• Journal of Korean Society for Atmospheric Environment
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• 제32권5호
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• pp.526-535
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• 2016

Recently, fine dust in atmosphere have been considerably issued as a harmful element for human. Nitrogen oxide ($NO_x$) exhausted from diesel engines and power plants has been disclosed as a main source of secondary production of fine dust. In order to prevent exhausting these nitrogenous compounds into atmosphere, a treatment system with selective catalytic reduction (SCR) catalyst with ammonia as a reductant has been used in various industries. Urea solution has been widely studied to supply ammonia into a SCR catalytic reactor, safely. However, the conversion of urea solution to ammonia has several challenges, especially on a slow conversion velocity. In the present study, a fast urea conversion system including a plasma burner was suggested and designed to evaluate the performances of urea conversion and initial operation time. A designed lab-scale facility has a plasma burner, urea nozzle, mixer, and SCR catalyst which is for hydrolysis of isocyane. Flow rate of methane that is a fuel of the plasma burner was varied to control temperatures in the urea conversion facility. From experimental results, it is found that urea can be converted into ammonia using high temperature condition of above $400^{\circ}C$. In the designed test facility, it is found that ammonia can be produced within 1 min from urea injection and the result shows prospect commercialization of proposed technology in the SCR facilities.

• Korean Chemical Engineering Research
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• 제48권3호
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• pp.316-321
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• 2010

The $SO_2$ catalytic reduction was carried out under the condition of high pressure in this study. Sn-Zr based oxide and CO were used as the catalyst and reducing agent for the reduction of $SO_2$ to element sulfur, respectively. In order to compare the reactivity with the pressure on the catalytic process, the reactivity tests were performed under the conditions of atmospheric pressure and 20 atm. $SO_2$ conversion, the element sulfur yield and COS selectivity were also compared with changing the reaction temperature, $CO/SO_2$ mole ratio and the space velocity(GHSV). $SO_2$ conversion increased with increasing temperature and $CO/SO_2$ mole ratio under the condition of atmospheric pressure and element sulfur yield decreased due to the production of COS by the series reaction of CO and the produced sulfur. However, high $SO_2$ conversion and high element sulfur were obtained under the condition of 20 atm. It was concluded that COS decreased due to the condensation of the produced element sulfur under the condition of high pressure. Therefore, the high sulfur yield for $SO_2$ catalytic reduction could be profitably obtained under the condition of high pressure.

• Proceedings of the IEEK Conference
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• 대한전자공학회 2005년도 추계종합학술대회
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• pp.261-264
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• 2005

This paper presents the design of a down-conversion mixer with built-in active balun integrated in a $0.25\;{\mu}m$ pHEMT process. The active balun consists of series-connected common-gate FET and common-source FET. The designed balun achieved broadband characteristics by optimizing gate-width and bias condition for the reduction in parasitic effect. From DC to more than 6GHz, the active balun shows the phase error of less than 3 degree and the gain error of less than 0.4 dB. A single-balanced down-conversion mixer with built-in broadband active balun has been designed with optimum width, load resistor and bias for conversion gain and without any matching component for broadband operating. The designed mixer whose size of including on-chip bias circuit is $1\;mm{\times}1\;mm$ shows the conversion gain of better than 7 dB from 2 GHz to 6 GHz and $P_{1dB}$ of -10 dBm at 5.8 GHz

• Journal of environmental and Sanitary engineering
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• 제16권4호
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• pp.69-76
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• 2001

The catalytic oxidation of volatile organic compounds (VOCs), which were benzene and toluene, was studied in the supercritical carbon dioxide($SC-CO_2$) media. In $SC-CO_2$ media, the deep oxidation conversion of VOCs was increased with the temperature and pressure. The deep oxidation conversion in SC -$CO_2$ media is better than that in air media at same pressure condition. This can be explained by the solubility of VOCs in $SC-CO_2$. The many intermediates produced by the partial oxidation of VOCs were detected from off-line samples. The intermediates were Identified as benzene, toluene, benzaldehyde, phenol, naphthalene, 1,1`-biphenyl, benzoic acid, 3-methylphenol, 1,1'-(1,2-ethanediyl)bis- benzene, 1,1'-(1,2-ethene- diyl)bis-benzene, anthracene, and so on. The amount of intermediates was decreased as the molar radio of oxygen to carbon dioxide was decreased. When the molar ratio of oxygen to carbon dioxide was 1 : 16, the deep conversion was kept constant. Thus, the catalytic oxidation process in $SC-CO_2$ media can be combined on-line with supercritical fluid extraction of environmental matrices and supercritical regeneration of used adsorbent. Thus, the nontoxic $SC-CO_2$ media process was suggested as the new VOCs control technology.

• Transactions of the Korean Society of Automotive Engineers
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• 제16권2호
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• pp.58-65
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• 2008

The finite element programs have been developed for structure, collision, flow, dynamics, heat transfer, acoustics, electromagnetism, MEMS (Micro Electro Mechanical Systems), and etc. These programs can be classified as either "package" program or "single purpose" program. Single purpose programs usually have convenient and powerful functions, but these programs have limited expandability to different fields of analysis. Therefore, the method to converter the analysis results of single purpose program to other programs is needed. In the research, multi-body data conversion methods of 1) finite element model and 2) solid model were created to convert fluid analysis result of CFD-ACE+ to ANSYS data structure. Automatic boundary condition algorithms were developed for blade, and finite element model was compared with solid model. It is expected that, by sealess data transfer, the Multi-body Data Conversion Program could reduce the development period of torque converters.

• Journal of the Korean Solar Energy Society
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• 제25권4호
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• pp.85-92
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• 2005

One of the most effective methods for utilizing solar energy is to combine thermal solar and optical energy simultaneously using a hybrid panel. Many systems using various kinds of photovoltaic panels have already been constructed. But utilizing solar energy by means of a hybrid panel with concentrator has not been to be attempted yet. Normally if sunlight is directed on the solar cell, and there is no increase in temperature, the absorption energy of each cell will increase per unit area. In a silicon solar cell. however, cell conversion efficiency decreases according to the increasing temperature. Therefore, to maintain cell conversion efficiency under normal condition, it is necessary to keep the cell at operating temperature. we design and make new hybrid panel with cooling system to prevent increasing of temperature on cell, collect effectively thermal energy. We compared performance of new hybrid panel with PV module and thermal panel. We also evaluated conversion efficiency, electric power and thermal capacity and confirmed cooling effect from thermal absorption efficiency.

• Journal of the Korean Solar Energy Society
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• 제27권1호
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• pp.75-81
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• 2007

Steam reforming of methane using Xe-arc solar simulator was studied for the application of concentrated solar energy into chemical reaction. The reactor, a volumetric absorber, consisted of a porous ceramic foam disk coated with commercial reforming catalyst. Operating temperature was in the range of $450\;-\;550^{\circ}C$ and the excess steam ratio to methane was from 3.0 to 5.0. At the steady-state condition, the conversion of methane Increased with temperature in the range of 15 % - 30 % and the experimentally determined conversion was found to be close to theoretical equilibrium conversion. It was also found that the CO selectivity slightly decreased with excess steam ratio. Finally, the conversion of methane decreased significantly with space velocity of reactants.

• Journal of the Korean Society of Mechanical Technology
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• 제13권2호
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• pp.123-128
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• 2011

It has been stand high in estimation to converse from Carbon dioxide to Dimethyl Ether in new alternative fuel energy division in 21C, especially Using of DME in point of view of transportation fuel has been discussed of a new clean energy which is very lower of exhaust gas than gasoline and diesel energy. In this paper it is used ZSM-5 and I developed new catalyst by addition of cerium to control acidity. The new catalyst was proved high conversion rate, when it was conversed from methanol to DME, there wasn't any additional material except DME and water, and I overlooked reaction temperature, reaction time, amount of catalyst, amount of added cerium, effect of water content in methanol, reaction temperature by making change of reaction time. I have conclude that conversion rate to DME was increased as increased of catalyst amounts. The best catalyst condition of without additional product was treated poisoning from ZSM-5 to 5% cerium and new catalyst was not effected in purity of fuel methanol.

• Journal of ILASS-Korea
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• 제23권4호
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• pp.244-253
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• 2018

Recently, The ministry of Environment in korea have introduced Euro-6d temp which was strengthened at the same time as Europe. Small Light-duty passenger vehicles need the SCR system of after-treatment to meet enhanced emission regulations. However, SCR system has a low conversion efficiency in a low temperature less than 200 degree. In this study, the NOx conversion efficiency of SCR system was analyzed by installing a NOx sensors and a temperature sensors in a diesel vehicle. Also, in order to analyze the effect of the cold-start, the test was performed on the same RDE route and compared with the test of hot-start. As a result, SCR system has characteristics of low conversion efficiency under cold-start conditions.

• Transactions of the Korean hydrogen and new energy society
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• 제22권4호
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• pp.465-473
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• 2011

To find the optimum mixing ratio of WGS catalyst with $CO_2$ absorbent for SEWGS process, water gas shift reaction tests were carried out in a fluidized bed reactor using commercial WGS catalyst and sand (as a substitute for $CO_2$ absorbent). WGS catalyst content, gas velocity, and steam/CO ratio were considered as experimental variables. CO conversion increased as the catalyst content increased during water gas shift reaction. Variations of the CO conversion with the catalyst content were small at low gas velocity. However, those variations increased at higher gas velocity. Within experimental range of this study, the optimum operating condition(steam/CO ratio=3, gas velocity = 0.03 m/s, catalyst content=10 wt.%) to get high CO conversion and $CO_2$ capture efficiency was confirmed. Moreover, long time water gas shift reaction tests up to 20 hours were carried out for two cases (catalyst content = 10 and 20 wt.%) and we could conclude that the WGS reactivity at those conditions was maintained up to 20 hours.