• 한국세라믹학회지
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• 제34권9호
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• pp.986-992
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• 1997

Cordierite ceramic was prepared by sol-gel method. It was analyzed by Infrared spectroscopy and X-ray diffraction patterns that the ceramic was chemically mixed in molecular level and transformed to $\alpha$-cordierite at 125$0^{\circ}C$. Water vapour treatments for aging and drying process were conducted to get porous cordierite with thermally stable pore structure. It resulted in 220-410 $m^2$/g BET surface area and mesoporous structure with mean pore diameter, 40$\AA$. Compared to naturally dried ceramic, the ceramic showed superior thermal stability of surface area up to $700^{\circ}C$. Surfaces of porous cordierite ceramics were observed by SEM.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1009-1010
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• 2006

In this study, we attempt to synthesize the cordierite from the reaction of fly-ash, alumina, silicon dioxide, and magnesia powders. For the purpose of air purification, the honeycomb filter with porous cordierite was fabricated from the combination of synthetic cordierite and pore forming agent. Fabricated porous cordierite honeycomb was prepared with high porosity (58%), and good compressive strength (69MPa).

• 한국산학기술학회논문지
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• 제14권12호
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• pp.6106-6113
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• 2013

가솔린 엔진 차량용 삼원촉매담체는 주로 코제라이트 세라믹으로 제작되는 다공성 부품으로 엔진의 혼합기가 농후한 경우 삼원촉매의 열적 내구성이 급격히 떨어져 설계 내구 수명을 제대로 만족시키지 못하고 있다. 따라서 본 연구에서는 SiC 세라믹 촉매 담체의 내구성 평가에 사용할 기계적 물성치를 유한요소해석으로 구하기 위하여 등가물성평가방법을 이용하여 SiC 세라믹 하니컴 담체의 기계적 물성치를 유한요소해석용 시험편으로 구하였다. MOR과 탄성계수는 코제라이트 세라믹 하니컴 담체에 비하여 SiC 세라믹 하니컴 담체가 최소 2배와 9.3배 정도 크게 평가되고 있어 SiC 세라믹 하니컴 담체는 코제라이트 세라믹 하니컴 담체에 비하여 높은 구조 강도를 가지고 있다.

• 한국재료학회지
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• 제28권12호
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• pp.719-724
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• 2018

Cordierite composed of an alumina-silica-magnesia compound has a low coefficient of thermal expansion(CTE) and excellent thermal shock resistance. It also has a low dielectric constant and high electrical insulation. However, due to low mechanical strength, it is limited for use in a ceramic heater. In this study, $ZrO_2$ is added to an 80 wt% cordierite-20 wt% mullite composition, and the effect of $ZrO_2$ addition on the mechanical strength and thermal shock resistance is investigated. With an increasing addition of $ZrO_2$, cordierite-mullite formed $ZrO_2$, $ZrSiO_4$ and spinel phases. With sintering conducted at $1400^{\circ}C$ with the addition of 5 wt% $ZrO_2$ to 80 wt% cordierite-20 wt% mullite, the most dense microstructure forms along with an excellent mechanical strength with a 3-point flexural strength of 238MPa. When this composition is quenched in water at ${\Delta}T=400^{\circ}C$, the 3-point flexural strength is maintained. Moreover, when this composition is cooled from $800^{\circ}C$ to air, the 3-point flexural strength is maintained even after 100 cycles. In addition, the CTE is measured as $3.00{\times}10^{-6}{\cdot}K^{-1}$ at $1000^{\circ}C$. Therefore, 80 wt% cordierite-20 wt% mullite with 5 wt% $ZrO_2$ is considered to be appropriate as material for a ceramic heater.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.304-304
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• 2007

고주파 모률에서 사용되는 기판소재는 저유전율과 낮은 loss 특성을 요구함으로 지속적인 연구를 필요로 한다. 지금까지의 ceramic/glass composite 에서 주로 사용된 ceramic filler는 Al2O3로 낮은 유전률을 구현에 한계가 있었다. Cordierite는 낮은 유전율 (${\varepsilon}_r$ < 4)을 나타내는 filler로서 그 가능성이 높지만 아직까지 보고된 결과들이 미흡한 실정이다. 따라서 본 연구에서는 cordierite filler와 SiO2-B2O3-Al2O3-RO (R : Zn, Sr, Ba, Ca)계의 glass를 혼합하여 LTCC용 기판소재로서의 가능성을 확인하고자 저온 동시소성이 가능한 소결온도인 $850^{\circ}C{\sim}1.000^{\circ}C$ 사이에서 소재의 소결실험을 진행하였다. 소결온도에 따른 상변화, 유전특성을 확인한 결과 filler로 사용된 cordierite상만이 관찰 되었으며 소결조건에 따라 5.0~5.5의 낮은 유전율과 1.000~1,500의 Q를 나타내는 것을 확인 하였다.

• 한국세라믹학회지
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• 제12권4호
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• pp.29-36
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• 1975

Korean clinochlore, kaolin, pyrophillite and a technical grade of alumina have been used to investigate the effects of Al2O3 on the formation and properties of cordierite bodies. The body compositions were formulated from the proper proportions of the above raw materials to cover the range of composition from the point corresponding to the stoichiometric formula of cordierite, bythe consecutive increasment of 0.2mol. Al2O3, toward the apex of Al2O3 on the MgO-Al2O3-SiO2 triaxial diagram. Each of bodies was fired with the elevated temperatures from 110$0^{\circ}C$ to 140$0^{\circ}C$ by 5$0^{\circ}C$ interval. Linear shrinkage and water absorption were taken as measures for the firing range of the bodies. The formation of cordierite was estimated from the comparative study of X-ray diffraction and dilatometry of the fired bodies. The formation of a large amount of cordierite was initiated about 120$0^{\circ}C$. The content of Al2O3 exceeded up to 0.8 mol. comparing to the stoichiometric formula of cordierite broadens the firing range of the body.

• 한국세라믹학회지
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• 제27권5호
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• pp.625-630
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• 1990

Cordierite powders were prepared from Si(OC2H5)4, Al(OC3H7i)3 and Mg(OC2H5)2 by the sol-gel method. Two different methods were applied for producing fine and homogeneous powders. One is that Si(OC2H5)4 with a lowr rate of hydrolysis was partially hydrolyzed and then Al(OC3H7i)3 and Mg(OC2H5)2 were mixed and reacted. The other is based on the simultaneous hydrolysis of these metal alkoxides using i-C4H9OH which retards the rate of hydrolysis of Al(OC3H7i)3 and Mg(OC2H5)2. It was confirmed that ifne and homogeneous powders were obtained from both methods. Also these powders were calcined at four different temperatures during two hours. X-ray diffraction patterns show only ${\mu}$-cordierite phase at 1000$^{\circ}C$, ${\mu}$-cordierite and ${\alpha}$-cordierite phases at 1100-1200$^{\circ}C$ and ${\alpha}$-cordierite phase at 1300$^{\circ}C$ respectively.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.328-328
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• 2008

As a low K material for high frequency high integration modules, glass/ceramic composites were investigated. Glass composition were selected from $SiO_2-B_2O_3-Al_2O_3-R_2O$-RO system which having very low dielectric constant and cordierite was used as a ceramic filler. These composites were sintered at temperature range from $850^{\circ}$ to $950^{\circ}$ and XRD, SEM microstructure analysis of sintered bodies were performed for understanding sintering behavior. Any crystallization was not occurred and dense sintered bodies were attained. Dielectric and mechanical properties of these sintered glass/cordierite composites were analysed by network analyzer and UTM. Glass/ceramic composite with 50 wt% cordierite showing a dielectric constant (${\varepsilon}_r$) of 5.4, Q${\times}f_0$ (Q) of 1600 at 1 GHz and maximum bending strength of 163 MPa was attained.

• 한국세라믹학회지
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• 제42권3호
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• pp.155-164
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• 2005

PVA론 이용한 solution-polymerization법에 의해 mullite싸 cordierite 및 mullite-cordierite 복합분말을 합성한 실험 결과를 바탕으펀, 소결조제로서 $TiO_2$를 액상 첨가한 후 mullite-cordierite 합성분말을 제조하고 그때의 소결특성을 조사하였다. 각 조성에 대해 $1300^{\circ}C$에서 하소한 후 planetary mill로 4시간 분쇄를 행하여 합성분말을 준비하였다. 이 합성분말을 사용하여 cordierite의 분해가 일어나지 않는 $1450^{\circ}C$로 소결을 행하였다. 그 결과, mullite $100\%$인 조성에서는 소결시간에 관계없이 원활한 소결이 이루어지지 않았으나, cordierite의 양이 증가함에 따라 상대밀도가 $98\%$ 이상으로 증가하며 소결성이 향상되어졌다 또한 소결시간이 증가함에 따라 mullite와 cordierite의 비율이 50 : 50인 조성의 경우, 16시간 소결하였을 때 복합체치 치밀화로 인해 190MPa의 강도값과 $3.07{\times}10^{-6}/^{\circ}C$의 열팽창계수값을 나타내었다. 하지만 그 이상의 조성에In-1는 cordierite로 인한 액상의 과다생성으로 인해 소결특성은 좋지 않았다. 소결조제로서의 $TiO_2$ 첨가 영향에 대한 조사에서도 $TiO_2$의 함량이 증가함에 따라 mullite의 주상으로의 성장자 cordierite의 액상 증가가 더 빠르게 일어남이 확인되었지만, 이 때문에 $5wt\%$에서는 오히려 특성값이 저하됨이 확인되었다.

• 한국세라믹학회지
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• 제25권4호
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• pp.397-407
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• 1988

Spinel, mullite and cordierite powders have synthesized from Mg(NO3)2.6H2O, Al(NO3).9H2O and SiCl4 solution by spray pyrolysis method. The two-fluid nozzle was used as an atomizer. The powders of sinel and mullite were synthesized above 80$0^{\circ}C$, but the cordierite composition was noncrystalline for all synthersizing temperature. Those noncrystalline powders were crystallized to $\alpha$-cordierite during calcining at 130$0^{\circ}C$ for 2hrs. The synthesized spinel, mullite and cordierite powders seem to be consisted of agglomerated hollow spherical particles. For all powders, the particle size ranged from submicron to about 3${\mu}{\textrm}{m}$ and mean particle size was about 1.4${\mu}{\textrm}{m}$ in diameter. The specific surface area values of spinel, mullite and cordierite powders were maximum for powders prepared at 100$0^{\circ}C$, and those were 45.9, 25.8 and 13.6$m^2$/gr, respectively.