• Bulletin of the Korean Chemical Society
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• 제35권11호
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• pp.3313-3318
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• 2014

The reaction mechanism of Lead ions catalyzing complexation reactions between TIPP and metal ions was investigated by researching the kinetics of the formation of metalloporphyrins by UV/Vis-spectra, and verified by exploring the formation of metalloporphyrins catalyzed by acetic acid. Kinetics studies suggested that the fluctuations of reaction rate indicated the formation of metalloporphyrin was step-wise, including the pre-equilibrium step (the coordination of the pyrrolenine nitrogens to $Mn^+$) and the rate-controlling step (the deprotonation of the pyrrole proton). In the pre-equalization step, a sitting-atop (SAT) structure formed first with the complexation between larger radius of $Pb^{2+}$ and TIPP, changed the activation, then $Pb^{2+}$ left with the smaller radius of metal ions attacking from the back of the porphyrin ring center. In the rate-controlling step, two pyrrole protons dissociated to restore a stable structure. This was verified by adding acetic acid at different reaction times.

• 한국세라믹학회지
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• 제31권10호
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• pp.1107-1114
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• 1994

Although various theories have been presented on the mechanism of setting retardation of plaster in addition to organic admixtures. The purpose of this paper is that Hydration studies of plaster of paris in the presence of carboxylic acids under alkalinity are examined in the coordination chemistry. Setting of plaster of paris is retarded by the addition of carboxylic acids except oxalic acid. And setting of plaster of paris contained 5 wt% of Ca(OH)2 is also retarded by the addition of above-mentioned carboxylic acids. The degree of retarding effect under alkalinity is found to be a function of the number of the functional group and the length of carbon chain of carboxyl acids. These reasons are attributed to the soluble complex formation, that is calcium complex formation between calcium ion and carboxylic acids. The author's proposal was confirmed by the results of electrical conductivity measurement. The formation of calcium complex was surpported by IR spectra.

• Journal of Communications and Networks
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• 제16권3호
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• pp.311-321
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• 2014

This paper focuses on contention-based medium access control (MAC) protocols used in wireless local area networks. We propose a novel MAC protocol called adaptive backoff tuning MAC (ABTMAC) based on IEEE 802.11 distributed coordination function (DCF). In our proposed MAC protocol, we utilize a fixed transmission attempt rate and each node dynamically adjusts its backoff window size considering the current network status. We determined the appropriate transmission attempt rate for both cases where the request-to-send/clear-to-send mechanism was and was not employed. Robustness against performance degradation caused by the difference between desired and actual values of the attempt rate parameter is considered when setting it. The performance of the protocol is evaluated analytically and through simulations. These results indicate that a wireless network utilizing ABTMAC performs better than one using IEEE 802.11 DCF.

• 한국경영과학회:학술대회논문집
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• 대한산업공학회/한국경영과학회 2006년도 춘계공동학술대회 논문집
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• pp.1656-1660
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• 2006

Distributed coordination function(DCF) is the primary random access mechanism of IEEE 802.11, which is the basic protocol of wireless LAN based on the CSMA/CA protocol. It enables fast installation with minimal management and maintenance costs and is a very robust protocol for the best effort service in wireless medium. The current DCF, however, is known to be unsuitable for real-time applications such as voice message transmission. In this paper, we focus on the performance issues of IEEE 802.11 which accommodate the prioritized messages. Existing results use the initial window size and backoff window-increasing factor as tools to handle the priority of the messages. Instead, we introduce a novel scheme which chooses the backoff timer with arbitrary probabilities. By this, one can greatly reduce the backoff delay of the lower priority messages without degrading the performance of higher priority.

• 약학회지
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• 제21권4호
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• pp.184-192
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• 1977

In the presence of dithionite, two kinds of molybdothiol complexes, particularly isolated Mo-cysteine complexes, used as models for xanthine oxidase or aldehyde oxidase exhibited catalytic activity on the reduction of nitrofurazone to its amino derivative. Of the two Mo-cysteine complexes, the activity of oxo-bridged one was apparently greater than that of sulfido-bridged one. The promoting effect was hardly shown by added cofactors or their replacements of the enzymes. The catalyzed reduction is considered to take place by consecutive direct two-electron transfer mechanism from catalytically active reduced form of the molybdothiol complexes to nitrofurazone and the probable intermediates.

• 대한화학회지
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• 제12권3호
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• pp.128-137
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• 1968

In the oligomerization of p-aminophenol by the catalytic action of Fe-EDTA complex in the aqueous medium, the mixed complex intermediate, Fe-EDTA-M type, is considered to be formed, from which active radicals of the monomer are produced. In this system, polymerization is presumed to proceed as follows: Free radical formation ${\to}$ Coupling ${\to}$ Activation ${\to}$ Coupling, and so on. In this study, the form of the monomer and coordination state in the mixed complex, the catalytic action of Fe-EDTA the complex, the reaction mechanism, and the structure of the oligomers are discussed.

• Journal of information and communication convergence engineering
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• 제7권3호
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• pp.399-403
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• 2009

In IEEE 802.15.1 (Bluetooth) Ad-hoc networks, the frequency is resolved by the specific part of the digits of the Device clock and the Bluetooth address of the Master device in a given piconet. The piconet performs a fast frequency hopping scheme over 79 carriers of 1-MHz bandwidth. Since there is no coordination between different piconets, packet collisions may occur if two piconets are located near one another. In this paper, we proposed a software/hardware co-design of an adaptive frequency decision mechanism so that more than two different kinds of wireless devices can stay connected without frequency collision. Suggested method was implemented with C program and HDL (Hardware Description Language) and automatically synthesized and laid out. The adaptive frequency hopping circuit was implemented in a prototype and showed its operation at 24MHz correctly.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제6권6호
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• pp.1565-1585
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• 2012

The characteristics of ad hoc networks, such as the absence of infrastructure, a dynamic topology, a shared wireless medium and a resource-constrained environment pose various security challenges. Most previous studies focused on the detection of misbehavior after it had occurred. However, in this paper we propose a new way of thinking to evade the occurrence of misbehavior. In our scheme, we firstly present a clustering algorithm that employs a powerful analytic hierarchy process methodology to elect a clusterhead for each cluster. The clusterhead in each cluster is then allowed to assign the backoff values to its members, i.e., originators, rather than permitting the originators to choose the backoff values by themselves. Through this media access control layer misbehavior detection mechanism, the misuse of the backoff in the media access control layer in the 802.11 distributed coordination function can be detected.

• 한국표면공학회지
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• 제38권2호
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• pp.83-87
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• 2005

We enhanced the color of blue sapphires and rubies successfully by using a oxygen-propane torch flame annealing, which had not been employed so far. We confirmed that about 1 mm-thick de-coloring of the corundum samples were available with 60 minutes flame annealing through eye evaluation, color coordination characterization, and methylene iodide immersion observation. We also suggest that the color centers such as $[Fe_{Al}^{\cdot}]$ may transform into transparent $[Fe_{Al}^{x}],\;[Cr_{A1}^{x}]$ sites with $[V_o^']$ generation at the elevated temperature in oxygen-rich atmosphere by diffusion mechanism. Our results implied that the longer diffusion time and the higher oxygen partial pressure might lead to the better de-coloring enhancement in corundum gem stones.

• 산업경영시스템학회지
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• 제35권3호
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• pp.163-172
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• 2012

Regarding project management, many organizations have developed and distributed general project management knowledge systems, and application fields use the knowledge systems to apply the process suitable for characteristics of a project. This study suggests project management process models to apply to system integration projects. This system integration project management process model is composed of six top processes of initiation, preparation for contract, planning, implementation management, coordination and control, and termination and transfer. The five processes are re-divided into 25 bottom processes. These processes are expressed as input, control, output, and mechanism by using the IDEF0 model. For this model development, it has chosen the items which constituted a process through a questionnaire of experts.