• 제목/요약/키워드: Contamination of Surface

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A Study on the Assessment of the Contamination by Acid Mine Drainage in Abandoned Coal Mines (국내폐탄광의 산성폐수 오염도 평가에 관한 연구)

  • 최우진
    • Journal of Korea Soil Environment Society
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    • v.2 no.3
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    • pp.31-38
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    • 1997
  • Temporal and spatial comparisons of acid mine drainage contaminated waters are difficult because of the complex physico-chemical nature of the pollutant. In the present study, an acid mine drainage index has been developed and evaluated for the assessment of surface waters. AMD index is calculated using a modified arithmetic weighted index using seven parameters which are most indicative of AMD contamination, i. e. pH value, sulphate, iron, zinc, aluminum, copper and manganese. Weighting is used to express the relative indicator value of each parameter. The proposed AMD index is used to quantify contamination from acid mine drainage over ten different old mine sites and assess the degree of impact on surface on surface waters. As a result of AMD evaluation, the Sukbong Mine located near the Moonkyung province showed lowest AMD value indicating the worst acid mine drainage quality. In overall, Youngdong mine sites showed higher contaimination compared to the other mine sites including Youngsuh, Choongbu, Suhbu and Nambu area.

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Application of Soil's Self-Decontamination Ability to Contaminated Ground (흙의 자체정화능력을 이용한 오염된 토양정화)

  • Jeong, Jin-Seob;Jhung, Jhung-Kwon;Kim, Tae-Hyung;Fang, Hsai-Yang
    • Journal of Korean Society on Water Environment
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    • v.22 no.4
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    • pp.632-638
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    • 2006
  • There are numerous approaches available to cleanup a contaminated surface and subsurface ground currently in use, however, these methods all classify the decontamination after the contamination has penetrated into the soil masses and is costly. Unlike these approaches, in this study, utilization of soil's self-decontamination ability by rearranging and preplanning of the topographical features and surface and subsurface drainage systems for the potential contamination sites before or during contamination process has been considered as an another cleanup method. Step by step explanations on why and how to develop the self-decontamination procedure is proposed in detail. Two examples are presented including contaminated saltwater intrusion along a coastal region and control or prevention of radioactive toxic radon gas ($^{222}Rn$) in residential areas. The effectiveness of the proposed systems to these two examples using the soil's self-decontamination ability is well illustrated.

Study of point defects caused by a thin contamination layer in a-Si TFT-LCD

  • Oh, Jae-Young;Lee, Jae-Kyun;Yang, Moung-Su;Kang, In-Byeong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.845-848
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    • 2007
  • Analysis of point defects invisible by a microscope has been studied on the a-Si thin film transistor panel. The point defects which were named Invisible Point Defect (IPD) is characterized by no particles or distortion of patterns on a pixel structure and randomly distributed on panels. To investigate the IPD, measurements were carried out: gray level driving, transistor transfer characteristic, focused ion beam (FIB), and secondary ion mass spectrometry (SIMS). The results showed that a contamination layer had a bad influence on an active surface. The contamination layer consisted of oxygen and iron from a water supply line during cleaning process. After the process tuning, IPD has been stabilized.

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Effect of Accumulated charges on Surface Hydrophobicity of RTV Silicone Rubber (RTV 실리콘 고무 코팅재의 표면전하 축적이 발수성에 미치는 영향)

  • 연복희;허창수;조한구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.597-600
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    • 2001
  • In this paper, we evaluated the effect of accumulated charges on hydrophobicity of room temperature vulcanized(RTV) silicone rubber, which could improve the contamination performance of porcelain insulators, with uv radiation time. Outdoor insulating material could be charged by the corona discharge on field intensified area of insulator and discharge between the water drops. In addition, we performed the accelerated uv radiation on samples and investigated the change of charging decay with time. In this results, it is found that silica-like structure on the surface of RTV silicone rubber was formed by uv treatments and this layer have the characteristic of retaining the charges on surface for a long time. These charges have effects on its hydrophobicity and so adversely effects on contamination performance. Based on our results, we discussed the other degradation mechanism with well known ones.

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A Study on Soil Contamination Investigation of Farmland Around Industrial Areas in Northern Gyeonggi Province (경기북부 산업단지 주변 농지의 토양오염도 조사연구)

  • Park, Jin-Ho;Kwon, Kyung-Ahn;Jung, Eun-Hee;Kim, Jae-Kwang;Kim, Ji-Young;Oh, Jo-Kyo
    • Journal of Environmental Health Sciences
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    • v.43 no.5
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    • pp.393-400
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    • 2017
  • This study was investigated on pH, heavy metals, oils and solvents in 34 surface soil samples and the samples are collected at two times for 17 farmland sites around 7 industrial areas in Northern Gyeonggi Province. As a result of pH for soil contamination monitoring network, the range of pH showed 4.4~8.4 and average was 6.3. The range of pH for Agricultural land around industrial area was 6.7~7.5 and average indicated 7.1 that mostly showed neutral condition in this area. he average concentrations of Cu, Pb, Ni, As and $Cr^{6+}$ are lower than Korea soil contamination worrisome levels at region 1 and the mean levels of farmland from the soil quality monitoring network. The average concentrations of Zn, Cd and Hg didn't exceed the soil contamination worrisome levels at region 1 but slightly higher than the mean levels of farmland from the soil quality monitoring network. The heavy metal levels of all samples are within Korea soil contamination worrisome levels at region 1. The results showed that the detected heavy metal concentrations ranged from N.D. to ~32.7% of Korea soil contamination worrisome levels at region 1. BTEX, TPH, TCE and PCE were not detected in all samples and thus the farmland around the industrial areas were free from oils and solvents contamination.

THE EFFECTS OF SURFACE CONTAMINATION ON THE SHEAR BOND STRENGTH OF COMPOMER

  • Heo, Jeong-Moo;Lee, Su-Jong;Im, Mi-Kyung
    • Proceedings of the KACD Conference
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    • 2001.11a
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    • pp.577-577
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    • 2001
  • The lastest concepts in bonding are "total etch", in which both enamel and dentin are etched with an acid to remove the smear layers, and "wet dentin" in which the dentin is not blown dry but left moist before application of the bonding primer. Ideally, the application of a bonding agent to tooth structure should be insensitive to minor contamination from oral fluids. Clinically contaminations such as saliva, gingival fluid, blood and handpiece lubricant are often encountered by dentists during preparation of a restoration. The aim of this study was to evaluate the effect of contamination by hem-ostatic agents on shear bond strength of compomer restorations. One hundred and ten extracted human maxillary and mandibular molar teeth were collected. The teeth were cleaned from soft tissue remnant and debris and stored in physiologic solution until they were used. Small flat area on dentin of the buccal surface were wet ground serially with 400, 800 and 1200 abrasive paper on automatic polishing machine. The teeth were randomly divided into 11 groups. Each group was conditioned as follows: Group 1 : Dentin surface was not etched and not contaminated by hemostatic agents. Group2 : Dentin surface was not etched but was contaminated by Astringedent (Ultradent product Inc., Utah, U.S.A.). Group3 : Dentin surface was not etched but was contaminated by Bosmin (Jeil Phann, Korea.). Group4 : Dentin surface was not etched but was contaminated by Epri-dent (Epr Industries, NJ, U.S.A.). Group5: Dentin surface was etched and not contaminated by hemostatic agents. Group 6 : Dentin surface was etched and contaminated by Astringedent. Group7 : Dentin surface was etched and contaminated by Bosmin. Group8 : Dentin surface was etched and contaminated by Epri-dent. Group9 : Dentin surface was contaminated by Astringedent. The contaminated surface was rinsed by water and dried by compressed air. Group10 : Dentin surface was contaminated by Bosmin. The contaminated surface was rinsed by water aud dried by compresfed air. Group 11 : Dentin surface was contaminated by Epri-dent. The contaminated surface was rinsed by water and dried by compresfed air. After surface conditioning, F2000 was applicated on the conditoned dentin surface. The teeth were thermocycled in distilled water at $5^{\circ}C\;and\;55^{\circ}C$ for 1000 cycles. The samples were placed on the binder with the bonded compomer-dentin interface parallel to the lmife-edge shearing rod of the Universal testing machine(Zwick 020, Germany) running at a cross head speed of 1.0mmimin. There were no significant differences in shear bond strength between groups 1 and group 3 and 4, but group 2 showed significant decrease in shear bond strength compared with group 1. There were no significant differences in shear bond strength between group 5 and group 7 and 8, but group 6 showed significant decrease in shear bond strength compared with group 5. There were no significant differences in shear bond strength between group 5 and group 9, 10 and 11.

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A Study on the Removal of Cu and Fe Impurities on Si Substrate (Si 기판에서 구리와 철 금속불순물의 제거에 대한 연구)

  • Choi, Baik-Il;Jeon, Hyeong-Tag
    • Korean Journal of Materials Research
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    • v.8 no.9
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    • pp.837-842
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    • 1998
  • As the size of the integrated circuit is scaled down the importance of Si cleaning has been emphasized. One of the major concerns is abut the removal of metallic impurities such as Cu and Fe on Si surface. In this study, we intentionally contaminated Cu and Fe on the Si wafers and cleaned the wafer by cleaning splits of the chemical mixture of $\textrm{H}_2\textrm{O}_2$ and HF and the combination of HF treatment with UV/$\textrm{O}_3$ treatment. The contamination level was monitored by TXRF. Surface microroughness of the Si wafers was measured by AFM. The Si wafer surface was examined by SEM. AES analysis was carried out to analyze the chemical composition of Cu impurities. The amount of Cu impurities after intentional contamination was abut the level of $\textrm{10}^{14}$ atoms/$\textrm{cm}^2$. The amount of Cu was decreased down to the level of $\textrm{10}^{10}$ atoms/$\textrm{cm}^2$ by cleaning splits. The repeated treatment exhibited better Cu removal efficiency. The surface roughness caused by contamination and removal of Cu was improved by repeated treatment of the cleaning splits. Cu were adsorbed on Si surface not in a thin film type but in a particle type and its diameter was abut 100-400${\AA}$ and its height was 30-100${\AA}$. Cu was contaminated on Si surface by chemical adsorption. In the case of Fe the contamination level was $\textrm{10}^{13}$ atoms/$\textrm{cm}^2$ and showed similar results of above Cu cleaning. Fe was contaminated on Si surface by physical adsorption and as a particle type.

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Contamination Status and Characteristics of Persistent Organochlorine Pesticides in the Saemangeum Environment (새만금 해양환경에서의 잔류성 유기염소계 농약의 분포 및 특성)

  • Hong, Sang-Hee;Shim, Won-Joon;Li, Dong-Hao;Yim, Un-Hyuk;Oh, Jae-Ryoung;Kim, Eun-Soo
    • Ocean and Polar Research
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    • v.28 no.3
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    • pp.317-329
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    • 2006
  • To assess the contamination status of organochlorine pesticides in the marine environment of Saemangeum, surface seawater and sediments were collected and analyzed. Organochlorine pesticides were widely distributed in the Saemangeum environment, with DDT, HCH and endosulfan II contamination being particularly prevalent. The overall concentrations of DDTs, HCHs, and endosulfan II in surface seawater were in the rage of 0.03-0.65ng/l (mean value: 0.36ng/l), 1.31-4.54ng/l (2.63 ng/l), and not detected (ND)-0.96ng/l (0.49ng/l), respectively. Among the target organochlorine pesticides, endosulfan II showed the hi띤est level at the river mouth flowing into the Saemangeum. Additionally, its negative gradient from the rivers to the outside and a good correlation with $NO_3^-$ indicate that endosulfan ll inflows to the Saemangeum through the river; this conclusion is also supported by the elevated levels of endosulfan II in sediments at the river mouth. In sediment, the concentration of DDTs, HCHs, CHLs, and endosulfan II were in the range of 0.05-1.96 ng/g, 0.03-0.31ng/g, 0.01-0.13ng/g, and ND-0.62ng/g, respectively. Levels of contamination in Saemangeum are relatively lower than the median concentrations previously observed at the Korean coastal regions and sediment quality guidelines suggested by NOAA (Long et at. 1995).

Contamination structure and process on SUS 316 under UHV, HV and air (초고진공, 고진공, 대기압에서 SUS 316의 오염 구조와 오염 과정 연구)

  • 서지근;이규장;신용현;홍승수;정광화
    • Journal of the Korean Vacuum Society
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    • v.6 no.1
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    • pp.1-8
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    • 1997
  • The contamination structure and process on SUS 316 under various exposure conditions were investigated using x-ray photoelectron spectroscopy. The metal-oxide, metal-H-oxides, CO, COH, and $C_xH_y$ are the main components of contaminants on the SUS surface. The compositional profiles of the contaminants are shown to be $C_xH_y$/CO(COH)/metal-oxide on SUS. The contamination proceeds in two steps. The oxidation of the metallic constituents followed by adsorption of hydrocarbons. Under UHV conditions the contamination is mainly due to the oxidation, and, as the exposure time increases, the oxidation continues. In HV or higher pressure, most of the oxides are formed almost immediately after exposure and as the exposure time increases the contamination of hydrocarbons continues to grow. For the SUS sample exposed to atmosphere, the metal oxide is distributed deep inside the surface with an exponentially decreasing concentration, and its thickness is nearly in the order of photoelectron mean free path. It is also seen that the Fe oxide is segregated over Cr oxide in the highly oxidized samples.

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Contamination of Butyltin Compounds in Sediments inside Jeju Harbor of Jeju Island (제주도 제주항내 퇴적물 중의 부틸주석화합물의 오염)

  • Kam, Sang-Kyu;Hu, Chul-Goo;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.20 no.5
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    • pp.655-665
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    • 2011
  • Contamination of butyltin compounds (BTs), namely tributyltin (TBT), dibutyltin (DBT) and monobutyltin (MBT), was evaluated in sediments collected inside Jeju Harbor in 2001. The concentrations of BTs in surface sediments were comparable to those in other sites of domestic and foreign countries. The high correlations between BTs in surface ($r^2$ = 0.83~0.91) and core ($r^2$ = 0.70~0.79) sediments and the significant correlations between BTs concentrations and the number of incoming and outgoing vessels indicated that DBT and MBT were mainly degraded from TBT based on antifouling paints of vessels etc. and other sources, such as DBT and MBT, could be ignored. The butyltin degradation indices ([DBT] + [MBT]/[TBT]) in surface sediments were in the range of 2.2~3.6 (mean 2.7), indicating that the parent compound, TBT, was inflowed into the surface sediments a long ago, degraded and deposited. The sedimentation age of BTs contaminated core sediments could not estimated because the content of $^{210}Pb$ activity was nearly all the same and so the sedimentation rate could not obtained.