• Journal of Korean Society of Water and Wastewater
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• v.19 no.1
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• pp.31-37
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• 2005

One of the major obstacles confronted in promoting the rainwater harvesting is the concerns of acid rain and heavy metals. Although there are many data concerning the quality of rainwater precipitation for the study of acid rain, the study on the quality of stored rainwater has been limited. In this study, we monitored the quality of stored rainwater at Galmoe middle school, where a rainwater harvesting system is installed and in use for more than two years. We measured water quality parameters such as pH, Electro Conductivity(EC), Dissolved Oxygen(DO), and some metals (aluminium (Al), chromium(Cr), manganese(Mn), zinc(Zn), copper(Cu), arsenic(As), cadmium(Cd), lead(Pb)). The monitoring period was during one year from September 9th 2003 to August 5th 2004. It was observed that the average pH of stored rainwater is neutral. DO is similar to tap water and EC is lower than tap water. Metal Concentrations are within the concentration specified in Drinking Water Quality Standard. Overall, the stored rainwater quality is good enough for sundry use and there's no threat of acid rain and air pollution, if the rainwater harvesting system is well designed and maintained.

• Journal of Korean Society of Water and Wastewater
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• v.32 no.3
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• pp.253-259
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• 2018

Cu(II) can cause health problem for human being and phosphate is a key pollutant induces eutrophication in rivers and ponds. To remove of Cu(II) and phosphate from solution, chitosan as adsorbent was chosen and used as a form of hydrogel bead. Due to the chemical instability of hydrogel chitosan bead (HCB), the crosslinked HCB by glutaraldehyde (GA) was prepared (HCB-G). HCB-G maintained the spherical bead type at 1% HCl without a loss of chitosan. A variety of batch experiment tests were carried out to determine the removal efficiency (%), maximum uptake (Q, mg/g), and reaction rate. In the single presence of Cu(II) or phosphate, the removal efficiency was obtained to 17 and 16%, respectively. However, the removal efficiency of Cu(II) and phosphate was increased to 50~55% at a mixed solution. The maximum uptake (Q) for Cu(II) and phosphate was enhanced from 11.3 to74.4 mg/g and from 3.34 to 36.6 mg/g, respectively. While the reaction rate of Cu(II) and phosphate was almost finished within 24 and 6 h at single solution, it was not changed for Cu(II) but was retarded for phosphate at mixed solution.

• Journal of Environmental Health Sciences
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• v.27 no.3
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• pp.99-106
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• 2001

A laboratory experiment was performed to investigate phosphorus and nitrogen removal from synthetic wastewater by intermittently activated sludge process packed with aluminium plate. Three continuous experimental systems, I. e. an intermittently activated sludge process(Run A), an intermittently activated sludge process with an aluminium plate packed into the reactor(Run B), and a reactor post stage(Run C) were compared. In the batch experiments, the phosphorus removal time in the reactor packed with copper and aluminium plate simultaneously was faster than that of the reactor packed with only an aluminium plates. However, the reactor packed with only an aluminium plate could be used for phosphorus removal. Move phosphorus was removed with an increase of surface area of aluminium plate and electrolysis(NaCl) concentration. The efficiency of COD and nitrogen removal was not affected in Run B. However, the phosphrus removal efficiency decreased because of reaction products and activated sludge which gradually covered gradually the surface of the aluminium plate. The efficiency of phosphorus removal in Run C was 86.3% at the HRT of 3.2 hours. Especially, the efficiency of phosphorus removal in Run C was higher than that in Run B.

• Journal of Korean Society of Water and Wastewater
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• v.13 no.2
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• pp.47-54
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• 1999

SRB(Sulfate Reducing Bacteria) converts sulfate into sulfide using an organic carbon source as the electron donor. The sulfide formed precipitates the various metals present in the AMD (Acid Mine Drainage). This study is the fundamental research on heavy metal removal from AMD using SRB. Two completely mixed anaerobic reactors were operated for cultivation of SRB at the temperature of $30^{\circ}C$ and anaerobic batch reactors were used to evaluate the effects of carbon source, COD/sulfate($SO_4^=$) ratio and alkalinity on sulfate reduction rate and heavy metal removal efficiency. AMD used in this study was characterized by low pH 3.0 and 1000mg/l of sulfate and dissolved high concentration of heavy metals such as iron, cadmium, copper, zinc and lead. It was found that glucose was an organic carbon source better than acetate as the electron donor of SRB for sulfate reduction in AMD. Amount of sulfate reduction maximized at the COD(glucose)/sulfate ratio of 0.5 in the influent and then removal efficiencies of heavy metals were 97.5% of Cu, 100% of Pb, 100% of Cr, 49% of Mn, 98% of Zn, 100% Cd and 92.4% of Fe. Although sulfate reduction results in an increase in the alkalinity of the reactor, alkalinity of 1000mg/1 (as $CaCo_3$) should be should be added continuously to the anaerobic reactor in order to remove heavy metals from AMD.

• Bulletin of the Korean Chemical Society
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• v.28 no.8
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• pp.1375-1382
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• 2007

A column preconcentration method with pulverized Amberlite XAD-4 loaded with bismuthiol I (BI) has been developed for the determination of trace Cd(II) and Cu(II) in various real samples by flame atomic absorption spectrophotometry. Various experimental conditions, such as the size of XAD-4, adsorption flow rate, amount of bismuthiol I, stirring time for adsorbing bismuthiol I on XAD-4, pH of sample solution, amount of XAD-4- BI, desorption solvent, and desorption flow rate, were optimized. Also, the adsorption capacity and the adsorption rate of Cd(II) and Cu(II) on XAD-4-BI were investigated. The interfering effects of various concomitant ions were investigated, Bi(III), Sn(II) and Fe(III) were found to affect the determination. But the interference by these ions was completely eliminated by adjusting the amount of XAD-4-BI resin to 0.70 g, although the adsorption flow rate was slower. For Cd(II) our proposed technique obtained a dynamic range of 0.5-40 ng mL-1, a correlation coefficient (R2) of 0.9913, and a detection limit of 0.3 ng mL-1. For Cu(II), the corresponding values were 2.0-120 ng mL-1, 0.9921 and 1.02 ng mL-1. To validate this proposed technique, the aqueous samples (stream water, reservoir water, tap water and wastewater), the diluted brass sample and the plastic sample, as real samples, were used. Recovery yields of 91-103% were obtained. These measured data were not different from ICP-MS data at 95% confidence level. Our proposed method was also validated using rice flour CRM (normal, fortified) samples. From the results of our experiment, we found that the technique we present here can be applied to the determination of Cd(II) and Cu(II) in various real samples.

• Membrane and Water Treatment
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• v.9 no.2
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• pp.95-104
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• 2018

Copper pollution around the world has caused serious public health problems recently. The heavy metal adsorption on traditional membranes from wastewater is limited by material properties. Different adsorptive materials are embedded in the membrane matrix and act as the adsorbent for the heavy metal. The carbonized leaf powder has been proven as an effective adsorbent material in removing aqueous Cu(II) because of its relative high specific surface area and inherent beneficial groups such as amine, carboxyl and phosphate after carbonization process. Factors affecting the adsorption of Cu(II) include: adsorbent dosage, initial Cu(II) concentration, solution pH, temperature and duration. The kinetics data fit well with the pseudo-first order kinetics and the pseudo-second order kinetics model. The thermodynamic behavior reveals the endothermic and spontaneous nature of the adsorption. The adsorption isotherm curve fits Sips model well, and the adsorption capacity was determined at 61.77 mg/g. Based on D-R model, the adsorption was predominated by the form of physical adsorption under lower temperatures, while the increased temperature motivated the form of chemical adsorption such as ion-exchange reaction. According to the analysis towards the mechanism, the chemical adsorption process occurs mainly among amine, carbonate, phosphate and copper ions or other surface adsorption. This hypothesis is confirmed by FT-IR test and XRD spectra as well as the predicted parameters calculated based on D-R model.

• International Journal of Industrial Entomology and Biomaterials
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• v.18 no.2
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• pp.97-103
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• 2009

Sericulturists in the vicinity of Bangalore city irrigate their mulberry gardens with Vrishabhavathy stream water, which is polluted with domestic and industrial wastes from the city. To investigate the effect of pollutants on silkworm crops, a detailed field survey was conducted to study the cocoon yield pattern of the crops raised on mulberry irrigated with wastewater as against irrigation by bore/open wells. The villages along the stream were grouped into five test batches at about a distance of $5{\sim}8$ km from each other. The seasonal yield data with relevant information were collected through questionnaires from 117 rearers using stream water and 35 rearers using bore/open wells, the latter serving as control group. The average yield for 100 layings was 46 to 57 kg in the control group whereas in test groups, it ranged between 34 to 51 kg in the first test group and 22 to 38 kg in the rest. The difference in yield was $9{\sim}19$ kg depending on the season between control and test batches. In summer, this difference was higher, with high co-efficient of variation in test groups ($33{\sim}52$%). Further, water, soil and leaf samples were collected from selected rearers and were analyzed for zinc, copper, iron, lead and nickel. Results indicated significantly higher contents of these metals in samples from gardens using wastewater when compared control samples. Significantly (p<0.05 & p<0.01)) higher levels of zinc ($24{\sim}122$ ppm) and iron ($208{\sim}683$ ppm) were noticed in mulberry leaves during summer followed by winter and rainy season. The significance of high content of heavy metals in mulberry leaves and cocoon yield pattern of this area in relation to the quality of irrigation water is discussed.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.2
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• pp.235-242
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• 2007

Road runoff water includes various heavy metals (zinc, Zn; lead, Pb; copper, Cu; chrome, Cr; cadmium, Cd; etc.) and pathogens (E-coli and coliform). Since these pollutants are significantly harmful to human beings and have negative impact on water streams, numerous studies have been conducted to determine the characterization of these non-point pollutants from road runoff water. However, since these non-point pollutant concentrations vary depending on road traffic, road construction, and road maintenance, measurement of pollutant loadings in different site is necessary to estimate the effect of road runoff water on drinking water source. The objective of this study was to examine the quality of road runoff water from a city bridge in Seoul, Korea. This study was conducted for two years to assess annual discharge pollution loads. In this study, five key heavy metals (Zn, Pb, Cu, Cr, and Cd) and two pathogens (E-coli and coliform) were measured at 18 different events. The pollutant load mass transported was always higher than the corresponding runoff volume for Zn, Cu, and Cd, while Pb and Cr showed similar values between the load mass transported and the corresponding runoff volume. The event mean concentrations were Zn (0.908 mg/L), Pb (0.092 mg/L), Cu (0.141 mg/L), Cr (0.023 mg/L), and Cd (0.006 mg/L). Like Zn, Cu, and Cd, E-coli and coliform values (relatively high in Summer and Fall) are higher at the beginning of each event and decrease afterwards.

• Journal of Environmental Science International
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• v.21 no.5
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• pp.597-603
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• 2012

Non-thermal plasma processing using a dielectric barrier discharge (DBD) has been investigated as an alternative method for the degradation of non-biodegradable organic compounds in wastewater. The active species such as OH radical, produced by the electrical discharge may play an important role in degrading organic compound in water. The degradation of N, N-Dimethyl-4-nitrosoaniline (RNO) was investigated as an indicator of the generation of OH radical. The DBD plasma reactor of this study consisted of a plasma reactor, recycling pump, power supply and reservoir. The effect of diameter of external reactor (15 ~ 40 mm), width of ground electrode (2.5 ~ 30 cm), shape (pipe, spring) and material (copper, stainless steel and titanium) of ground electrode, water circulation rate (3.1 ~ 54.8 cm/s), air flow rate (0.5 ~ 3.0 L/min) and ratio of packing material (0 ~ 100 %) were evaluated. The experimental results showed that shape and materials of ground were not influenced the RNO degradation. Optimum diameter of external reactor, water circulation rate and air flow rate for RNO degradation were 30 mm, 25.4 cm/s and 4 L/min, respectively. Ground electrode length to get the maximum RNO degradation was 30 cm, which was same as reactor length. Filling up of glass beads decreased the RNO degradation. Among the experimented parameters, air flow rate was most important parameters which are influenced the decomposition of RNO.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.6
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• pp.794-800
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• 2004

The purpose of this study is to propose a method of controlling freshwater algae which grows abundantly and forms water bloom in the eutrophic water body with $H_2O_2$. Both laboratory and field methodologies were used. For the laboratory test $H_2O_2$ was injected into the different growth phases of incubated Microcystis aeruginosa and the resulting algae growth control rate was examined. For the field test, $H_2O_2$ was dispersed into a lake. Lake water quality was evaluated using a pre-test and post-test analysis of chlorophyll-a, luminance, transmittance, etc., which allowed a comparative evaluation of water quality change. From the experimental results, the growth of algae can be controlled with the small amount of 1mg/L of $H_2O_2$ at the lag phase of growth. The field test results show that the green colour of lake water was removed completely by the reduction of chlorophyll-a and improved transmittance, luminance, TKN, TP, TOC and SS. These indicators of water quality were improved significantly after $H_2O_2$ injection. Toxicity test results using the lake fish show no evidence of detrimental effect of $H_2O_2$ up to 15mg/L. The results of $EC_{50}$ with P. phosphoreum show that the toxicity of $H_2O_2$ was negligible compared to copper which was commonly used for algae control.