viscous flow at 850∼950$^{\circ}C$. The degree of crystallization and sintering temperatue were dependent upon the ratio of glass/alumina. The second phase from the reaction between glass and alumina was not observed which was confirmed by XRD and properties analysis. The density dielectric constant and specific resistivity of specimen were 2.30∼3.26g/cm2 5.8∼7.38 at 1 GHz density dielectric constant and specific resistivity of specimen were 2.30∼3.26g/cm3 5.8∼7.38 at 1GHz and 1.23∼4.70${\times}$107 $\Omega$$.$m respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.304-304
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• 2008

최근 이동통신의 사업의 발달로 인하여 제품의 고속신호 전달에 대한 관심이 부각되고 있다. 이로 인해 고집적 LTCC 모듈로 제작이 가능하고 고속신호 전달이 용이한 저유전율과 낮은 loss특성을 요구하는 소재 개발의 지속적인 연구를 필요로 한다. 지금까지의 ceramic/glass composite에서 주로 사용된 ceramic filler는 $Al_2O_3$로 낮은 유전율을 구현하는데 한계가 있었다. Cordierite는 낮은 유전율(${\varepsilon}r$ < 4)을 나타내는 filler로서 저유전율 기판소재로 사용될 가능성이 높지만 아직까지 보고된 결과들이 미흡한 실정이다. 선행 연구에서 cordierite filler와 $SiO_2-B_2O_3-Al_2O_3$-RO (R Zn, Sr, Ba, Ca)계의 glass를 혼합하여 LTCC 용 기판소재로서의 가능성을 확인한 결과 5.0~5.5 의 낮은 유전율과 1,000~1,500의 Q를 나타내는 것을 확인 하였다. 하지만 sheet로 제작 시 $B_2O_3$ 계로 인해 볼밀 공정에서 슬러리를 응집시켜 점도를 증가(gelation)시키는 현상이 발생하였다. 이를 개선하기 위한 glass 조성의 $B_2O_3$ 함량을 5%줄여 만든 glass를 이용해 미세구조, 유전율과 Q 그리고 강도를 측정하였다.

• Journal of the Korean Ceramic Society
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• v.31 no.4
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• pp.427-435
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• 1994

Cu-metallized low firing temperature substrates were synthesized by cofiring green sheet of cordierite-based glass with Cu. By Sol-Gel method, Cu powder was coated with borosilicate gel which should act as a glass frit in Cu paste during cofiring. Theoretical weight ratios of Glass/Cu were controlled to be 2.5, 5, 10 and 15% by varying alkoxide concentrations. Average particle size of coated Cu was 0.629~0.674 ${\mu}{\textrm}{m}$ in comparison to that of as-received Cu(0.596 ${\mu}{\textrm}{m}$), which increased with alkoxide concentration but did not increase above certain concentration. The weight ratios of coated layer were 2.11~5.37%. The properties of Cu-metallized low firing temperature substrate, cofired at 90$0^{\circ}C$ for 1h under H2/N2 atmosphere, were as follows; sheet resistance was 13~43 m{{{{ OMEGA }}/$\square$, adhesion strength was 1.0~2.1 kgf/$\textrm{mm}^2$. From the observations of SEM photographs, the gel coated on Cu performed excellently as a glass frit.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.30 no.12
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• pp.776-781
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• 2017

In this study, we investigated the effect of electrode pattern design on the thermal shock resistance and temperature uniformity of a ceramic heater. A cordierite substrate with a low thermal expansion coefficient was fabricated by tape casting, and a tungsten electrode was printed and used as a heating element. The temperature distribution of the ceramic heater was calculated by a finite-element method (FEM) by considering various electrode patterns, and the tensile stress distribution due to the thermal stress was calculated. In the electrode pattern with a single-line width, the central part of the ceramic heater was heated to the maximum temperature, and the position of the ceramic heater having a double-line width was changed to the maximum temperature, depending on the position of the minimum line width pattern. The highest tensile stress was found along the edges of the ceramic heater. The temperature gradient at the edge determined the tensile stress intensity. The smallest tensile stress was observed for electrode pattern D, which was expected to be advantageous in resisting thermal shock failures in ceramic heaters.

• Korean Journal of Materials Research
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• v.6 no.2
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• pp.182-187
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• 1996

물과 에탄올의 혼합용액에 HCI을 촉매로하여 금속알콕사이드의 가수분해로부터 코오디어라이트 분말을 제조하였다. 이때 HCI/precursor 몰비로써 촉매의 양을 조절하였다. 건조분말 중의 용매를 제거하기위해 80$0^{\circ}C$에서 3시간 하소처리하였다. 이들 하소된 분말에 대하여 시차열분석과 X-선회절분석을 행한 결과-92$0^{\circ}C$에서 $\mu$-cordierite, -103$0^{\circ}C$에서 $\alpha$-cordierite 결정상의 생성을 확인하였다. 또한, 하소분말을 가압성형한 후 130$0^{\circ}C$에서 4시간 열처리한 결과 HCI양에 따라 기공율 19.45-25.45%, 부피비중 2.06-1.70g/㎤, 유전상수 1.38-3.38 범위의 소결체를 얻었다. HCI양이 증가할수록 기공율은 증가한 반면에 비유전상수와 부피비중은 감소하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1992.11a
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• pp.97-101
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• 1992

Cordierite glass ceramic has become an electronic substrate material for electronic circuits and the use of whiskers for improving strength and toughness is evident. Green sheets of mixtures containing 15% silicon nitride were sintered to greater than 99 % density. The microstructure was analysed using optical microscopy, scanning electron microscopy (SEM), and X-ray diffraction (XRD). The toughness and hardness were improved with increasing the whisker vol. % and sintering temperature. Especially, it is assumed that toughening increasing at the more high sintering temperature relevants to the glass phase increasing, as showned in the roughness of the fracture surfaces. It was directionally dependent of whisker direction during processing.