• 청정기술
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• 제20권4호
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• pp.383-389
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• 2014

이산화탄소 흡수공정은 대규모의 이산화탄소를 처리하는데 유리하지만, 다량의 흡수액을 재생하는데 필요한 현열과 증발열로 인한 에너지 비용 상승이 단점으로 지적되고 있다. 이를 극복하기 위해 이산화탄소를 흡수한 탄산칼륨 흡수액을 냉각 결정화시켜, 다량의 물로부터 이산화탄소가 많이 포함된 중탄산칼륨 결정을 선택적으로 분리할 수 있다. 본 연구에서는 이산화탄소 분리효율을 높이기 위해 입체 장애 알카놀아민 첨가제를 도입하여, 이들이 중탄산칼륨 연속식 결정화에 미치는 영향에 대해 살펴보았다. 결정의 석출량은 2-아미노-2-메틸-1-프로판올(2-amino-2-methyl-1-propanol, AMP), 2-아미노-2-메틸-1,3-프로판디올(2-amino-2-methyl-1,3-propanediol, AMPD), 2-아미노-2-히드록시메틸-1,3-프로판디올(2-amino-2-hydroxymethyl-1,3-propanediol, AHPD)의 순서로 증가하였으며, 반용매로 작용하는 첨가제들의 히드록실기 개수와 관계가 있는 것으로 나타났다. 탄소 핵자기공명분광 분석 결과, 첨가제들은 입체 장애 효과에 의해 중탄산 이온의 생성을 유도하고 과포화도를 상승시킨 것으로 나타났다. 또한, 첨가제들은 과포화도 상승을 통해 평균 입도와 결정 성장 속도를 증가시키는 것으로 나타났다. 입체 장애 알카놀아민 첨가제는 중탄산칼륨 결정화를 촉진함으로써, 물로부터 이산화탄소의 분리효율을 향상시키고 재생에너지를 저감시킬 수 있을 것으로 기대된다.

• Korean Chemical Engineering Research
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• 제50권2호
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• pp.198-203
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• 2012

염석결정화 방법으로 염료용액으로 부터 염료를 결정화하였다. 이번 연구에서 반응성 염료(RB-8, RB-49, RR-218)의 모액의 용해도와 결정화 속도를 연구하였다. 그 결과 연속식 결정화기에서 반응성 염료(RB-8, RB-49, RR-218)에 대한 결정화 속도식 RB-8에서 결정성장 속도 $G=7.1{\times}10^{-4}{\Delta}C^{0.67}$와 핵생성 속도 $B^0=3.1{\times}10^{15}{\Delta}C[1.2{\times}10^{-8}+{\Delta}C^{0.7}M_T{^2}]$이고 RB-49는 결정성장 속도 $G=5.2{\times}10^{-4}C^{0.3441}$와 핵생성 속도 $B^0=7.2{\times}10^{15}{\Delta}C[3.3{\times}10^{-8}+({\Delta}C)^{0.7}M_T{^2}]$, RR-218의 결정성장 속도 $G=4.4{\times}10^{-4}C^{0.2361}$와 핵생성 속도 $B^0=6.3{\times}10^{15}{\Delta}C[7.9{\times}10^{-8}+({\Delta}C)^{0.7}M_T{^2}]$의 실험식으로 표현할 수 있다. 또한 특성 곡선 법을 적용하여 입도분포를 계산한 결과 실험식과 일치하는 결과를 확인할 수 있었다.

• 한국주조공학회지
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• 제15권2호
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• pp.164-174
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• 1995

New metallic powder making processes, named "Centrifugal Emulsification Process(CEP)" and "Mixer and Settler(MS)" have been developed to synthesize rapid solidified metallic powders. Through CEP and MS processings, the high temperature metals as well as the low temperature alloys are manufactured. Also, the effects of rapid solidification on the undercooling, solidification rate and crystallization behaviors can be evaluated effectively through the processes. The standard deviations of the synthesized typical Pb-Sn eutectic powders are 1.63 and 1.51 for CEP and MS respectively, and the average size of the MS powders was $18{\mu}m$. The possibility of the customized not only size and shape control but microstructure control was also shown. Both of the new methods can be applied to continuous powder making processes.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2009년도 제40회 하계학술대회
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• pp.1447_1448
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• 2009

In this paper, each specimen blended at weight proportions of 80% HDPE to 20% EVA, 70% HDPE to 30% EVA, 60% HDPE to 40% EVA, and 50% HDPE to 50% EVA was manufactured respectively. The insulation performances of the proposed insulator were compared with conventional XLPE, main insulating material of CV cable on the basis of the investigation results of DC insulation performances. From the space charge density, electric field and potential profiles with raising DC voltage and time variation in HE82, distortion of electric field distribution was improved. As EVA mixed into the bulks acts as nucleation in crystallization process of HDPE, the size of spherulites became decreased and finally formed continuous network structure. Ultimately it resulted from extinction of space charge in the interfacial region of spherulites.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1999년도 PROCEEDINGS OF 99 INTERNATIONAL CONFERENCE OF THE KACG AND 6TH KOREA·JAPAN EMG SYMPOSIUM (ELECTRONIC MATERIALS GROWTH SYMPOSIUM), HANYANG UNIVERSITY, SEOUL, 06월 09일 JUNE 1999
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• pp.209-225
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• 1999

Detailed description of the crystal growth methods permitting one to obtain complicated shape crystals from the melt is given. The variable shaping technique provides the growth of crystals with a discrete altering cross-section configuration during crystallization. The dynamic local shaping technique enables one to grow items with a continuous alteration of the side surface profile by a preset program.

• 한국결정성장학회지
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• 제9권4호
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• pp.417-423
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• 1999

Detailed description of the crystal growth methods permitting one to obtain complicated shape crystals from the melt is given. The variable shaping technique provides the growth of crystals with a discrete altering cross-section configuration during crystallization. The dynamic local shaping technique enables one to grow items with a continuous alteration of the side surface profile by a preset program.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2000년도 추계학술발표대회 논문집
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• pp.212-215
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• 2000

For the production of high strength constructional glass reinforced plastics and various composite materials continuous glass fibers of high strength and increased modulus of elasticity are used. As is known, the glasses with highest strength were obtained in magnesia alumosilicate and magnesia lime-alumosilicate systems when introducing oxides of titanium and zirconium, boric anhydride, etc. in some cases. The experimental investigations have shown that some glass compositions are characterized by the ratio viscosity/crystallization which is favourable for glass fiber drawing process that permits the attainment of high strength level at the conditions of high temperature glass melting and formation.

• 한국광물학회지
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• 제11권1호
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• pp.32-44
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• 1998

The transformation sequence of kaolinite to mullite is examined with new electron diffraction data obtained mainly by an energy filtering transmission electron microscope. Kaolinite is transformed finally into mullite and cristobalite through several steps of continuous reactions by heating, which result in metakaolinite, microcrystalline spinel-type phase and amorphous silica. Metakaolinite maintains a short-range order in its structure ven at $920^{\circ}C$. Spinel phase results from a topotactictransformation of metakaolinite apart from the breakdown of metakaolinite structure. the first strong exothermic peak on DTA curve is mainly due to the extraction of amorphous silica from metakaolinite and the gradual nucleation of mullite. Metakaolinite decomposes around$ 940^{\circ}C$ to mullite that doesn't show a clear crystallographic relationship to the parent metakaolinite structure. However, spinel phase produced previously is maintained. The initially formed spinel and mullite phases are suggested to be Al-rich, but progressively gain Si in their structures at higher temperatures. Spinel phase decomposes completely through a second weak exothermic reaction promoting the growth of mullite, and crystallization of amorphous silica to cristobalite.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2004년도 춘계종합학술대회
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• pp.687-690
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• 2004

The preparation of A1203-SiO2 thin films from less than one micron to several tens of microns in thickness had been Prepared from metal alkoxide sols. Two methods, dip-withdrawal and electrophoretic deposition, were employed for thin films and sheets formation. The requirements to be satisfied by the solution for preparing uniform and strong films and by the factors affecting thickness and other properties of the films were examined. For the preparation of thin, continuous A12O3-SiO2 films, therefore, metal-organic-derived precursor solutions contained Si and Al in a chemically polymerized form has been developed and produced in a clear liquid state.

• 전기학회논문지
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• 제58권11호
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• pp.2229-2235
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• 2009

In this paper, each specimen blended at weight proportions of 80% HDPE to 20% EVA, 70% HDPE to 30% EVA, 60% HDPE to 40% EVA, and 50% HDPE to 50% EVA was manufactured respectively. The insulation performances of the proposed insulator were compared with conventional XLPE, main insulating material of CV cable on the basis of the investigation results of DC insulation performances. From the space charge density, electric field and potential profiles with raising DC voltage and time variation in HE82, distortion of electric field distribution was improved. As EVA mixed into the bulks acts as nucleation in crystallization process of HDPE, the size of spherulites became decreased and finally formed continuous network structure. Ultimately, it resulted from extinction of space charge in the interfacial region of spherulites.