• Bulletin of the Korean Chemical Society
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• 제34권3호
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• pp.810-814
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• 2013

The thermodynamic parameters for the intercalative interaction of structurally related well known intercalators, 9-aminoacridine (9AA) and proflavine (PF) were determined by means of fluorescence quenching study. The fluorescence intensity of 9AA decreased upon intercalation to DNA, poly[$d(A-T)_2$] and poly[$d(G-C)_2$]. A van't Hoff plot was constructed from the temperature-dependence of slope of the ratio of the fluorophore in the absence and presence of a quencher molecule with respect to the quencher concentration, which is known as a Stern-Volmer plot. Consequently, the thermodynamic parameters, enthalpy and entropy change, for complex formation was calculated from the slope and y-intercept of the van't Hoff plot. The detailed thermodynamic profile has been elucidated the exothermic nature of complex formation. The complex formation of 9AA with DNA, poly[$d(A-T)_2$] and poly[$d(G-C)_2$] was energetically favorable with a similar negative Gibb's free energy. On the other hand, the entropy change appeared to be unfavorable for 9AA-poly[$d(G-C)_2$] complex formation, which was in contrast to that observed with native DNA and poly[$d(A-T)_2$] cases. The equilibrium constant for the intercalation of PF to poly[$d(G-C)_2$] was larger than that to DNA, and was the largest among sets tested despite the most unfavorable entropy change, which was compensated for by the largest favorable enthalpy. The favorable hydrogen bond contribution to the formation of the complexes was revealed from the analyzed thermodynamic data.

• 한국작물학회:학술대회논문집
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• 한국작물학회 2017년도 9th Asian Crop Science Association conference
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• pp.357-357
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• 2017

The combined application of oil cake and rice bran into the soil surface was found useful for weed control in our previous pot study. The present study was undertaken to evaluate the performance of white clover (Trifolium repens L.) while incorporated in the paddy field and effects of combined fertilizer on weed control and rice yield. A plot was divided into two parts i.e. white clover incorporated and not incorporated. The nitrogen content of the incorporated white clover was $12.5gm^{-2}$. Chemical fertilizer and combined fertilizer plots were compared with non-fertilizer conditions. The mixed ratio of combined fertilizer was oil cake 1.35 and rice bran 1.0. Combined fertilizer was applied to the soil surface, and chemical fertilizer was mixed in the soil. Nitrogen application rate was $8gm^{-2}$ for any fertilizer. The weed numbers were significantly reduced in the white clover plot irrespective of application condition both at heading and harvest time. Also, weed control ability was improved by the use of combined fertilizer. In the not incorporated plot, the number of weeds was suppressed about 90% by applying combined fertilizer. The rice yield was markedly increased by the incorporation with white clover under all fertilization conditions. Contribution rates of increased rice yield by white clover and combined fertilizer were about 55% and about 25%, respectively. The rice yield was increased by the incorporation with white clover, and the number of weeds remarkably decreased as well. Also, these effects were improved due to combined application of oil cake and rice bran.

• 한국자원식물학회지
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• 제25권1호
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• pp.63-71
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• 2012

To assess parameters of mating system in seed orchard, such as outcrossing rates, number of potential pollen contributors, and degree of pollen contamination, seeds, produced in '77 plot of the Japanese red pine (Pinus densiflora S et Z) seed orchard at Anmyeon island, were collected in 2007 and analysed by nSSR and cpSSR markers. Estimates of outcrossing rates ranged from 91.2 to 100% (mean 97.7%) on the basis of the analysis of cpSSR haplotypes and from 81.6 to 100% (mean 95.3%) on the basis of the analysis of nSSR genotypes. By cross checking of both DNA markers, seeds, presumed to be products of self pollination on the basis of single marker, were confirmed as outcrossed seeds, which resulted in cumulative outcrossing rates of 98.9%. On the basis of pooled cpSSR haplotype of each seed, the number of pollen contributors and paternal contribution rates were estimated as 14.8 and 0.512, respectively. In conclusion, considering pretty high level of outcrossing rates observed in a seed orchard, good genetic potential of the seeds, produced in '77 plot of the seed orchard of Japanese red pines at Anmyeon island, may be guaranteed. Investigated results from the analysis of mating system of Japanese red pines in a '77 plot of the seed orchard may also be expected to provide useful information for the management and establishment of the seed orchard of the progressive generation.

• 한국환경복원기술학회지
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• 제10권6호
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• pp.99-109
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• 2007

The main objectives of this comparative study were 1) to compare the floristic similarity of species composition between the extant vegetation and seedlings from soil seed bank and 2) to quantify the potential contribution of soil seed bank to revegetation of forest in a constructed area, which is called "ecological impact mitigation" in conjunction with the power plant extension. Forest topsoil of seven plots was collected from the surface soil after measurements were taken on the ground vegetation in each plot. A greenhouse experiment was conducted and monitored to analyze the germination potential of soil seed bank. The forest topsoil was spread on plastic trays ($0.7m^2{\times}7$) filled with a 5cm layer of sterilized potting mix. The results of monitoring for 2 years in a greenhouse were as follows : 1) seedlings of soil seed bank per 4.9$m^2$ were 1,269 with 36 species (1st year) and 2,615 with 25 species (2nd year). 2) 38${\pm}$8% of the flora species were germinated from soil seed bank. It can be concluded that the use of soil seed bank would be effective to promote establishment of diverse species and vegetation. However, it behooves to continue monitoring on succession of vegetation and pursue revegetation with other methods for ecological restoration. Finally, adequate topsoil deposit and gathering methods should be studied properly.

• Geomechanics and Engineering
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• 제33권5호
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• pp.427-437
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• 2023

The objective of this work is to study the wave propagation of an FGM plate via a new integral inverse shear model with temperature-dependent material properties. In this contribution, a new model based on a high-order theory field of displacement is included by introducing indeterminate integral variables and inverse co-tangential functions for the presentation of shear stress. The temperature-dependent properties of the FGM plate are assumed mixture of metal and ceramic, and its properties change by the power functions of the thickness of the plate. By applying Hamilton's principle, general formulas of wave propagation were obtained to plot the phase velocity curves and wave modes of the FGM plate with simply supported edges. The effects of the temperature and volume fraction by distributions on wave propagation of the FGM plate are investigated in detail. The results of the dispersion and the phase velocity curves of the propagation wave in the functionally graded plate are compared with previous research.

• 응용통계연구
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• 제34권4호
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• pp.589-597
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• 2021

단순회귀와 다중회귀에서 회귀계수의 의미는 차이가 있고 회귀계수의 추정값은 같지 않을 뿐 아니라 그 부호가 서로 다른 경우도 발생한다. 회귀모형에서 설명변수의 상대적 기여도의 파악은 회귀분석의 수행의 중요한 부분이다. 표준화 회귀모형에서 표준화 회귀계수는 해당 설명변수를 제외한 나머지 설명변수의 값이 고정되어있는 상황에서 설명변수가 표준편차만큼 증가하였을 때 반응변수가 표준편차를 기준으로 얼마나 변화했는가로 해석할 수 있지만 표준화 회귀계수의 크기가 각 설명변수의 상대적 중요도를 나타내는 척도라고 할 수 없음은 잘 알려져 있다. 본 논문에서는 다중회귀에서 회귀계수의 추정량을 상관계수와 결정계수의 함수로 나타내고 이를 추가적인 설명력과 추가적인 결정계수의 관점에서 생각해 본다. 또한 다양한 산점도에서의 상관계수와 회귀계수 추정값의 관계를 알아보고 설명변수가 두 개인 경우에 구체적으로 적용해 본다.

• Asian-Australasian Journal of Animal Sciences
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• 제25권2호
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• pp.207-212
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• 2012

The effects of sheep urine and dung patches on methane ($CH_4$) and carbon dioxide ($CO_2$) fluxes were investigated during the summer-autumn in 2010, to evaluate their contribution to climate change in a desert grassland in Inner Mongolia, China. Results indicate that the cumulative $CH_4$ emissions for dung patches, urine patches and control plots were -0.076, -0.084, and -0.114 g/$m^2$ and these were net $CH_4$ sinks during the measured period. The level of $CH_4$ intake from urine and dung plots decreased 25.7%, and 33.3%, respectively, compared with a control plot. $CO_2$ fluxes differed (p<0.01) in urine plots, with an average of 569.20 mg/$m^2$/h compared with control plots (357.62 mg/$m^2$/h) across all sampling days. Dung patches have cumulative $CO_2$ emissions that were 15.9% higher compared with the control during the 55-d period. Overall, sheep excrement weakened $CH_4$ intake and increased $CO_2$ emissions.

• Bulletin of the Korean Chemical Society
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• 제35권7호
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• pp.2081-2085
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• 2014

Second-order rate constants ($k_N$) have been measured spectrophotometrically for the reactions of phenyl 2- pyridyl carbonate (6) with a series of cyclic secondary amines in MeCN at $25.0{\pm}0.1^{\circ}C$. The Br${\o}$nsted-type plot for the reaction of 6 is linear with ${\beta}_{nuc}$ = 0.54, which is typical for reactions reported previously to proceed through a concerted mechanism. Substrate 6 is over $10^3$ times more reactive than 2-pyridyl benzoate (5), although the reactions of 6 and 5 proceed through the same mechanism. A combination of steric hindrance, inductive effect and resonance contribution is responsible for the kinetic results. The reactions of 6 and 5 proceed through a cyclic transition state (TS) in which H-bonding interactions increase the nucleofugality of the leaving group (i.e., 2-pyridiniumoxide). The enhanced nucleofugality forces the reactions of 6 and 5 to proceed through a concerted mechanism. In contrast, the corresponding reaction of 4-nitrophenyl 2-pyridyl carbonate (7) proceeds through a stepwise mechanism with quantitative liberation of 4-nitrophenoxide ion as the leaving group, indicating that replacement of the 4-nitrophenoxy group in 7 by the PhO group in 6 changes the reaction mechanism (i.e., from a stepwise mechanism to a concerted pathway) as well as the leaving group (i.e., from 4-nitrophenoxide to 2-pyridiniumoxide). The strong electron-withdrawing ability of the 4-nitrophenoxy group in 7 inhibits formation of a H-bonded cyclic TS. The presence or absence of a H-bonded cyclic TS governs the reaction mechanism (i.e., a concerted or stepwise mechanism) as well as the leaving group (i.e., 2-pyridiniumoxide or 4-nitrophenoxide).

• Applied Biological Chemistry
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• 제16권2호
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• pp.99-111
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• 1973

전국적(全國的)으로 실시한 삼요소(三要素) 시험중(試驗中) 1967년(年) 51개소(個所) 68년(年)에 32개소(個所)에서 N 8, 10, 12, 14kg/10a 수준(水準)과 $P_2O_5$ 및 $K_2O$ 각(各) 6과 8kg 시비수준(施肥水準)에 대(對)한 삼요소(三要素) 이용율(利用率)을 조사(調査)하였다. 삼요소(三要素) 이용율(利用率)과 수량(收量) 및 건물생산량(乾物生産量), 삼요소(三要素) 및 규산흡수량(珪酸吸收量)과의 아래와 같은 관계에서 무기양분(無機養分)의 생산(生産)에 기여하는 양상(樣相)이 시용(施用)한 P가 1차적(次的)으로 Si흡수(吸收)를 이차적(二次的)으로 Si가 N흡수(吸收)를 조장(助長)하여 기여하는 P형(型)과 시용(施用)한 K가 P흡수(吸收)를, 이차적(二次的)으로 P가 N흡수(吸收)를 조장(助長)하여 기여하는 K형(型)으로 연도별(年度別) 주도형(主導型)을 구분(區分)할 수 있었다. 1. 질소(窒素)는 전포장수(全圃場數)의 4%, 인산(燐酸)은 48%, 가리(加里)는 38%가 0 또는 부(負)의 이용율(利用率)을 보였으며 이용율(利用率)의 발현빈도(發現頻度) 백분분포(百分分布)가 N는 30 내지 40에서 최고빈도(最高頻度)를 보이는 정규분포(正規分布)에 가깝게, P와 K는 0 이하(以下)에서 최고빈도(最高頻度)를 갖고 점차 감소하는 편의 분포(分布)를 갖는다. 2. 삼요소(三要素) 이용율(利用率) (0 이상(以上)만)은 67년(年)에 N는 33(10kg 시비(施肥) 수준이상(水準以上)) P는 27, K는 40이고 68년(年)엔 40, 20, 46%이고 부(負)의 이용율(利用率)을 0으로한 2개년(個年) 평균(平均)은33(8kg 이상(以上)) 13, 27이었다. 3. 이용율(利用率)의 표준편차(漂準偏差)는 P와 K에서 이용율(利用率)보다 크고 P이용율(利用率)의 변이(變異)가 가장 크다. 4. 이용율(利用率)과 수량(收量) 또는 건물생산량(乾物生産量)과의 유의상관(有意相關) 출현빈도(出現頻度)는 N>K>P의 순(順)이며 10kg 수준의 N이용율(利用率)은 67년(年)엔 P이용율(利用率)과만 63년(年)엔 K이용율(利用率)과만 유의상관(有意相關)을 갖는다. 5. P이용율(利用率)은 그것이 높고 K이용율(利用率)이 낮았던 67년(年)에만, 그리고 K이용율(利用率)은 그와 반대였던 68년(年)에만 모든 처리구의 건물생산량(乾物生産量)과 유의상관(有意相關)을 보이고, 유의상관(有意相關)이 없는 해에는 무비구(無肥區) 및 결비구(缺肥區)區에서 부상관계수(負相顯係數)를 보이고 있다. 6. 이용율(利用率)과 수량(收量)과의 상관(相關)은 이용율(利用率)과 건물생산량(乾物生産量)과의 상관(相關)과 경향은 유사하나 유의성이 적어삼요소(三要素) 영양(營養)은 건물생산(乾物生産)에서 잘 표현된다. 7. N이용율(利用率)은 N시비구(施肥區)의 N흡수량(吸收量)과 많은 경우 유의상관(有意相關)을, 무(無)N구(區)의 흡수량(吸收量)과는 유의부상관(有意負相關)을 보이며, N시비구(施肥區)의 P, K또는 Si흡수량(吸收量)과도 여러 경우 유의상관(有意相關)을 보였다. 8. P이용율(利用率)은 그것이 높았던 67년(年)만 모든 처리구에서 Si흡수량(吸收量)과, 그리고 무(無)P구(區)를 제(除)한 모든 처리구의 N 흡수량(吸收量)과 유의상관(有意相關)을 보여 P는 일차적(一次的)으로 Si흡수(吸收)를 돕고 이차적(二次的)으로 Si흡수(吸收)가 N흡수(吸收)를 조장(助長)함을 나타낸다. P이용율(利用率)은 N시비구(施肥區)의 P흡수량(吸收量)과 K흡수량(吸收量)과도 많은 경우 유의상관(有意相關)을 보였다. 9. K이용율(利用率)은 그것이 컸던 68년(年)에 모든 처리구의 P흡수량(吸收量)과 무(無)N구(區)을 제(除)한 모든 처리구의 N흡수량(吸收量)과 그리고 무(無)P구(區)를 제(除)한 모든 처리구의 K흡수량(吸收量)과 유의상관(有意相關)을 보이며 무(無)K구(區)의 K흡수량(吸收量)과는 부상관(負相關)이고 K이용율(利用率)이 적었던 67년(年)에는 무비구(無肥區)나 결비구(缺肥區)의 P흡수량(吸收量)과 유의성(有意性)은 없으나 부상관(負相關)이었다. K이용율(利用率)은 N나 P와는 달리 K흡수량(吸收量)과 보다 수량(收量)이나 건물생산량(乾物生産量)과의 상관(相關)이 더 크며 K이용율(利用率)이 컸던 해에만 Si흡수량(吸收量)과 무(無)N구(區)와 최고시비구(最高施肥區)에서 유의상관(有意相關)을 갖고 무(無)K구(區)에서 유의부상관(有意負相關)을 보였다. 이로서 K는 일차적(一次的)으로 P흡수(吸收)를 돕고 이차적(二次的)으로 P가 N흡수(吸收)를 도와서 생산(生産)에 기여하는 것 같다. 10. N이용율(利用率)과 수량(收量)이나 건물생산량(乾物生産量)과의 상관(相關)이 무(無)P구(區)에서 보다 무(無)K구(區)가 높고 무(無)K구(區)보다 시비구(施肥區)에서 높으며 이러한 경향은 N이용율(利用率)과 N흡수량(吸收量)사이에서도 동일(同一)하였다. 이 사실과, K이용율(利用率)과 건물생산량(乾物生産量)과의 관계는 P가 N흡수(吸收)를 돕고 N나 P가 부족(不足)할 때에는 K가 N흡수(吸收)를 경쟁적으로 억제하여 생산(生産)을 저하(低下)시키는 것을 나타낸다. 11. 삼요소(三要素) 이용율(利用率)은 67년(年)에는 무(無)P구(區)의 상대건물생산량(相對乾物生産量)과, 68년(年)에는 무(無)K구(區)의 상대수량(相對收量)과 유의상관(有意相關)을 갖는다. 이는 P가 분얼 즉 영양생장단계에, K가 곡실형성 즉 생식 생장단계에 더 작용(作用)하였음을 나타내고 있다. 12. 삼요소(三要素) 이용율(利用率)과 결비구(缺肥區)의 상대생산량(相對生産量)이나 무비구(無肥區)의 결비구(缺肥區)에 대(對)한 상대생산량(相對生産量)과의 상관(相關)에서 어느 경우에도 N가 수도생산(水稻生産)에 가장 큰 역할(役割)을 하고 있음을 보였다. 13. 이상의 결과에서 40 내지 50%의 포장(圃場)은 P와 K를 시비(施肥)하지 아니해도 되며 시비량(施肥量)도 연도(年度)및 포장에 따라 변이(變異)가 커야 할 것이며 특히 P에서 그러하다.

• 천문학회보
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• 제41권1호
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• pp.79.3-80
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• 2016

We have investigated the correlation analysis between global temperature anomaly and two main factors: geomagnetic activity (aa index) of Earth external factor and CO2 of Earth internal factor. For this, we used NOAA Global Surface Temperature anomaly (Ta) data from 1868 to 2015. The aa index indicates the geomagnetic activity measured at two anti-podal subauroral stations (Canberra Australia and Hartland England) and the CO2 data come from historical ice core records and NOAA/ESRL data. From the comparison between (Ta) and aa index, we found several interesting things, First, the linear correlation coefficient between two parameters increases until 1985 and then decreases rapidly. Second, the scattered plot between two parameters shows a boundary of the correlation tendency (positive and negative correlation) near 1985. A partial correlation of (Ta) and two main factors (aa index, CO2) also shows that the geomagnetic effect (aa index) is dominant until about 1985 and the CO2 effect becomes much more important after then. These results indicate that the CO2 effect become very an important factor since at least 1985. For a further analysis, we simply assume that Ta = Ta(aa)+Ta(CO2) and made a linear regression between (Ta) and aa index from 1868 to 2015. A linear model is then made from the linear regression between energy consumption (a proxy of CO2 effect) and Ta-Ta(aa) since 1985. Our results will be discussed in view of the prediction of global warming.