• 제목/요약/키워드: Continuous Flow Reactor

검색결과 156건 처리시간 0.034초

원자력발전소 유출계통의 과도현상에 대한 연구 (A Study on Hydraulic Transients of Letdown System of Nuclear Power Plant)

  • 김민;정장규;김은기;노태선;이성노;유성연
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2002년도 유체기계 연구개발 발표회 논문집
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    • pp.493-498
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    • 2002
  • The letdown system of pressurized water reactor (PWR) nuclear fewer plants had experienced instabilities in letdown system due to unacceptable flow characteristics of control valves. The Korean Standard Nuclear Power Plants (KSNPs) have three flow paths in parallel for letdown new control. Each flow path consists of two offices and one isolation valve. This study evaluates the effect of orifice arrangement and valve stroke time of letdown isolation valve on the system transients because sudden flow changes due to valve actuation can generate high pressure peaks in letdown line. A pressure transient analysis has been preformed to evaluate the impact of dynamic transients. This analysis uses MMS which is a simulation code developed by EPRI based on the method of characteristics. The result shows that the pressure peak is reduced in the continuous arrangement but negligible. Additionally, it shows that the stroke time of linear type flog valve greater than 15 seconds can give more stable performance.

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$TiO_2$ 광촉매반응을 이용한 수중의 은이온 제거에 관한 연구 (A Study on the Removal of Ag(I) in Water Using $TiO_2$ Photocatalysis)

  • 김현용;조일형;양원호;김민호;이홍근
    • 환경위생공학
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    • 제15권2호
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    • pp.58-64
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    • 2000
  • The photocatalytic removal of Ag(I) in water by $TiO_2$ at a various conditions, which are initial Ag(I) concentration, circulation flow rate, $TiO_2$ dosage and methanol concentration, was studied. A continuous flow system with a circular type reactor of the TiO2 suspensions with UV light through an photoreactor column was applied. The major results of this study were as follows; 1. First order kinetics was observed from the result at different initial concentration of Ag(I). As the initial Ag(I) concentration was incereased, the reaction rate was decreased. 2. The removal efficiency of Ag(I) increased with increasing the circulation flow rate and $TiO_2$ dosage. However, over $4{\ell}/min$ of circulation flow rate and $1.5g/{\ell}$ of $TiO_2$ dosage, increasing of the efficiency reached a plateau. 3. The addition of methanol as hole scavenger enhanced the removal efficiency of Ag(I) but the removal efficiency reached a plateau over some level of methanol. 4. It was found that $TiO_2$ photocatalysis was effective method to remove of Ag(I) from aqueous solution.

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수소 생산을 위한 Sulfur-Iodine Cycle 분젠반응의 Pilot-Scale 공정 모델 개발 및 공정 최적화 (Design and Optimization of Pilot-Scale Bunsen Process in Sulfur-Iodine (SI) Cycle for Hydrogen Production)

  • 박준규;남기전;허성구;이종규;이인범;유창규
    • Korean Chemical Engineering Research
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    • 제58권2호
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    • pp.235-247
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    • 2020
  • Sulfur-Iodine cycle (SI cycle)은 요오드와 황을 첨가하여 최종적으로 물을 열화학적으로 분해하여 산소와 수소를 생산하는 공정으로 황산분해, 요오드화 수소 분해, 분젠반응 등 세가지 반응들로 이루어져 있다. 분젠 반응은 두가지 공정 중간에 존재하므로 두 반응에 필요한 화학물을 조달하는 역할로 이에 대한 상분리 및 반응기에 대한 분석이 중요하다. 본 연구에서는 50 L/hr 수소를 생산하는 pilot scale의 Sulfur-Iodine Cycle 중 분젠 공정에 대한 모사, 민감도 분석, 민감도 분석을 토대로한 각각 상분리기와 분젠 반응기에 대한 최적 조건을 제시하였다. 열역학 물성치의 계산을 위해 Electrolyte Non-Random Two Liquid (ELECNRTL) model 사용하였다. 모델에 대한 신뢰도 확보를 위해서 실제 pilot scale의 공정 데이터와 검증을 수행하였다. 반응기의 종류를 선정하기 위해 Continuous Stirred Tank Reactor (CSTR)과 Plug Flow Reactor (PFR) 동일한 온도 및 부피 변화에서 SO2 전환율을 비교하였다. 상분리기 선정을 위해 3상 분리 시스템(기체-액체-액체)과 액체-기체 분리 후 액체-액체 구조에서 H2SO4 상과 HIX 상에서의 불순물들을 비교하였다. PFR에서 온도, 지름, 길이를 결정 변수로 SO2 전환율을 최대화 하기 위한 최적화를 수행하였는데, 온도 121 ℃와 PFR의 지름이 0.20 m 및 길이 7.6 m 일 때 SO2 전환율이 98% 최적 결과임을 확인하였다. 기존 pilot scale과 동일한 운전 조건 하에 PFR의 지름 3/8 inch, 길이 3.0 m, 120 ℃ 일 때 인입 몰량인 I2 및 H2O를 결정 변수로 SO2 전환율에 대한 최적화를 수행하였을 때, SO2 전환율이 10% 일때 H2O 및 I2 의 인입 몰량은 각각 17%와 22%로 감소하였다. 앞선 조업 조건 최적화 조건 (121 ℃, 지름 0.20 m, 길이: 7.6 m) 경우에는 SO2 전환율이 98% 일 때 H2O가 1% 그리고 I2가 7% 감소하였다. 상분리기에서 HIX 상내 H2SO4 최소화하는 목적함수에서 그에 상응하는 온도, I2와 H2O를 결정 변수로 설정하였을 때, H2O 몰량이 기존공정보다 17% 감소하고 I2 몰량이 24% 감소하였을 때 최소 불순물이 생성하였다.

이상혐기공정의 축산폐수 공공처리시설 적용 가능성에 관한 실험적 연구 (A Study on the Evaluation of Two-Phase Anaerobic Process for Public Livestock Wastewater Treatment Plant)

  • 오성모;김문호;배윤선;박철휘
    • 상하수도학회지
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    • 제21권3호
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    • pp.331-339
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    • 2007
  • The purpose of this study was to investigate the biodegradability and performance of organic removal and methane production rate when treating piggery wastewater using a pilot scale two-phase anaerobic system operated up to a volumetric rate of $10m^3/day$. The pilot scale two-phase anaerobic process is consisted of a continuous-flow stirred-tank reactor (CFSTR) for the acidification phase and an Upflow Anaerobic Sludge Blanket reactor (UASB) for the methanogenesis. The acidogenic reactor played key roles in reducing the periodically applied shock-loading and in the acidification of the influent organics. The acidogenic CFSTR was operated at organic loading rates (OLR) between 1.8 and $14.4kgCOD/m^3{\cdot}day$, and the UASB reactor was operated between 0.5 and $5.6kgCOD/m^3{\cdot}day$. A stable maximum biogas production rate was $81m^3/day$ and the methane conversion rate of the organic matter varied from 0.30 to $0.42L\;CH_4/g\;COD_{removed}$(0.40) at hydraulic retention time (HRT) above 3.5days. The methane contents ranged from 73 to 82% during the experimental period. It is known that most of the removed organic matter was converted to methane gas, and the produced biogas might be high quality for its subsequent use.

Pilot 규모 연속배열형 인공습지의 영양염류 제거효능 규명 및 평가모델 연구 (A Pilot-Scale Study of Multiple Stage of Constructed Wetland Treatment System and Modeling for Nutrient Removal)

  • 최승일;;이재성
    • 한국물환경학회지
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    • 제26권5호
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    • pp.781-788
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    • 2010
  • A pilot study was performed to examine the feasibility of multiple stage of constructed wetland (CW) for nutrient removal. The system is composed of six wetland cells connected with water-ways. The hydraulic of wetland cells is designed as free water surface flow. The treatment capacity was $25m^3d^{-1}$ at HRT of about one day for each cell. The magnitude of nutrient removal was related with the length of wetlands and plant density. Total N and P removal rates were 1353 and $246mg\;m^{-2}d^{-1}$ respectively. The pilot-scale reactor was model as continuous flow system containing contribution of CSTR and PFR typed-reactors. The $k-C^*$ model equation was applied to predict N and P reduction. The result indicated the equation was well guided to estimate reduction of $NO_3-N$ and $PO_4-P$.

HIGH-THROUGHPUT PROCESS FOR ATOMIC LAYER DEPOSITION

  • Shin, Woong-Chul;Choi, Kyu-Jeong;Baek, Min;Kim, Mi-Ry
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.23.2-23.2
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    • 2009
  • Atomic layer deposition (ALD)have been proven to be a very attractive technique for the fabrication of advanced gate dielectrics and DRAM insulators due to excellent conformality and precise control of film thickness and composition, However, one major disadvantages of ALD is its relatively low deposition rate (throughput) because the deposition rate is typically limited by the time required for purging process between the introduction of precursors. In order to improve its throughput, many efforts have been made by commercial companies, for example,the modification reactor and development of precursors. However, any promising solution has not reported to date. We developed a new concept ALD system(Lucida TM S200) with high-throughput. In this process, a continuous flow of ALD precursor and purging gas are simultaneously introduced from different locations in the ALD reactor. A cyclic ALD process is carried out by moving the wafer holder up and down. Therefore, the time required for ALD reaction cycle is determined by speed of the wafer holder and vapor pressure of precursors. We will present the operating principle of our system and results of deposition.

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케미컬루핑 연소시스템을 위한 산소전달입자의 상온-상압 고체순환특성 (Solid Circulation Characteristics of Oxygen Carrier for Chemical Looping Combustion System at Ambient Temperature and Pressure)

  • 윤주영;김하나;김정환;이도연;백점인;류호정
    • 한국수소및신에너지학회논문집
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    • 제28권4호
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    • pp.384-391
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    • 2017
  • Effects of operating variables on solid circulation rate were measured and discussed using two-interconnected circulating fluidized bed system at ambient temperature and pressure. OCN 706-1100 particles were used as oxygen carrier. The measured solid circulation rates increased as the lower loop seal gas flow rates and the solid height in the fuel reactor increased. Suitable operating conditions to avoid choking of the air reactor were confirmed. Continuous long-term operations of steady-state solid circulation were also demonstrated at two different conditions based on the operating window.

혐기-호기 상향류 필터 공정에서 양식배출수의 질산화 및 탈질 연구 (Nitrification and Denitrification of Land-based Fish Farm Wastewater using an Anaerobic-Aerobic Upflow Biological Aerated Filter)

  • 박노백;이현영;김성민;이준상
    • 한국수산과학회지
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    • 제47권5호
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    • pp.622-629
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    • 2014
  • This study induced biological denitrification and nitrification via a biofiltration process with the view of removing nitrogen from land-based fish farm effluent. To achieve this, we operated an aquaculture nitrogen-removal system that includes a denitrification and nitrification reactor [working volume 40 L, flow rate 64.8 L, HRT (hydraulic retention time) 14.8 h, HRT considering recycling of NOx 7.4 h]. In the continuous process, the nitrification rate of ammonium nitrogen exceeded 90% at a steady state and the denitrification efficiency exceeded 80% with recycling to a pre-anoxic reactor. In addition, the pH in the final effluent was lower with a low influent water alkalinity averaging 100 mg/L (as $CaCO_3$). For effective denitrification reactions, carbon must be supplied via particulate organic matter (POM) hydrolysis because of the low C/N (carbon/nitrogen) ratio in the water.

호기성 침지형 생물막법을 이용한 Polyester 감량폐수의 처리 (Treatment of Polyester Weight Loss Wastewater by Aerated Submerged Biofilm Process)

  • 박종웅;김대희
    • 한국환경보건학회지
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    • 제23권3호
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    • pp.85-90
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    • 1997
  • The objective of this study was to investigate biodegradation of TPA(terephthalic acid) and EG (ethylene glycol), treatment efficiency of polyester weight loss wastewater and microbial characteristics by aerated submerged biolfilm(ASB) p.rocess. In a batch reactor, pH increased from 7.0 to 8. 5 in the biodegradation of TPA. Whereas, in case of EG, decreased from 7.0 to 5.2. COD concentration rapidly decreased within 24hr in the biodegradation of TPA and EG. COD removal velocity constant(k) were 0.065-0.088 hr$^{-1}$. The biodegradation velocity of TPA was 1.4 times faster than that of EG. The ratio of suspended biomass to the total biomass in the reactor was 18.3-33.3%, increased as a high ratio of EG content. Biofilm thickness, biofilm dry density and attached biomass were 346-432 $\mu$m, 41.8-61.9 mg/cm$^3$, 1.45-2.67 mg/cm$^2$, respectively. There values increased as a high ratio of TPA content. In the hydraulic retention time of 36 hr, organic loading rate of 4 kgCOD/m$^3\cdot$ day and packing ratio of 70%, the effluent concentrations of TCOD, SCOD in a continuous flow reator were 1,388 mg/l, 147 mg/l and removal efficiencies were 77%, 97.6%, respectively.

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INVESTIGATION ON EFFECTS OF ENLARGED PIPE RUPTURE SIZE AND AIR PENETRATION TIMING IN REAL-SCALE EXPERIMENT OF SIPHON BREAKER

  • Kang, Soon Ho;Lee, Kwon-Yeong;Lee, Gi Cheol;Kim, Seong Hoon;Chi, Dae Young;Seo, Kyoungwoo;Yoon, Juhyeon;Kim, Moo Hwan;Park, Hyun Sun
    • Nuclear Engineering and Technology
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    • 제46권6호
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    • pp.817-824
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    • 2014
  • To ensure the safety of research reactors, the water level must be maintained above the required height. When a pipe ruptures, the siphon phenomenon causes continuous loss of coolant until the hydraulic head is removed. To protect the reactor core from this kind of accident, a siphon breaker has been suggested as a passive safety device. This study mainly focused on two variables: the size of the pipe rupture and the timing of air entrainment. In this study, the size of the pipe rupture was increased to the guillotine break case. There was a region in which a larger pipe rupture did not need a larger siphon breaker, and the water flow rate was related to the size of the pipe rupture and affected the residual water quantity. The timing of air entrainment was predicted to influence residual water level. However, the residual water level was not affected by the timing of air entrainment. The experimental cases, which showed the characteristic of partical sweep-out mode in the separation of siphon breaking phenomenon [2], showed almost same trend of physical properties.