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Hot Corrosion Properties of Heat Resistant Chrome Steels (내열강의 고온부식특성에 대한 크롬함량의 영향)

  • Lee, Han-sang;Jung, Jine-sung;Yoo, Keun-bong;Kim, Eui-hyun
    • Korean Journal of Metals and Materials
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    • v.48 no.4
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    • pp.277-288
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    • 2010
  • The hot corrosion properties of heat-resistant steels were investigated in an oxidation atmosphere including artificial ash and sulfur dioxide. The heat-resistant steels of T22, T92, T122, T347HFG, Super304H and HR3C were evaluated at 620, 670 and $720^{\circ}C$ for 400 hours. The relationship between the corrosion rate and the temperature followed a bell-shaped curve with a peak rate at around $670^{\circ}C$. The corrosion rates showed a decreasing tendency as the chrome contents of these steels increased from 2.15 wt.% to 24.5 wt.%, and austenitic steels had a lower corrosion rate than ferritic steels. Sulfidation by $SO_2$ as well as molten salt corrosion also had an effect on the total corrosion rate, especially showing an increase in the corrosion rate in ferritic steels. Regardless of the chrome content in the steels and irrespective of the test temperature, the corrosion scale was composed of an outer oxide and an artificial ash mixed layer, a middle oxide layer and inner sulfide, and a mixed oxide layer. As the chrome content increased, the proportion of chrome oxide in the corrosion scale increased. Before spalling of the corrosion scale, voids and cracks were initiated in the sulfide and the mixed oxide layer or at the interface with the substrate.

Evaluation of Lightweight Soil as a Subgrade Material (경량혼합토의 도로 노상층 재료 사용 가능성 평가)

  • Park, Dae-Wook;Vo, Viet Hai
    • International Journal of Highway Engineering
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    • v.15 no.5
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    • pp.57-64
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    • 2013
  • PURPOSES : It is to evaluate lightweight soil as a subgrade material based on mechanical tests and calculation of pavement performance. METHODS : In this research, various contents of cement and air foam are used to make lightweight soil using wasted dredged soil. Uniaxial compressive strength test is conducted to evaluate strength of 7 and 28 day cured specimens. Secant modulus was calculated based on the stress and strain relationship of uniaxial compressive strength test. Resilient modulus test was measured using by repeated triaxial compression test. The measured resilient modulus was used in layered elastic program to predict fatigue and rutting life at a given pavement structure. RESULTS : Uniaxial compressive strength increases as cement content increases but decrease as air foam content increases. Resilient modulus also increases as cement content increases and decrease as air foam content decrease. CONCLUSIONS : It is concluded that dredge clay soil can be used as subgrade layer material using by lightweight treated soil method.

Effect of Al content on coating adhesion of hot rolled galvanized iron manufactured without pickling process (무산세 열연 용융아연도금강판의 도금밀착성에 미치는 도금욕 Al농도의 영향)

  • 전선호;최진원
    • Journal of the Korean institute of surface engineering
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    • v.32 no.1
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    • pp.31-42
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    • 1999
  • The effect was investigated that aluminium in the zinc bath has on the coating adhesion of Hot-rolled Galvanized Iron(HGI) manufactured without pickling process. It is thought that the coating adhesion of HGI manufactured without pickling process is good due to the fact that increasing aluminium content in the zinc bath makes zinc and aluminium diffuse to the cracks or pores in the scale formed through the reduction heat treatment, and Fe-Zn-Al compound with good ductility is formed in the scale layer and plays a role of anchor between zinc coating and substrate. It is possible that HGI with the good coating adhesion was produced without pickling treatment in the zinc bath with more that 3wt% of Al content even at the $550^{\circ}C$ of conventional reduction heating temperature. In creasing the temperature of heating section and aluminium content in the zinc bath prevents the Zn-Fe alloy. The corrosion resistance of HGI manufactured without pickling process is excellent because of the mixed reaction of zinc sacrifice and aluminium passivity film.

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Tensile Properties of Carbon-Glass/Epoxy Hybrid Laminates Produced by VARTM (VARTM 법으로 제작한 탄소-유리/에폭시 하이브리드 적층재의 인장 특성)

  • Kim, Yonjig
    • Korean Journal of Metals and Materials
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    • v.49 no.10
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    • pp.760-765
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    • 2011
  • This paper presents a study of the tensile behavior of carbon and glass fiber reinforced epoxy hybrid laminates manufactured by vacuum assisted resin transfer molding (VARTM). The objective of this study was to develop and characterize carbon fiber reinforced plastic hybrid composite material that is low cost and light-weight and that possesses adequate strength and stiffness. The effect of position and content of the glass fabric layer on the tensile properties of the hybrid laminates was examined. The strength and stiffness of the hybrid laminates showed a steady decrease with an increase of the glass fabric content this decrease was almost linear. Fracture strain of these laminates showed a slight increasing trend when glass fabric content was increased up to 3 layers, but at a glass fabric content > 3 layers the strain was almost constant. When glass fabric layers were at both outer surfaces, the hybrid laminate exhibited a slightly higher tensile strength and elastic modulus due to the small amount of glass yarn pull-out.

Primary Production System in the Southern Waters of the East Sea, Korea III. Vertical Distribution of the Phytoplankton in Relation to Chlorophyll Maximum Layer

  • Shim, Jae-Hyung;Park, Jong-Gyu
    • Journal of the korean society of oceanography
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    • v.31 no.4
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    • pp.196-206
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    • 1996
  • Vertical profiles of the chlorophyll ${\alpha}$, phytoplankton abundance, nutrients and sigma-t were compared with the vertical distribution of phytoplankton species in conjunction with $^{14}$C primary production in the Southern Waters of the East Sea, Korea. In the upper mixed layer the water column was only weakly stratified and ambient nitrogenic nutrient concentrations were markedly depleted. Dissolved silicate seemed to be another limiting nutrient in the surface layer. The occupation of different water depths by several dominant diatom species was well explained by the degree of silicification of each cell and the silicate concentration of ambient seawater. Subsurface chlorophyll maxima were continuously observed in the lower parts of the euphotic layer and the depth coincided with nutricline, supporting our view that chlorophyll maximum was sustained partially by enhancement of in situ growth of phytoplankton and partially by increase of cellular chlorophyll content. The persistence of chlorophyll maximum layer was attributed to the physiological adaptation of the phytoplankters to low light intensities and to the utilization of regenerated nutrients. Integrated water column production of organic matter by photosynthesis appeared to be better related to phytoplankton cell division than to the cell growth in terms of biosynthesis of pigments and other intracellular components.

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Electroless Ni-P Plating and Heat Treatments of the Coating Layer for Enhancement of the Cavitation Erosion Resistance of Vessel Propellers (선박 프로펠러의 케비테이션 침식 저항 향상을 위한 Ni-P 무전해 도금층 형성 및 열처리를 통한 미세조직 제어)

  • Kim, Young-jae;Son, In-Jun;Yi, Seonghoon
    • Korean Journal of Materials Research
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    • v.27 no.8
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    • pp.409-415
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    • 2017
  • For enhanced cavitation erosion resistance of vessel propellers, an electroless Ni-P plating method was introduced to form a coating layer with high hardness on the surface of Cu alloy (CAC703C) used as vessel propeller material. An electroless Ni-P plating reaction generated by Fe atoms in the Cu alloy occurred, forming a uniform amorphous layer with P content of ~10 wt%. The amorphous layer transformed to (Ni3P+Ni) two phase structure after heat treatment. Cavitation erosion tests following the ASTM G-32 standard were carried out to relate the microstructural changes by heat treatment and the cavitation erosion resistance in distilled water and 3.5 wt% NaCl solutions. It was possible to obtain excellent cavitation erosion resistance through careful microstructural control of the coating layer, demonstrating that this electroless Ni-P plating process is a viable coating process for the enhancement of the cavitation erosion resistance of vessel propellers.

Morphology and Electrical Properties of Back Electrode for Solar Cell Depending on the Mo : Na/Mo Bilayer Thickness (Mo : Na/Mo 이중층 구조 두께에 따른 태양전지 후면전극의 조직 및 전기적 특성)

  • Shin, Younhak;Kim, Myunghan
    • Korean Journal of Materials Research
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    • v.23 no.9
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    • pp.495-500
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    • 2013
  • Mo-based thin films are frequently used as back electrode materials because of their low resistivity and high crystallinity in CIGS chalcopyrite solar cells. Mo:Na/Mo bilayer thin films with $1{\mu}m$ thickness were deposited on soda lime glass by varying the thickness of each layer using dc-magnetron sputtering. The effects of the Mo:Na layer on morphology and electrical property in terms of resistivity were systematically investigated. The resistivity increased from $159{\mu}{\Omega}cm$ to $944{\mu}{\Omega}cm$; this seemed to be caused by increased surface defects and low crystallinity as the thickness of Mo:Na layer increased from 100 nm to 500 nm. The surface morphologies of the Mo thin films changed from a somewhat coarse fibrous structures to irregular and fine celled structures with increased surface cracks along the cell boundaries as the thickness of Mo:Na layer increased. Na contents varied drastically from 0.03 % to 0.52 % according to the variation of Mo:Na layer thickness. The change in Na content may be ascribed to changes in surface morphology and crystallinity of the thin films.

Prediction models of the shear modulus of normal or frozen soil-rock mixtures

  • Zhou, Zhong;Yang, Hao;Xing, Kai;Gao, Wenyuan
    • Geomechanics and Engineering
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    • v.15 no.2
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    • pp.783-791
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    • 2018
  • In consideration of the mesoscopic structure of soil-rock mixtures in which the rock aggregates are wrapped by soil at normal temperatures, a two-layer embedded model of single-inclusion composite material was built to calculate the shear modulus of soil-rock mixtures. At a freezing temperature, an interface ice interlayer was placed between the soil and rock interface in the mesoscopic structure of the soil-rock mixtures. Considering that, a three-layer embedded model of double-inclusion composite materials and a multi-step multiphase micromechanics model were then built to calculate the shear modulus of the frozen soil-rock mixtures. Given the effect of pore structure of soil-rock mixtures at normal temperatures, its shear modulus was also calculated by using of the three-layer embedded model. Experimental comparison showed that compared with the two-layer embedded model, the effect predicted by the three-layer embedded model of the soil-rock mixtures was better. The shear modulus of the soil-rock mixtures gradually increased with the increase in rock regardless of temperature, and the increment rate of the shear modulus increased rapidly particularly when the rock content ranged from 50% to 70%. The shear modulus of the frozen soil-rock mixtures was nearly 3.7 times higher than that of the soil-rock mixtures at a normal temperature.

The Evaluation Technique of Surface Region using Backward-Radiated Ultrasound (후방 복사된 초음파를 이용한 표면 지역의 평가 기술)

  • Kwon, S.D.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.16 no.4
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    • pp.241-250
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    • 1997
  • The velocity dispersion of surface acoustical wave(SAW) of Si layer/mesh Au/Si substrate was measured by the frequency analysis technique of backward radiation at liquid/solid interface. The difference of backward radiation patterns depending on used transducers (2, 5, 10MHz) confirmed that the backward radiation phenomenon was caused by the energy radiation from SAW generated in surface region. An ultrasonic goniometer was constructed to measure continuously the angular dependence of backscattered intensity. The angular dependences of backward radiation(5MHz) were measured for Ni layer/Al substrate specimens that were bonded by epoxy involving different content of Cu powder. It was known that the width and pattern of backward radiation had informations such as the velocity dispersion, bonding quality and structure of surface region.

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GROUND TREATMENT CASE HISTORY OFR SOFT CLAY LAYER AND EVALUATION OF ITS IMPROVEMENT (연약지반처리와 개량효과 평가사례)

  • Lee, Yeong-Nam;Lee, Hyeong-Ju;Sim, Dong-Hyeon
    • Proceedings of the Korean Geotechical Society Conference
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    • 1992.10a
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    • pp.113-120
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    • 1992
  • The construction of container terminal at Brani, Singapore required the improvement of soft clay layer having the thickness of about 6.5m, average moisture content of 79.4%, liquid limit of 90.4%, plastic limit of 21.8%, field vane strength of 10 to 25 KPa, pre-consolidation pressure of 225 to 60 KPa and compression index of 0.4 to 1.0. For the improvement of this layer, Colbon drains of 1.3m spacing in triangular pattern were installed to the bottom of the layer and surcharge of more than 11.25m high sand fill was later applied to the treated area. The settlement and lateral displacement of the ground were measured and the speed of surcharge filling was controlled, based on these readings. The removal of surcharge was determinied using the estimated time for the 90% degree of consolidation under the design pressure of 180KPa. The field and laboratory test results show that the soft clay layer has been improved substantially in its strength and consolidation characteristics: increase in strength of about 50KPa and pre-consolidation pressure and decrease in void ratio and compression index.

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